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11.
C. Athanassiou G. Pekridis N. Kaklidis K. Kalimeri S. Vartzoka G. Marnellos 《International Journal of Hydrogen Energy》2007
In the present work, the prospects and trends of solid electrolyte membrane reactors (SEMRs) towards hydrogen production, are discussed. Initially, an overview of the principles, the properties and the techniques related to the usage of the SEMRs, are presented. In the following, a literature survey covering earlier and recent developments of the various methods (e.g. reforming or partial oxidation or dehydrogenation of hydrocarbons, steam electrolysis) employed in the SEMRs for the production of hydrogen, is performed. Finally, the current status of this research field is analyzed and future research topics are proposed. 相似文献
12.
Effect of Rare Earth Element Cerium on Mechanical Properties and Morphology of TiN Coating Prepared by Arc Ion Plating 总被引:7,自引:0,他引:7
TiN coatings were deposited on polished substrates of W18Cr4V high speed steel by means of vacuum arc ion plating. The effect of cerium on adhesion between TiN coating and substrate was studied. The microstructures and composition of TiN coatings were also investigated by means of scanning electron microscope (SEM), Auger electron spectroscopy (AES), and X-ray diffraction (XRD) technique. It was found that cerium is an effective modifying agent and the addition of suitable amount of cerium to TiN coatings can produce relatively excellent properties such as micro-hardness, wear resistance, oxidation resistance and porosity. The experimental results show that the added cerium in TiN coatings makesa contribution to form the preferred direction along with a (111 ) or (222) close packed face, which may be one of the reasons that improves some properties mentioned above. 相似文献
13.
A remarkable nonlinearity has been observed for electric transport in K-TCNQ (potassium tetracyanoquinodimethane) quasi-one-dimensional
conductor. The negative differential resistance region appears afterV
m (turn over voltage), beyond which voltage goes down with increase of current. A possible mechanism is discussed in terms
of dynamics of charged solitons and domain walls in one-dimensional molecular stacks of these types of crystals. 相似文献
14.
A. Andreev L. Prahov M. Gabrovska A. Eliyas V. Ivanova 《Applied catalysis. B, Environmental》1996,8(4):365-373
The catalytic activity of a wide range of transition metal oxides in oxidation of sulphide ions by air in aqueous medium was studied. Some specific features of the reaction mechanism on some of the studied oxides were considered. The transition metal oxides are promising catalysts for practical application. Some of these oxides will allow the preparation of catalysts possessing activity comparable to that of the cobalt phthalocyanine based catalysts, popular in industrial practice. 相似文献
15.
离子注入对Cr12MoV钢表面组织结构和力学性能的影响 总被引:1,自引:0,他引:1
研究了Cr12MoV钢离子注入层的显微组织特征及其对表面性能的影响。结果表明,离子注入使Cr12MoV钢的表面硬度和耐磨性能得到显著改善,且存在着一个最佳的注入剂量,约为3×10^1^7N^+/cm^2左右。离了注入在Cr12MoV钢表面层中形成了大量细小弥散的第二相粒子,并使α-Fe晶格发生严重畸变,从而引起材料表面强化。 相似文献
16.
飞行时间二次离子质谱--强有力的表面、界面和薄膜分析手段 总被引:8,自引:0,他引:8
二次离子质谱(Secondary ion mass spectrometry,简称SIMS)是一种对表面灵敏的质谱技术,建立在表面各种类型带正、负电荷原子或分子发射的基础上。用飞行时间(Time of flight,简称TOF)仪器对这些二次离子进行质量分析,能确保并行质量登录、高质量范围、高流通率下的高分辨和精确质量测定这些优异性能。配合细聚焦扫描一次离子束,可在优于1nm的高深度分辨和优于50nm的横向分辨本领下,实现对表面优于单层ppm(百万分之一)量级的极高检测灵敏度。当今TOF-SIMS已发展为一种成熟且完善的表面分析技术。极高的灵敏度,再加上即使对大分子及不易挥发性分子都独具的敏感性,使它成为很多高技术领域不可缺少的分析手段,这些领域包括微电子学、化学和材料科学以至纳米技术和生命科学等。本文简述了TOF-SIMS的原理、仪器及其多方面的应用和展望。 相似文献
17.
18.
The paper presents experimental results of secondary ion energy distributions obtained for Ti and Si targets bombarded by 20-30 keV monoisotope Ar+ ion beam. The influence of the extraction voltages between target and a slit of the electrostatic energy analyzer entrance on the energy distributions of secondary ions was investigated. After optimization of the secondary ion extraction system, the mass spectra of secondary ions were also measured. The investigations were done using recently built experimental system. Experimental data are compared with the computer simulation results obtained using TRQR and SATVAL codes. 相似文献
19.
对传统的钼酸铵溶液净化工艺及文献介绍工艺进行了较为详细的分析 ,并与实验数据对比分析 ,找到了较为合理的工艺方案 相似文献
20.