Effect of Thickness on the Structure and Tribological Properties of MoSx Coating

MoSx coatings were prepared by bipolar-pulse DC unbalanced magnetron-sputtering system with the variation of coating thickness at different Ar pressures.The composition and surface morphology were determined by using energy dispersive X-ray and scanning electron microscopy;the structural characterization was analyzed by X-ray diffraction.The friction and wear properties were investigated by fretting tests in air with less than 10% and 50% relative humidity.At 0.40 Pa pressure,(002) basal plane orientation was formed throughout the coatings.At 0.88 Pa and 1.60 Pa pressures,(002) basal plane orientation was only noticed in the first stage of coating growth(around 0.20 μm in thickness), and then edge orientations with their basal planes perpendicular to the surface would be evolved in the coatings.Humidity has a minor influence on the coatings that have(002) basal plane orientation,whereas the tribological properties of MoSx coatings with edge orientations are greatly affected by humidity.The mechanisms of coating growth and friction and wear processes are discussed.     

Stress in Thin Films;Diffraction Elastic Constants and Grain Interaction

Untextured bulk polycrystals usually possess macroscopically isotropic elastic properties whereas for most thin films transvers isotropy is expected,owing to the limited dimenionlity .The usually applied models for the calculation of elstic constants of polycrystals from single crystal elastic contants(so-called grain interaction models)erroneously predict macroscopic isotropy for an(untextured) thin film.This paper presents a summary of recent work where it has been demonstrated for the first time by X-ray diffraction analysis of stresses in thin films that elastic grain interaction can lead to macroscopically anisotropic behaviour (shown by non-linear sin^2φ plots).A new grain interaction model,predictin the macroscopically anisotropic behaviour of thin films,is proposed.     

油藏条件下饱和度测井解释

石油，天然气勘探开发过程中的油气储层划分和油气储量评估主要依赖于油层原始含油饱和度及其它储层参数，评价油层原始含油饱和度主要有岩心直接测定，测井解释、毛管压力计算三种方法。其中计算饱和度最常用方法是电性模型(即Archic公式)，岩电实验是其基础(获得胶结指数Ⅲ和饱和度指数等)。为了得到油(气)藏真实的饱和度数据，实验室岩电测量应尽可能在接近油(气)藏条件下进行，这些条件主要包括：温度、压力、毛管压力及流体分布平衡、润湿性等。     

固相反应和离子注入制备硅化镍薄膜

采用固相反应和镍离子注入硅方法分别制备了硅化镍薄膜,利用卢瑟福背散射谱(RBS),X射线衍射(XRD)和喇曼光谱对它们的成分和结构进行了表征.结果表明固相反应方法中,硅化镍薄膜的相结构取决于不同的热退火条件,纯相的NiSi2薄膜需要在高温(1123K)下两步热退火才能获得.而利用离子注入方法,则可以在较低温度(523K)下直接得到单相的NiSi2薄膜.在30～400 K范围内测量了它们的电阻率和霍尔迁移率随温度的变化关系,结果表明固相反应制备的NiSi和NiSi2薄膜都表现出典型的金属性电导行为,而离子注入制备的NiSi2薄膜则表现出完全不同的电学性质.