Consolidation of unidirectional CF/PEEK composites from commingled yarn prepreg

Relationships between impregnation mechanisms, consolidation quality and resulting mechanical properties of CF/PEEK thermoplastic composites manufactured from a commingled yarn system have been investigated. A small compression mould was used to apply the different processing conditions (i.e. pressure, holding time and processing temperature). The consolidation quality of finished samples was characterized mainly through microscopic studies of the microstructure of the material associated with density measurements and evaluations of mechanical properties using a small transverse flexure testing facility. A model for qualitatively describing the impregnation and consolidation processes in commingled-yarn-based thermoplastic composites was developed, which predicts variations of void content during consolidation as well as the time, temperature and pressure required to reach full consolidation. Good correlations between predictions and the experimental data indicate the success of the approach. For a desired, minimum level of void content (X_v = 0.5%), optimum processing windows for manufacturing of CF/PEEK composite parts from the commingled yarn preform are suggested.     

Diffusion Interaction during Preparation of Nanocrystalline Powders in the System ZrO2-Y2O3

The properties of ZrO₂ - 3 mole% Y₂O₃ nanocrystalline powder prepared by diffusion impregnation are studied. The original nanocrystalline powder of M-ZrO₂ is prepared with hydrothermal treatment of aqueous zirconium hydroxychloride solution by different regimes. It is found that after diffusion impregnation for all of the powders with yttrium oxide two solid solutions are formed (F-ZrO₂ and M-ZrO₂) in mixture. It is established that the morphological features typical for the original powders are retained. The efficiency of diffusion impregnation is determined by the slightly-agglomerated powder with a high degree of crystallinity.__________Translated from Poroshkovaya Metallurgiya, Nos. 3–4(442), pp. 3–11, March–April, 2005.     

地质雷达勘察坝体“散浸”

某大坝零星分布有浸水现象，利用高频电磁波在不同介质传播特征的差异，借助地质雷达勘察坝体“散浸”，从而揭示了坝体介质的富水特征及其不均匀特性，为地质论证“散浸”范围进而推断其原因提供了部分依据。     

一种微细浸染型金矿金的赋存状态研究

本文首次报导了湖北省微细浸染型金矿金的赋存状态。通过研究确定了金属于超显微粒级的不可见金,查明了金的赋存形式多样:毒砂中的金是以类质同象晶格金的形式存在,Au~(1+)替代毒砂中的Fe~(2+);粘土矿物中的金呈小园球状的次显微金和胶体金粒被吸附在水云母、高岭石晶体边缘,自然金粒度为0.02～0.35微米。此成果为研究本矿床成因,矿床综合评价和工业利用提供了可信依据。     

硫化型NiMo加氢催化剂制备与表征

以四硫代钼酸铵溶液和硝酸镍溶液为浸渍液,根据活性组分Ni和Mo浸渍顺序的不同,采用真空饱和浸渍法制备了MN系列和NM系列 NiMoS/γ-Al₂O₃催化剂。在固定床加氢中试反应装置上研究了NiMoS/γ-Al₂O₃催化剂对二苯并噻吩加氢反应的催化性能,结果表明,NiMoS/γ-Al₂O₃催化剂对二苯并噻吩加氢反应具有良好的活性和选择性。Ni助剂的加入,有利于二苯并噻吩加氢反应的活性和选择性。MN-0.3为最优NiMoS/γ-Al₂O₃催化剂。在空速10 h^-1、反应压力2.0 MPa、氢油体积比300∶1、氢气预处理温度320 ℃和反应温度300 ℃条件下,催化剂对二苯并噻吩加氢反应转化率达83.9%,加氢反应活性较高。     

Ni/YSZ and Ni–CeO2/YSZ anodes prepared by impregnation for solid oxide fuel cells

