分子内敏化鎓盐的合成及光敏性研究

二芳基碘鎓盐和三芳基硫鎓盐是阳离子聚合的光引发剂和光敏产酸物,但他们在300nm以上的光吸收很低,限制了对紫外光的利用效率。为解决此问题,本文合成了一些新的碘鎓盐和硫鎓盐,并用凝胶时间方法考察了它们的光引发效率。实验结果表明,2-苯硫基甲基,2′,4′-二甲基二苯碘鎓盐和9-蒽丙基,二苯基硫鎓盐具有特别高的光引发效率,这归之于光照时这些鎓盐发生了分子内电荷转移反应,即发生了分子内敏化。9-蒽丙基二苯硫鎓盐分子中的蒽基(An)是电子给体也是敏化基团,光照时可发生如下反应:     

Prediction model of compressive strength development of fly-ash concrete

Based on experimental results concerning the compressive strength development of concrete containing fly ash, the authors derived an estimation equation for compressive strength development. The equation can express coefficient , which indicates the activity of fly ash as a binder, in the form of a function of age, fly-ash content, and Blaine specific surface area of fly ash.

This equation is capable of explaining the increases in the early strength due to fly ash in place of part of fine aggregate, the decreases in the early strength due to fly ash in place of part of cement, the increases in the long-term strength due to pozzolanic reaction, the relationship between the fly-ash replacement ratio and the ratio of strength increase/decrease, and the effect of fly ash's Blaine specific surface area on the strength.     

循环式活性污泥法处理炼油污水

研究为在炼油污水的CAST工艺的主反应区中 ,通过恰当控制pH值和DO(污水中溶解氧含量 )值 ,可以使硝化与反硝化反应同步进行 ,在去除COD ,BOD的同时 ,也可提高其脱氮效果 ,从而得出DO的最佳值为 0 .8mg/L ,pH为 7.3～ 7.7之间。     

月桂氮草酮研究进展

介绍了月桂氮草酮作为高效皮肤促渗剂的发展概况、合成工艺、研究进展及其应用前景。     

OXYGEN TRANSFER IN HORIZONTAL PIPELINE AERATORS WITH NOZZLES

Horizontal pipeline and tubular loop aerators are of interest for fermentation and waste water treatment and are ideally suited for continuous processing. A major drawback is that these pipeline contactors invariably operate in the “elongated bubble and plug” regime in which the mass transfer rate is low. This article evaluates the performance of a horizontal pipeline aerator fitted with nozzles equispaced along its length to enhance mass transfer rates by promoting turbulence and augmenting effective interfacial area. Such devices can also be advantageously used in long pipe lines as in the case of treating waste while it is being transported. Pressure drop and overall liquid-side mass transfer coefficient data are reported as functions of liquid (water) and gas flow rates and nozzle size and spacing. It is shown that for all the conditions studied, k_La = 0.026(ΔP/L)^1.036 and that the pressure gradient is given by a simple correlation, provided an empirical parameter which characterises a nozzle is known. Preliminary investigations on the effect of surfactant ad the presence of suspended solids (size 75 μm) on mass transfer coefficient are also reported. Very high values of power dissipation can be achieved in such aerators without mechanically moving parts and high values of mass transfer coefficient can be realized.     

Modelling the effects of human papillomavirus in cervical cells

Worldwide, cervical cancer is the second most common cancer in women, after breast cancer. The prevalence of this malignant disease is estimated at 1.4 million cases worldwide, causing about 290,000 deaths and 500,000 new cases per year, of which 80% correspond to women living in developing countries. In this work we propose a family of ordered models for basal cells of the cervix corresponding to different stages ranging from normal cells to the formation of precancerous lesions. We analyse the first member of the family analytically and for the second member we developed a non-standard numerical method in order to extract some biological information.     

MATHEMATICAL MODELING OF THROUGH-HOLE-PLATING IN ELECTROCHEMICAL MICROFABRICATION II. AXISYMMETRIC TWO-DIMENSIONAL CONVECTIVE MASS TRANSFER

Axisymmetrical, two dimensional mass transfer in a tube and a through-hole was studied. The elliptic convective-diffusion equation was solved numerically by taking into account both the axial and radial diffusion in the entrance region of an infinite tube. The whole mass-transfer region in a tube of finite length was also studied by dividing the domain into several regions according to different mass-transfer mechanisms. A similar analysis is then conducted for a through-hole geometry by assuming a modified Hagen-Poiseuille fluid pattern. Results show that mass-transfer rate in a through-hole is larger than that in a tube by approximately 10%. This is due primarily to faster fluid flow within the concentration boundary layer in a through-hole.     

碰撞式混合器的设计和使用

从反应注射成型过程对混合器的结构设计、操作条件等的要求出发，对碰撞式混合器的设计和使用应注意的问题进行了分析探讨，并提出了相应的解决办法和处理措施。     

Propagation of the Chain Explosive‐Decomposition Reaction in Silver Azide Crystals

The velocity of the chain explosivedecomposition reaction in silver azide whiskes has been measured (1500 m/sec). The measured velocity is identified as the propagation velocity of the diffusion front of holes generated in the course of explosive decomposition.