Desorption kinetics of trichloroethylene and perchloroethylene from aged dense nonaqueous phase liquid-contaminated soil

Batch experiments were conducted to investigate the desorption kinetics of a contaminated soil collected from a field site at Hill Air Force Base (AFB), Utah. The site has been contaminated with many dense nonaqueous phase liquids (DNAPLs), primarily trichloroethylene (TCE) and perchloroethylene (PCE), for more than 60 years. Similar desorptive behaviour of both TCE and PCE was observed: a stage of fast release of the contaminant at the start followed by a very slow stage. Moreover, it is suggested that not all the contaminant in the solid phase may be released to the aqueous phase, apparently due to the age factor. Local variations were observed in the effective diffusivity and other sorption-related parameters across the site due to aquifer heterogeneity. Experimental results were then simulated using a numerical code based on the intraparticle diffusion model. Good agreement was found between both results.     

Seeker optimization algorithm for global optimization: A case study on optimal modelling of proton exchange membrane fuel cell (PEMFC)

In order to optimize the proton exchange membrane fuel cell (PEMFC) model parameters, a novel approach based on seeker optimization algorithm (SOA) is proposed. The SOA is based on the concept of simulating human searching behaviors, where the choice of search direction is based on the empirical gradient by evaluating the response to the position changes and the decision of step length is based on uncertainty reasoning by using a simple Fuzzy rule. In this study, after evaluated on benchmark function optimization, the SOA is applied to optimal modelling of the PEMFC by using a fuel cell test system in Fuel Cell Application Centre (FAC) at the Temasek Polytechnic, and compared with several state-of-the-art versions of differential evolution (DE) and particle swarm optimization (PSO) algorithms. The simulation results show that the proposed approach is superior to other compared algorithms, and the PEMFC model with optimized parameters by SOA fitted experimental data well. Hence, SOA is an effective and reliable technique for optimizing the parameters of PEMFC model, and can be helpful for system analysis, optimization design and real-time control of the PEMFCs.     

A Novel Approach to Analyzing the Occupancy of the Geo/Geo/∞ Queueing System

Discrete time queueing systems have been successfully used to model packet queues in computer and digital communications systems. In this article we introduce a novel approach to analyzing the Geo^X/Geo^Y/∞ queueing system, which is suitable for modelling high speed computer and communications systems. The approach is based on characterizing the system by a functional equation which is then solved recursively to give identical results to those obtained using other approaches.     

狭缝调相式分置斯特林制冷机理论模型与模拟

自从分置式斯特林制冷机出现以来,工程设计对可靠的整机理论模型有着迫切需求。给出狭缝调相式气动分置式斯特林制冷机热动力学模型及控制方程,直线压缩机采用了绝热模型,压缩活塞的运动规律采用了试验修正,模型中考虑了活塞驱动电机运动特征和回热不完全、轴向导热、穿梭运动、气体泵热、辐射等主要冷损,排出器运动采用单自由度强迫运动模型,并运用数值计算方法模拟整机性能。该模型可用来对整机性能进行预测并帮助设计者深入理解整机物理过程。     

激光通信测距技术发展现状及趋势研究

综述了国内外激光通信技术和激光测距技术的发展现状,指出由于空间条件等的限制,激光通信和测距的复合需求不断增加,激光通信测距一体化技术将成为未来发展趋势.在此基础上,深入分析了国外激光通信测距一体化技术研究进展,最后对激光通信测距技术的前景进行了介绍.     

Improved empirical relations for estimating original oil in place recovered during microbial enhanced oil recovery under varied salinity conditions

During microbial enhanced oil recovery (MEOR) processes, the interaction between injection water (IW) and formation water (FW) salinity causes in-situ salinity variation which affects the final oil recovery. The present study explicitly quantifies the Original Oil in Place (OOIP) recovered for different IW and FW salinity conditions through numerical simulation. Based on simulation results, user-friendly empirical correlations were deduced to quickly estimate the OOIP. The results suggest that the OOIP increases drastically in all reservoirs with any initial FW salinity as the adopted salinity of IW is lowered. The study would serve as a tool for making reservoir management decisions.     

BURIAL HISTORY AND THERMAL MATURITY EVOLUTION OF THE TERMIT BASIN,NIGER

Reconstruction of the burial history and thermal evolution of the Cretaceous – Tertiary Termit Basin, a sub‐basin within the larger Eastern Niger Basin of Niger, indicates spatially and temporally variable conditions for organic matter maturation during the basin's multi‐phased evolution. Three episodes of tectonic subsidence which correspond to the observed fault mechanical stratigraphy within the Termit Basin are identified: Late Cretaceous, Maastrichtian to early Paleocene, and Oligocene. These episodes fall within the regional tectonic phases of the West African Rift System delineated by previous studies. The basin exhibits substantial heterogeneity in the magnitude of the tectonic episodes and in consequent thermal maturities. For this paper, 1D burial and thermal histories of eight widely dispersed wells in the Agadem permit area in the SW of the Termit Graben were modelled to investigate the maturation of organic matter in source rocks ranging from Santonian to Oligocene in age. The kinetic modelled maturities match with maturities based on Rock‐Eval T_max values for four wells if present‐day heat flows are elevated. Future exploration strategies in the Termit Basin should take into consideration these heterogeneities in thermal histories and tectonic pulses, which may lead to the development of hydrocarbon accumulations with different oil‐gas compositions in different reservoir compartments.     

