单元系T—p相图的数学结构

作者以化学元素的稳定单质为基准,推演出了任意物质M_i(相态Ω)的热力学生成活度{相态Ω)的函数形式:?D_Ω数值的大小体现着相态Ω的热力学相对稳定性.根据集合论原理沿D(稳定性)座标取极大值的方法把物理性质互不连续的各个异相态连结在一起,建立了单元系在T-p面上的优势分布方程(PSDE):■作者以H_2O为实例,计算了T-p相图,与实验相图基本一致.     

Estimation of Thermodynamic Properties from Binary Phase Diagram

The general relationship between binary phase diagrams and the thermodynamic properties was system-atically derived without any assumption.A procedure was presented to estimate the thermodynamic proper-ties from the binary phase diagrams.     

Determination of the liquidus lines and isotherms of the Hg-Zn-Te system by a modified direct observation method

The modified direct observation method is employed for the determination of the liquidus lines in the (Hg_{1_x}Zn_x)_{1_y}Te_y, ternary system. The liquidus temperatures of the ternary samples of various compositions withx from 0.05 to 0.30 andy from 0.5 to 0.9 are measured. The temperature-composition phase diagrams and some liquidus isotherms are established for this system.     

Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

A pure, acicular lead titanate (PbTiO₃) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO₃ with I 4 symmetry, cell parameters of a = 12.358 Å and b = 14.541 Å, and a density of 6.80 g.cm⁻³. The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO₃ under hydrothermal conditions have been investigated. The acicular PbTiO₃ with I 4 symmetry, referred to as the PX phase, can be converted to the perovskite-type (PE phase) of PbTiO₃ at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX-phase PbTiO₃ are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH₂)₃CH₃]₄) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length.     

我国力车胎行业现状与展望

介绍了2002年我国力车胎的行业现状。近年的发展及展望。并着重描述了力车胎专用设备的新发展。     

An Arctangent Unwrapping Technique of Photoelasticity Using Linearly Polarized Light at Three Wavelengths

Abstract:  In the automatic measurements of the principal stress directions ψ and the total relative phase retardation ρ _tol, ψ and ρ _tol can be easily obtained by the phase unwrapping method using the arctangent function. However, only some published works exist on the measurements of ψ and ρ _tol by photoelastic techniques using a linearly polarised incident light source. This paper presents the technique of applying an unwrapping by means of the arctangent function to photoelasticity. The technique overcomes the error associated with the quarter-wave plate by using an incident light of different wavelength and does not need an interpolation for the determination of ψ . The technique is validated by determining ψ and ρ _tol for the well-known circular disk subjected to a diametral compressive load model.     

提高K-9曲拐质量的热处理工艺

K-9曲拐质量不合格主要是由于热处理后，珠光体数量太少所引起。因此应用正交试验，合理地选择了热处理工艺参数，提高了出炉温度，增加了珠光体数量，解决了K-9曲拐的质量问题。     

Calendar maintenance of arbitrarily structured systems

A semi-Markov model is constructed that describes an arbitrarily structured multicomponent technological system and takes into account its calendar maintenance. Using an aggregation algorithm, approximate values of stationary reliability characteristics and an optimal term of maintenance work are determined for the system. __________ Translated from Kibernetika i Sistemnyi Analiz, No. 2, pp. 69–86, March–April 2006.     

1422轧机滑块式万向接轴的故障及处理

以热轧板厂粗轧主传动滑块式万向接轴为例，分析了该接轴及接轴平衡机构的常见故障及其排除方法，提出了日常维护措施。     

Phase separation studies in RIM polyurethanes catalyst and hard segment crystallinity effects

Polyurethanes were prepared from pure 4,4′-diphenylmethane diisocyanate (MDI), 1,4-butane diol (BDO) or 1,2-ethane diol (EDO) and α,ω-hydroxyl poly(propylene oxide) (PPO) by reaction injection moulding (RIM). Hard segment (MDI + BDO or EDO) level was 45–50 wt%. The PPO had about 20% ethylene oxide copolymerized in at the chain ends to provide 80% primary OH end groups. M_n was varied from 2000 to 4000. Dibutyl tin dilaurate catalyst and mould temperature were varied. Dynamic mechanical, wide-angle X-ray, differential scanning calorimeter, molecular weight and tensile elongation measurements were made on the RIM polyurethanes. At low reaction rates (low catalyst or temperature) highly crystalline, well phase separated but low molecular weight polymers were produced. At high catalyst or temperature levels more poorly phase separated but high molecular weight, tough polymers resulted. Higher M_n PPO gave better phase separation and EDO gave higher melting temperatures. Preventing hard segment crystallinity by substituting asymmetric MDI or glycols resulted in phase compatibility.