Systems processed by thermoplastic extrusion can be regarded as heterophase polymer melts of incompatible water-plasticized
biopolymers. In the process of thermoplastic extrusion, proteins and polysaccharides are melted at high pressure and temperature
below the temperature region of their thermal decomposition. Dispersed particles of these systems can be deformed in flow.
The mixed-melt anisotropic structure, formed in flow, is fixed by rapid conversion of the melt jet that lets the extruder
die from a viscous state to a rubber-like state and then to a glassy state caused by cooling and drying. Incompatibility of
proteins and polysaccharides in their water-plasticized melt mixtures impacts on structure formation and texturization during
thermoplastic extrusion.
Presented at the 20th ISF World Congress and 83rd AOCS Annual Meeting and Expo, May 10–14, 1992, Toronto, Ontario, Canada. 相似文献
Summary: Segmented block copolymers, consisting of non‐polar soft segments from hydroxyl‐terminated liquid natural rubber (HTNR) and polar hard segments from α,ω‐diisocyanato telechelics obtained by “criss‐cross”‐cycloaddition, have been synthesized. The block copolymer formation took place under relatively mild reaction conditions at 80 °C in dichloroethane in the presence of dibutyltin dilaurate as a catalyst. The resulting block copolymers were characterized by spectroscopic techniques (1H NMR, FTIR, UV‐vis spectroscopy) as well as GPC for molar mass determination. The block copolymers were compression molded in a hot stage press, and the resulting samples were characterized by DSC and stress‐strain measurement. The solubility and phase morphology of the materials have also been studied.
Segmented block copolymer from HTNR and α,ω‐diisocyanato telechelics 相似文献