CO2固化碱性酚醛树脂的制备及固化机理研究

铸造用CO2固化碱性酚醛树脂是一种新型造型、制芯用粘结剂,它是由羟甲基含量较高的甲阶碱性酚醛树脂和含氧酸盐及碱等物质组成的混合物,甲阶碱性酚醛树脂性能及它们的组成是影响CO2固化碱性酚醛树脂砂强度的主要因素。模仿实际CO2固化酚醛树脂砂的固化过程,利用测定不同条件下碱性酚醛树脂水溶液pH值变化的方法,对CO2固化碱性酚醛树脂与不同交联剂的固化机理进行了探讨,从中得出有关CO2固化碱性酚醛树脂的交联剂和碱的用量范围,并在此基础上,考察它们和表面稳定剂对砂型抗压强度的影响,获得铸造用CO2固化碱性酚醛树脂较佳组成。     

含CaO陶瓷结合剂强度的研究

本文对含CaO陶瓷结合剂的强度影响机理进行了进一步的研究。研究结果表明,含CaO结合剂的强度与结合剂的网络结构参数Y有关。CaO作为网络改变体对网络结构的破坏作用可能是使含CaO陶瓷结合剂强度降低的一个主要原因。     

新型硬齿面环面蜗杆传动研究

采用精确磨削TI蜗杆的砂轮，用类似直廓环面蜗杆或平面包络环面蜗杆的磨削方法加工环面蜗杆，使该蜗杆和齿面形状与砂轮曲面相同的蜗轮相配合，形成一种新型蜗杆传动，给出了这种传动蜗杆副齿面的数学模型，并通过计算机仿真得出了这种传动蜗轮齿面上接触线的形状及分布特征，初步分析了其啮合特点。     

呋喃树脂砂型球铁铸件异常组织分析

采用呋喃树脂砂型铸造球铁件时，由于树脂和硬化剂分解产生的C,S渗入铁液使铸件表层局部区域形成大量密集的细片状和点状过冷石墨，这些区域加工表面上呈灰暗色。在容易产生这种缺陷的部位设置冷铁．使该部位不与树脂砂接触，因而能避免上述缺陷产生。     

The Structure Stability of Carbide-Free Bainite Wheel Steel

Metallographic structures of carbide-free bainite steel wheel rim are mainly composed of supersaturated lath ferrite and retained austenite film among bainitic ferrite laths. It is suspected that supersaturated ferrite and retained austenite are likely to decompose under the influence of temperature change and mechanical stress. Stability of wheel rim structure is studied by means of x-ray diffraction, dye microscopy, and micro-hardness test. When the samples are tempered in the range of 150-350 °C, the retained austenite films are at the state of relative stability. Fifty percent of retained austenite is decomposed when the sample is tempered at 400 °C. Microhardness increases when the sample is tempered at 150 °C. The decrease in hardness is mild when the samples are tempered from 200 to 500 °C. The mechanical stability of retained austenite film is studied with tensile sample under the effect of tensile stress. The retained austenite appears to be stable in low and middle degree of deformation, and decomposition occurs at great amount of deformation. Diffraction peak of carbide is not found in all above experiments. The steel enriched silicon prevents the carbide precipitation during the transformation. It indicates the carbide-free bainite wheel steels have an excellent thermal and mechanical stability.     

杭州湾跨海大桥钢管桩的涂层防护

杭州湾跨海大桥采用钢管桩沉桩基础。钢管桩的腐蚀问题采用涂层加阴极保护的防护体系,其中涂层部分采用单层/双层/三层重防腐环氧粉末喷涂防护方案解决。介绍了三种涂层结构及其用途。     

多元酚——甲醛树脂中游离酚,游离醛含量的测定

多元酚－－甲醛树脂是本院开发的热固粘接剂新产品，本文给出了这一产品技术指标中游离酚、游离醛含量的测定方法，并对方法进行了讨论。     

含氟树脂涂料的研究进展

概述了氟树脂的发展历程及其应用研究进展;总结了不同氟树脂的结构性能特征;归纳了PFEVE和PVDF两类典型氟树脂的基本物理性能和研究开发现状;简述了水分散氟树脂体系的制备方法。     

高吸水树脂研究进展

综述了高吸水树脂的制备、结构及吸水机理,介绍了高吸水树脂国内外发展现状及其在各方面的应用,并提出了目前的主要研究趋势。     

The Structure of the Irreversibly Bound Adhesion Promoter-Substrate Interfacial Layer of γ-Aminopropylsilanetriol on Crystalline Si, as Measured by XPS and FTIR

The irreversibly bound interfacial layer deposited by the γ-aminopropysilanetriol adhesion promoter onto a crystalline silicon substrate, which remains even after profuse washing, was found by XPS to have resulted from the fragmentation and rearrangement of the original γ-aminopropylsilanetriol molecule. A mechanism is proposed, involving the homolytic scission of the terminal N-C bond. One of the subsequent reactions is believed to involve hydrogen loss by abstraction and the formation of a terminal vinyl group, which bonds to the substrate. Support for this mechanism is found in IR spectroscopy of this layer.