In this paper, Ni/YSZ and Ni–CeO₂/YSZ anodes for a solid oxide fuel cell (SOFC) were prepared by tape casting and vacuum impregnation. By this method, the Ni content in the anode could be reduced compared to the traditional tape casting method. It was found that adding CeO₂ into the Ni/YSZ anode by a Ni(NO₃)₂ and Ce(NO₃)₃ mixed impregnation could further enhance cell performance. This was investigated in H₂ at 1073 K. XRD patterns indicated that CeO₂ and Ni were separate phases, and the CeO₂ addition could enhance the Ni dispersion on the YSZ framework surface which was observed by SEM images. It was shown that adding CeO₂ into the Ni anodes could decrease the cell polarization resistance. The maximum power density for cells with 25 wt.% Ni, 5 wt.% CeO₂–25 wt.% Ni/YSZ, or 10 wt.% CeO₂–25 wt.% Ni/YSZ anode was 230 mW cm⁻², 420 mW cm⁻² and 530 mW cm⁻², respectively, in H₂ at 1073 K. The OCV for these cells was 1.05–1.09 V, indicating that a dense electrolyte film was obtained by co-firing porous YSZ layer and dense YSZ layer.     

分子筛杂多酸复合物的制备及其在催化反应中应用的研究进展

对浸渍法和原位合成法制备分子筛杂多酸复合物及其在催化反应中的应用进行了综述。浸渍法制备的分子筛杂多酸复合物中杂多酸在分子筛内表面高度分散,其酸强度略有降低,可作为烷基化、异构化、酯化、裂解、聚合等诸多反应的催化剂,催化活性高、选择性好,但需解决杂多酸溶脱的问题;原位合成法制备分子筛杂多酸复合物中杂多酸可有效地固定在分子筛中,目前的研究仅处于初级阶段,需对其合成机理、催化活性、多品种合成等进一步研究。     

Effects of High-Pressure Pretreatment and Calcium Soaking on the Texture Degradation Kinetics of Carrots during Thermal Processing

ABSTRACT: Carrots ( Daucus carota ) pretreated under different high-pressure conditions were thermally processed at temperatures in the range of 90°C to 110°C. Texture degradation (hardness) was monitored objectively using a texture analyzer. For a given thermal treatment, the rate constant (k-value) decreased with increasing pretreatment pressure. A high-pressure pretreatment (200 to 500 MPa) at 60°C for 15 min resulted in a more pronounced texture improvement compared with the same pretreatment at 20°C and 40°C, respectively. Calcium impregnation conferred more beneficial effects when applied immediately after the high-pressure pretreat-ment. The observed changes in texture characteristics were associated with the degree of methylation of carrot pectins, which is dependent on pectinmethylesterase (PME) activity.     

制备方法对镍催化剂重整活性的影响

利用XRD ,TPR和活性评价等手段 ,研究了NiO/γ Al2 O3 催化剂的制备方法对CH4与CO2 转化制合成气催化活性的影响。在本实验条件下 ,采用浸渍法和焙烧温度为 4 0 0℃制备的NiO/γ Al2 O3 (NiO质量分数w =0 113)催化剂 ,在反应温度为 75 0℃和空速为 2 5 0 0h 1下 ,对CH4和CO2 重整反应会显示良好的催化活性。本文还对催化剂抗积炭性能作了初步讨论。     

Enhanced cycle stability of spinel LiMn2O4 by a melting impregnation method

Spinel LiMn₂O₄ particles were successfully coated with CuO, MgO, ZnO, Al₂O₃ and CeO₂ by a melting impregnation method. Except for the CeO₂-coated sample, all the others exhibit better cycling stability than bare LiMn₂O₄ at room temperature and at 55°C. Among these samples, the ZnO-coated sample shows the best cycling stability. A capacity of 100 mA·h·g⁻¹ still remained after 100 cycles at 55°C while the bare LiMn₂O₄ retains a capacity of only 80 mA·h·g⁻¹ after the same number of cycles. The improvement in the cycling stability is attributed to the suppressed Mn dissolution caused by HF.