分子电子结构的造型系统

本文叙述了一个实用的分子电子结构的造型系统,用来辅助研究分子内部的微观状态(如电子波函数、电荷密度、静电势和空间的分布等)。该造型系统将在VAX-11/780上得到的分子轨道计算结果在微机仿真图形工作站用三维网格图和云雾状点图表示出来。它为研究分子内部电子结构以及新材料的设计提供了有效的辅助工具。本文以抗肿瘤药物分子为研究对象,取得了初步结果。     

FACIES HETEROGENEITIES IN A RAMP CARBONATE RESERVOIR ANALOGUE: A NEW HIGH‐RESOLUTION APPROACH FOR 3D FACIES MODELLING

In contrast to the conventional view that facies distribution patterns on carbonate ramps are relatively simple, outcrop analogue studies point to a high degree of internal facies complexity. Depending on the diagenetic overprint, this complex pattern may result in reservoir compartmentalization due to the presence of interflow baffles. The often subseismic scale heterogeneities may not be included in conventional reservoir modelling. In order to evaluate how facies heterogeneities in shoal reservoirs can be modelled realistically, this paper presents a facies modelling workflow which includes a new approach to the design of training images for multiple‐point statistics (MPS). The workflow was developed in the course of a reservoir outcrop analogue study of a Ladinian (Middle Triassic) coquinadominated shoal complex in SW Germany which was deposited on an epicontinental, gently inclined carbonate ramp. The data set was based on an intensive field study and includes 3D facies and sequence stratigraphic analyses of the largest shoal complex in the Quaderkalk Formation (Upper Muschelkalk). This several metre thick shoal complex represents a subseismic scale, bioclast‐rich reservoir analogue and has a very heterogeneous facies pattern. Integrating 1D facies logs and sequence stratigraphic trends from tens of outcrop sections and cores, two nested 3D geocellular facies models were produced: (i) a large‐scale (30 × 30 km) model based on truncated Gaussian simulation (TGS); this formed the basis for (ii) a smaller‐scale (10 × 10 km), more detailed model based on multiple point statistics. In addition, a new approach for training image design was developed to honour small‐scale sequence stratigraphic trends and lateral facies patterns observed in modern analogues. Compared to facies patterns in modern analogues, the large‐scale model presents geologically‐feasible facies distribution patterns and geometries, and in addition shows a vertical facies distribution which is similar to the observed sequence stratigraphic architecture of the outcrop data‐set used. Due to the new training image design, the final small‐scale model has a distribution pattern of facies heterogeneities which looks similar to modern facies distributions in the offshore UAE and thus represents a valuable method of producing realistic reservoir facies models. The modelling workflow and the new approach for training image design presented will help to reduce uncertainties in the understanding and modelling of subsurface reservoirs by using a systematic combination of outcrop data and modern analogues, with the consistent application of sequence stratigraphic principles. In addition, this study emphasises the importance of careful training image design, derived from modern analogues, which can be used as realistic inputs in order to optimize multiple point simulations, and which may be applied to producing bioclastic reservoirs such as those located on the Arabian Plate or offshore Brazil.     

2D BASIN MODELLING IN THE EASTERN VARISCAN FOLD BELT (CZECH REPUBLIC): INFLUENCE OF THRUSTING ON PATTERNS OF THERMAL MATURATION

This study evaluates the geothermal history of Palaeozoic sedimentary rocks from the easternmost part of the Variscan external zone in the NE Czech Republic. The objective was to investigate the geothermal history of pre‐Variscan Palaeozoic carbonates in the study area, and to assess its relationship with that of the overlying Variscan flysch. In the study area, the Palaeozoic succession occurs at the surface or is overlain by Miocene sediments of the Carpathian Foredeep. Palaeozoic nappes and the main Variscan overthrust have been documented in the subsurface at the deep Pot?tát‐1borehole. Vitrinite reflectance measurements on 38 samples from the Pot?tát‐1 well and 19 samples from nearby surface outcrops and shallow boreholes were available. A 2D thermal model was created using PetroMod and the thermal maturity evolution was modelled by EASY%Ro. The thermal model was constructed based on interpretations of two NW‐SE seismic profiles (lines 5/83 and 5/84) oriented perpendicular to the main Variscan thrusts. The results were calibrated using measured vitrinite reflectance and were adjusted with 1D models from three shallow boreholes. At the Pot?tát‐1 borehole, modelled maximum palaeo‐temperatures of the Variscan flysch (Moravice Formation) ranged from 310°C at a depth of 7.3 km (the top of the preserved succession) to 395°C at the base of the succession, resulting in thermal maturities of >4%R_r. Peak maturation occurred prior to the end of Variscan thrusting. Modelling suggests that the basal heat flow for these thrust units reached a maximum value of 63 mW/m² at 325 Ma. In addition, the modelling suggests that the maturity of the Palaeozoic carbonates was controlled by the thickness of the overlying Variscan flysch nappes. Maximum palaeo‐temperatures for the Palaeozoic carbonates ranged from 265°C at the top of the interval (at a depth of 7.1 km) to 290°C at the base, resulting in a maturity of 3.8 to >4%R_r which is within the dry gas window. The study suggests that basal heat flows in the original (pre‐thrust) Early Carboniferous sedimentary basin were slightly higher than those in the post‐thrust location for the Variscan flysch nappes. This should be taken into account when evaluating the petroleum system in the South Moravian oil province (SW Czech Republic) where a complete sedimentary sequence has not been preserved.