基于PHREEQC模拟分析Na2S2O4对退役铀矿山采区地下水生态的修复

酸法原位地浸采铀作为回收铀资源首选工艺,不可避免会存在部分铀进入地下水污染生态环境,而采用还原剂Na2S2O4将游离的铀还原固定可高效解决此类问题。为此,针对某酸法地浸采铀退役铀矿山地下水铀污染,采用PHREEQC模拟分析Na2S2O4还原固定地下水中可溶性铀的机制,讨论NaHCO3在Na2S2O4还原固定可溶性铀的影响。模拟结果表明：1）该区域地下水中铀以U(Ⅵ)为主,其中UO2SO4、UO22+和UO2(SO4)22-为优势物种,分别占63.60%、32.35%和3.89%;2）Na2S2O4还原固定可溶性铀时,会降低地下水Eh值和Fe(Ⅲ)浓度,增强地下水还原性,促进沥青铀矿和黄铁矿沉淀,但会造成地下水酸化和高SO32-浓度;3）NaHCO3+Na2S2O4在还原固定可溶性铀时,减轻了地下水酸化,增强了对U(Ⅵ)和SO32-的去除,对Na2S2O4还原固定可溶性铀的影响较小,在Na2S2O4和NaHCO3浓度比为1︰1至1︰1.5时修复效果最佳。     

CaCO3固硫炼焦及其对生铁含硫量影响的实验室研究

研究了用ＣａＣＯ３作固硫剂的焦炭性质,并探讨了固硫焦对生铁含硫量的影响因素,结果表明用ＣａＣＯ３作用硫剂炼焦是可行的。     

桌面式眼动跟踪系统研究

眼动跟踪技术作为一种新的人机交互方式,已受到越来越多人的关注,现有的眼动跟踪系统大都是头戴式的,它的硬件设备复杂,对人干扰较大,而且价格昂贵。文章实现了一个简单的基于桌面的眼动跟踪系统,本系统硬件构成简单,而且不与人直接接触,使用虹膜中心坐标来估计用户的注视点。实验表明,当误差距离不超过40个像素时,系统估计的人眼注视点准确率超过80%。     

Using Combined Bipolar Semantic Scales and Eye‐Tracking Metrics to Compare Consumer Perception of Real and Virtual Bottles

Three‐dimensional virtual representations of consumer products are expected to gain relevance in e‐commerce applications as low cost virtual reality headsets arrive on the market in the next years. However, there are a limited number of studies related to the perceptual evaluation of virtual products and their packaging where virtual and real (photographic) representations are compared. As part of an extensive exploration toward understanding product perception in virtual stores, this work presents a study with 38 participants in which consumer perceptions of a photographic and a virtual representation of a beer bottle are examined. Perceptual evaluation is assessed using two metrics: first, an evaluation was performed by applying a bipolar semantic scale based on four axes: novelty, resolution, style and emotion. Second, eye‐tracking metrics were employed to analyse participant gaze behaviour during the visualization of stimuli. Virtual bottles were modelled using a medium polygonal load (5 K polygons per bottle), and render quality was also medium to intentionally recreate the computing limitations of smartphone‐based virtual reality headsets. Results show that a medium render quality alters consumer perception and responses using semantic scales. Eye‐tracking analysis confirms that the orientation of the bottle and how it is presented also affect consumer perception. While some orientations result in similar eye‐tracking metrics, others show different results. Copyright © 2015 John Wiley & Sons, Ltd.     

The microstructure and mechanical properties of prolonged and lower temperature aged Fe–Ni–Mn–Mo–Ti–Cr maraging steel

In this study, the microstructure and mechanical properties of Fe–Ni–Mn–Mo–Ti–Cr maraging steel at low temperature and prolonged aging condition were investigated. Optical and scanning electron microscopy examinations, tensile and hardness tests were conducted to study the microstructure, aging behavior and mechanical properties of the cold‐rolled steel. The results showed that aging of cold rolled Fe–Ni–Mn–Mo–Ti–Cr maraging steel resulted in the formation of Mo rich and Ti rich Lave phase precipitates. Existence of many dislocation cores due to cold rolling and subsequently, low temperature aging caused to formation of uniform distribution of very fine precipitates. The presence of these precipitates increased the yield and ultimate tensile strengths but couldn't improve the uniform tensile ductility. This alloy showed ultra‐high fracture stress of about 1950 MPa with a negligible tensile elongation (about 2 %) at the peak aged condition. The fractographic studies indicated this alloy shows semi‐brittle fracture in the subsequent aging treatment.     

Copper(I)‐Catalyzed Desulfinative Carboxylation of Sodium Sulfinates using Carbon Dioxide

A copper(I)‐catalyzed desulfinative carboxylation of sodium sulfinates using carbon dioxide has been developed. This reaction showed wide functional group tolerance. A series of sodium aryl‐ and alkenylsulfinates could be converted into the corresponding carboxylic acids in good to excellent yields. Additionally, the reaction mechanism was studied by in situ NMR analysis and isotopic labeling experiments.

     

戊二醛固着茧衣丝胶的工艺研究

用戊二醛作固着剂对茧衣进行丝胶固着,通过对戊二醛浓度和固胶温度的探索,得出了在茧衣不明显着色的前提下戊二醛固胶的较优工艺方案。     

抽水蓄能机组推力系统缺陷改造

介绍了抽水蓄能机组推力系统一起重大缺陷发现的经过,论述了现场检查情况,对造成缺陷的原因进行了分析,提出了整改处理意见和防范措施。     

In Vivo Metabolic Responses to Different Formulations of Amino Acid Mixtures for the Treatment of Phenylketonuria (PKU)

Phenylketonuria (PKU) is a rare autosomal recessive inborn error of metabolism where the mainstay of treatment is a Phe restricted diet consisting of a combination of limited amounts of natural protein with supplementation of Phe-free or low-Phe protein substitutes and special low protein foods. Suboptimal outcomes may be related to the different absorption kinetics of free AAs, which have lower biological efficacy than natural proteins. Physiomimic Technology^TM is a technology engineered to prolong AA (AA-PT) release allowing physiological absorption and masking the odor and taste of free AAs. The aim of these studies was to assess the impact of AA-PT formulation on selected functional and metabolic parameters both in acute and long-term experimental studies. Adult rats in fasting conditions were randomized in different groups and treated by oral gavage. Acute AA-PT administration resulted in significantly lower BUN at 90 min versus baseline. Both BUN and glycemia were modulated in the same direction as intact casein protein. Long-term treatment with AA-PT significantly reduces the protein expression of the muscle degradation marker Bnip3L (−46%) while significantly increasing the proliferation of market myostatin (+58%). Animals dosed for 15 days with AA-PT had significantly stronger grip strength (+30%) versus baseline. In conclusion, the results suggest that the AA-PT formulation may have beneficial effects on both AA oxidation and catabolism with a direct impact on muscle as well as on other metabolic pathways.     

利用库仑法测硫仪测试碳酸钙固硫效果的试验研究

介绍了采用库仑法测硫仪测试碳酸钙的固硫效果的条件试验,并对温度与钙硫比对固硫效果的影响进行探讨。试验结果分析表明,采用合适的钙硫比及燃烧温度等条件能够提高碳酸钙的固硫效果。