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41.
Zhen-Xue Liu Jung-Nam Park S. H. R. Abdi Seung-Kyu Park Yong-Ki Park Chul Wee Lee 《Topics in Catalysis》2006,39(3-4):221-226
In this paper, the ethylene adsorption capacities of the nano-sized carbon hollow spheres (CNB) and active carbon (AC), the
Pd (PdCl2) impregnated CNB or AC (Pd/CNB, Pd/AC) and heat treatment under various conditions, were studied at different ethylene concentrations
from 64 to 1060 ppm. The results indicated that AC had a good ethylene adsorption capacity at high ethylene concentration.
Pd impregnation decreased the ethylene adsorption capacity of AC. Heat treatment and H2 activation could increase the ethylene adsorption capacity, but also lowered than AC itself. CNB had lower ethylene adsorption
capacity than AC, but heat treatment and H2 activation could increase its ethylene adsorption capacity markedly. With activating condition from heat treatment in N2 at 300 °C to activation in H2/N2 at 100 °C, to activation in H2 at 200 °C, and to activation in H2 at 300 °C, the ethylene adsorption capacity of Pd/CNB was increased regularly. At low ethylene concentration, viz., 64 ppm,
the ethylene adsorption quantities (q
a) by Pd/CNB activated in H2 at 200 or 300 °C were higher than any other adsorbents. So, activated in H2 atmosphere at higher than 100 °C, Pd/CNB is particularly advantaged for adsorbing low concentration of ethylene. Amongst
all the adsorbents used, Pd/CNB activated in H2 atmosphere at 300 °C for 2 h has the highest ethylene adsorption capacity at lower concentration than 125 ppm. In addition,
all the CNB, Pd/CNB, AC, and Pd/AC samples can be easily regenerated in airflow for more than 3 h. 相似文献
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45.
废橡胶再生技术研究进展 总被引:12,自引:0,他引:12
综述了废橡胶再生利用的技术和方法,介绍了废橡胶的物理再生、化学再生的再行剂和微生物再生方法及进展,并对化学再生助剂、植物再生剂和生物再生助剂的再生效果进行了系统评述。 相似文献
46.
阐述了离子膜法烧碱系统中螯合树脂塔的工艺设计和生产中已出现和可能出现的问题,并介绍了解决问题的方法。 相似文献
47.
ABSTRACT This study explores an electrochemical adsorption method on the regeneration of aqueous drilling fluid waste. Response surface analysis was applied to investigating the electrochemical factors on the adsorption performance. The response surface polynomial model optimized the preferred electrochemical adsorption conditions with adsorption time of 20 min, spacing electrodes of 5 cm, adsorption concentration of 5% and NaCl concentration of 2 g/L. The model calculated electrochemical adsorption amount of drilling fluid showed only 1.3% deviation from the experimental results. Thus, the model could provide effective support for the device design and application of drilling fluid electrochemical adsorption process. 相似文献
48.
In this study, we explored a new ion exchange material synthesized by radical polymerization of styrene and 2‐acrylamido‐2‐methyl‐1‐propane sulfonic acid by using 2,2′‐azo‐isobutyronitrile (1 mol %) and divinylbenzene (0.5 mol %) as initiator and crosslinking reagents, respectively. The resin was obtained from a large excess (90%) of styrene in the feed. The yield was 72.3%. The resin was completely insoluble in water and characterized by elemental analysis, FTIR spectroscopy, scanning electron microscopy, and thermal analysis. The metal ion retention capability was investigated for Ag(I), Hg(II), Cd(II), Zn(II), Pb(II), and Cr(III). The effect of pH, time, and resin/metal ion mol ratio on the metal ion retention was studied. Selectivity of the resins from a mixture of metal ions and the maximum retention capacity at optimum pH were also determined. The recovery of the resin by using 1 and 4 M HClO4 and HNO3 demonstrated that it is possible to recover the resin above 80%. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 1230–1235, 2003 相似文献
49.
介绍了盐水二次精制的工艺流程、操作方法以及树脂塔的再生原理和注意问题。通过加强对盐水二次精制生产条件和螯舍树脂再生过程的控制,提高了树脂性能,保证了螯合能力的发挥,生产的合格精制盐水满足了离子膜电解生产的要求。 相似文献
50.
A micro-envioment for nerve cells and tissue growth were designed and constructed via surface modification of poly(L-lactide-co-glycolide)(PLGA)
with chitosan and hydroxyapatite(HA). The poly(L-lactide-co-glycolide)/chitosan/hydroxyapatite (PLGA/chitosan/HA) conduits
were manufactured by a combined solvent casting and particulate leaching technique. The conduits were highly porous with an
interconnected pore structure and 76.5% porosity. Micropores with 50–100 micrometer diameter were formed in the conduits.
In vivo application of PLGA/chitosan/HA conduits for reconstruction of 10 mm sciatic nerve defect was assessed by the walking
track analysis, the quantifying of the wet weight of tibialis anterior muscle and the histological assessment. The conduits
in host rats in vivo can not only be an effective in promoting regenerating of nerves but can also lead to favorable nerve
functional recovery.
Funded by the National Natural Science Foundation of China(No.50774096) 相似文献