Carbon molecular sieve films produced by dc sputtering

This paper reports adsorption measurements that show molecular sieve effects in amorphous hydrogenated carbon (a-C : H) films deposited by d.c. magnetron discharge decomposition of acetylene. Adsorption of organic gases on the films is studied by using a quartz crystal microbalance technique. The sieve effect in this material depends on both deposition and annealing conditions. Films having significant molecular sieve effects are found to be typically microporous and to have a very small characteristic micropore dimension. It is suggested that the d.c. sputtered a-C : H film may be useful as a molecular sieve material in selective adsorption and gas permeation studies.     

石英晶体最大双折射率色散特性的椭偏测量

为了测量石英晶体最大双折射率的色散特性,在椭偏光谱仪的水平透射测量模式下,通过对确定厚度的石英波片相位延迟量的精确测量,计算出了石英晶体的最大双折射率值,并进行了误差分析。结果表明:这种方法光路简单、操作方便,屏蔽了光源的不稳定性;双折射率测量精度达到了10-6,比连续偏光干涉法的测量精度提高了1个数量级;实现了对石英晶体的最大双折射率色散特性的连续光谱测量;此方法对其它双折射晶体材料的双折射率色散特性的研究也同样适用。     

Alkaline treatment kinetics of calcium phosphate by piezoelectric quartz crystal impedance

Calcium phosphate film was prepared by electrochemical deposition technology. Subsequently, the alkaline treatment process of calcium phosphate film in 0.1 mol/L NaOH solution was monitored on real time by the piezoelectric quartz crystal impedance (PQCI) technique. The variations of morphology and composition for the alkaline treatment products were characterized by scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) and X-ray diffraction (XRD), respectively. The dynamic variations of calcium phosphate can be characterized by the change of equivalent circuit parameters. The results show that the forming process of hydroxyapatite (HA) is composed of three stages: (1) acidic calcium phosphate dissolution; (2) phase transformation; and (3) HA formation. Furthermore, the correlative kinetic equations and parameters are obtained by fitting the static capacitance (C _s)—time curves. Foundation item: Project(2005CB623901) supported by the Major State Basic Research and Development Program of China     

19.6μm微管内部阻力特征

分别以蒸馏水、四氯化碳为工质,流过内径19.6 μm光滑石英管,分别采用"单管法"和"双管法"测量微管进出口压力、温度和流量,实验得到了雷诺数(Re数)在9.6～530之间的微管内部流动阻力,并与经典理论值进行了对比.实验研究结果表明,粘性耗散效应降低了摩擦系数,降低了约13.7%;进出口压力降、入口效应与双电层效应(electrical double layer,EDL效应)则增加微管内部摩擦系数,在Re数相同时,其中,进出口压力降与入口效应大约增加了16.12%摩擦系数,EDL效应增加了约6.84%摩擦系数.忽略3种微尺度效应,19.6 μm管流动摩擦系数与Hagen Poiseuille理论值几乎一致.     

改性石英砂的润湿性能研究

对经过改性处理之后的普通石英砂的润湿性能进行了研究。实验采用滴水穿透时间法（WDPT）、酒精溶液入渗法（MED）、接触角测定法三种方法。通过这三种方法来定性和定量地描述其润湿性能。实验结果表明：直接经过酸化处理的石英砂与经过硅烷化处理的石英砂的润湿性能有着明显的改变,前者较普通石英砂表现更为亲水,而后者表现出斥水性。此研究为用石英砂模拟不同润湿性能土壤提供了表面改性方法以及前期的理论准备。     

Measurement of intrinsic rates for homogeneous gas‐phase reactions at high temperatures

A coiled quartz tubular reactor has been designed to measure the intrinsic reaction kinetics for homogeneous reactions at high temperatures up to 1100°C. Actual gas residence times were less than 100 ms. A simple and well‐studied test reaction (i.e., the decomposition of nitrous oxide, N₂O), with published intrinsic kinetics, was used to verify the operation of the experimental reactor. For this system, Peclet numbers (Pe = uL/DL) computed from experimental conversion data were greater than 1000, indicating that the plug flow assumption could be used with this reactor system to determine intrinsic rate expressions with errors of less than 5% for the conditions studied.     

Efficiency of mineral admixtures in mortars: Quantification of the physical and chemical effects of fine admixtures in relation with compressive strength

This work is the fourth part of an overall project the aim of which was the development of general mix design rules for concrete containing different kinds of mineral admixtures. The two first parts presented the separation and quantification, by means of an empirical model based on semi-adiabatic calorimetry measurements, of the different physical effects responsible for changes in cement hydration (short terms) when chemically inert quartz powders were used in mortars. Part three dealt with an intensive experimental program, presenting and commenting more than 2000 compressive strength measurements. This program concerned 1 day to 6 months old mortars containing up to 75% of inert and pozzolanic admixtures. All these compressive strength results are analyzed in this fourth part and the influence of three effects, namely dilution, heterogeneous nucleation and the pozzolanic effect, are discriminated and quantitatively evaluated. An efficiency concept is proposed in order to take into account the effect of mineral admixture in mortars from both the physical and chemical points of view. It uses an efficiency function ξ(p) that has notable properties: it is independent of time, independent of fineness and independent of the type of mineral admixture.     

基于石英挠性加速度计A/D与I/F数据采集系统的对比研究

为满足对寻北仪导航系统中加速度计采集数据的高精度要求,提出了基于石英挠性加速度计的A/D采集系统与I/F数据采集系统的对比研究;系统采用了高精度A/D转换芯片AD7693和V/F高精度转换芯片LM331分别对石英挠性加速度计采集的数据进行处理转换,以FPGA芯片XC7Z020为逻辑控制核心对转换的数据进行编帧处理,通过RS232总线将处理的数据发送到上位机;测试结果表明,在相同条件下,I/F采集系统转换的精度99.99％优于A/D采集系统转换的精度98.7％;短时间内,I/F采集系统采集的数据变化不大,A/D采集系统采集的数据变化大,所以I/F采集系统稳定性更好.     

石英与长石在酸性介质中的浮选分离研究

以十二烷基磺酸钠(SDS)和N-十二烷基-1,3-丙二胺(DN12)作为混合捕收剂,采用单矿浮选实验分离石英与长石,探究DN12和SDS对长石和石英浮选回收率的影响及其浮选分离的机理。结果表明,在p H为2.0,DN12浓度为4.739×10-4mol/L,SDS浓度为2.38×10-4mol/L时,长石和石英回收率的差值最大,达62.3%。紫外光谱的分析得出,SDS和DN12捕收剂在长石表面仅存在物理吸附,在石英表面不仅存在物理吸附,还存在化学吸附,表明该捕收剂对石英具有更强的捕收能力。     

高Q值超低功耗谐振式磁传感器的设计与实现

针对现有谐振式磁传感器原理不能同时实现高品质因数(Q)和低功耗的缺点,利用双端固定石英音叉谐振器与铁镓磁致伸缩合金片复合,设计了一种隔离磁机阻尼的高Q值、数字频率输出的超低功耗谐振式磁传感器。利用音叉谐振器结构的解耦特性,设计应力耦合传递结构,隔离了磁致伸缩材料磁机阻尼,从而保证复合传感器Q值与音叉谐振器Q值相当。在磁场作用下,磁致伸缩力传递到音叉谐振器,由于音叉力敏感特性,实现磁-力-频率转换。制备了铁镓合金/石英音叉谐振器复合敏感结构,测试表明,在低气压封装条件下的品质因数约为16 764,门振荡电路功耗约为124.8μW,在线性区灵敏度为3.05 Hz/Oe,分辨率为6 mOe。