有机发光显示的几项新技术

有机发光显示(OLED)作为下一代显示器倍受关注。本文简要介绍OLED显示器的几项新技术和制作方法，以及其研究现状和今后的发展趋势。     

An Investigation of Milk Powders Produced by a Laboratory-Scale Spray Dryer

A mini spray dryer has been used to investigate morphological changes that occur to milk particles during the spray drying process. We have found that the mini spray dryer is ideal for such investigations, because phenomena such as skin and vacuole formation in particles can be analyzed without the added complication of particle agglomeration, which only occurs in much larger spray dryers where particle number concentrations are higher. We have confirmed observations made by various researchers that the bulk density of spray-dried milk powder is greatly affected by the drying temperature, due to the strong influence of the latter on the porosity of the particles. In addition, we have attempted to explain observations made by various workers that fat accumulates preferentially at the surface of a particle during drying by postulating that fluid fat is transported towards the surface, via a network of cracks and pores, by the development of a vacuole overpressure which is also responsible for the inflation of the particle. Finally, we have shown that milk powders can be spray dried a second time, by reconstitution with water, with no change to the thermodynamic characteristics of the resultant powder. Thus, milk concentrates for spray drying research can be prepared from already-spray-dried milk powders rather than using the more arduous evaporation method to concentrate unprocessed milk.     

Measurement of the Metal Surface Acidity/Electronegativity of Pt(110)

In previous work, it has been found that a hydrogen-covered Pt(110) surface is acidic, but quantification of the acidity has not yet been done. In this paper a spectroscopic method is developed to measure the acidity of a metal surface for the first time. The technique involves measuring the intensity of the N–H stretch from the C₅H₄XNH⁺ that forms when hydrogen coadsorbs with pyridine, 2-fluoropyridine and 3-fluoropyridine. The Bethe approximation is then used to estimate the metal surface acidity/electronegativity (MSAEL). The proton affinity/MSAEL of Pt(110) has been determined to be 907 ± 4 kJ/mol at high coverage. This is the first time the MSAEL has been measured on a metal surface. Implications for fuel cell catalysis are discussed.     

飞行时间二次离子质谱--强有力的表面、界面和薄膜分析手段

二次离子质谱（Secondary ion mass spectrometry，简称SIMS）是一种对表面灵敏的质谱技术，建立在表面各种类型带正、负电荷原子或分子发射的基础上。用飞行时间（Time of flight，简称TOF）仪器对这些二次离子进行质量分析，能确保并行质量登录、高质量范围、高流通率下的高分辨和精确质量测定这些优异性能。配合细聚焦扫描一次离子束，可在优于1nm的高深度分辨和优于50nm的横向分辨本领下，实现对表面优于单层ppm(百万分之一）量级的极高检测灵敏度。当今TOF－SIMS已发展为一种成熟且完善的表面分析技术。极高的灵敏度，再加上即使对大分子及不易挥发性分子都独具的敏感性，使它成为很多高技术领域不可缺少的分析手段，这些领域包括微电子学、化学和材料科学以至纳米技术和生命科学等。本文简述了TOF－SIMS的原理、仪器及其多方面的应用和展望。     

网格曲面中孔洞的光滑填充算法研究

三角网格模型是几何描述的一种重要形式，有着广泛的应用。但三角网络模型常常会存在孔洞缺陷。这些孔洞的存在一方面影响视觉效果，另一方面会影响许多后续的操作，如快速原型制造、有限元分析等，因此有必要对这些孔洞进行修补。目前绝大多数孔洞填充算法是将网格模型中的孔洞提取成空间多边形，并对孔洞多边形进行三角化。这种处理方法的主要缺陷是没有考虑网格曲面在孔洞附近的几何形态，因而填充部分不能与整个曲面光滑地融为一体。笔者提出了一种三角网格曲面中孔洞的光滑填充算法。该算法根据孔洞周围网格曲面的几何信息来增加孔洞内部的采样点，然后再对增加的采样点进行三角化，较好地解决了填充部分与整体曲面光滑连接的问题。     

Evaporation and Evolution of Suspended Solution Droplets at Atmospheric and Reduced Pressures

Thermal history and solute precipitation behavior of suspended solution droplets of sodium chloride (NaCl), magnesium sulphate (MgSO₄), and zirconium hydroxychloride (ZrO(OH)Cl) evaporating at atmospheric and reduced pressures are studied. Experimental measurements on the variation of droplet diameter, solution concentration, and temperature during the evaporation period are presented and discussed. The results of solute precipitation behavior in solution droplets observed under an optical microscope are displayed and discussed. Results indicate that reducing the pressure (∼ 33 kPa) results in a change in the solution droplet evaporation rate, but the thermal histories of a particular solution droplet are similar at the atmospheric and reduced pressures. At atmospheric and reduced pressures used in this study, the d² law for solution droplets is valid at early stages of the evaporation and before the solute precipitation initiates. Drying of MgSO₄ and ZrO(OH)Cl solution droplets results in the formation of spherical particles, whereas drying of spherical NaCl solution droplets results in the formation of cubic particles.     

提高曲面近似展开精度的方法与实现

通过对不可展曲面近似展开精度的研究，提出了根据曲面曲率的大小对曲面自动进行网格划分，通过对综合展开误差数据场进行数据拟合来选取最优展开基点，基于空间曲面与其展开图间近似的等距变换关系进行展开样形的误差矫正等3种方法，这几种方法的实现在不同程度上有效地减小了曲面的近似展开误差，提高了曲面的近似展开精度。     

从实例看花岗岩地基勘察的几个特点

以花岗岩类的硬质岩作为建筑物基础持力层,具有承载力高、稳定性好,抗震性强的特点,被许多重要建筑物所采用,尤其是沿海地区的高层建筑物。但往往此类基岩的层面不够“平整”,基岩层面的变化对基础的设计、施工,尤其是桩基础影响很大。本文通过对某高层建筑进行地基勘察的实例,总结了花岗岩地区风化岩层的几个特征及其在工程勘察中需注意的一些问题。     

Identification of gaps in mangrove forests with airborne LIDAR

Mangrove forests change frequently due to disturbances from tropical storms, frost, lightning, and insects. It has been suggested that the death and regeneration of trees in small gaps due to lightning may play a critical role in mangrove forest turnover; however, the large-scale quantification of spatial pattern and areas of gaps is lacking for investigating this issue. Airborne light detection and ranging (LIDAR) technology provides an effective way for identifying gaps by remotely obtaining direct measurements of ground and canopy elevations. A method based on an alternative sequential filter and black top-hat mathematical morphological transformation was developed to extract gap features. Comparison of identified gap polygons with raw LIDAR measurements and field surveys shows that the proposed method successfully extracted gap features in mangrove forests in Everglades National Park. There are 400–500 lightning gaps per square kilometer in mangrove forests at the study sites. The distribution of gap sizes follows an exponential form and the area of gaps with sizes larger than 100 m² account for 55–61% of the total area of gaps. The area of gaps in the mangrove forest in Everglades National Park is about 4–5% of the total forest area and the average gap formation rate is about 0.3% of the total forest area per year, indicating that lightning gaps play an important role in mangrove forest dynamics.