坨五站中间乳化层快速增长原因及治理方案

胜利采油厂坨五站高含水(95％)原油化学预脱水中，二级沉降罐内油水相之间的中间乳化层增长迅速，引起了一系列问题。现场调查和大量室内测试结果表明，产生这一现象的原因有：油溶性破乳剂WD-1加入点不合理。有2／3的含水原油在通过油水分离器之后才与破乳剂混合；二级沉降罐进油口伸入油相内，油流的冲击达不到中间层；WD-1对坨五站混合原油中的稠油破乳脱水性能欠佳，不能适应坨五站混合原油组成和含水的变化。针对上述各种原因筛选出了性能更好的一种破乳剂1916。根据确定的几种原因采取了相应的措施：将破乳剂加入点改在3个并联油水分离器之前；将二级沉降罐的进油口移到水相内；改用筛选出的破乳剂1916，结果使中间乳化层的增长受到了抑制。图2表4参2。     

溶液中微量甲基异丁基酮的分析方法

研究了微量甲异丁基酮在氟氧铌酸（H2NbOF5)及氟钽酸（H2TaF7)溶液中存在的形式，找到利用碘仿-硫代硫酸钠联合滴定的方法，来标定微量甲基异丁基酮在H2NbOF5及H2TaF7溶液中的含量，本方法在钽铌冶炼过程中操作简便易行且结果重现性好。     

Behaviour of ±45° glass/epoxy filament wound composite tubes under quasi-static equal biaxial tension–compression loading: experimental results

The primary aim of this paper is to present results describing in detail the behaviour of ±45° E-glass/MY750 (GRP) tubes, of various wall thicknesses, subjected to equal biaxial tension–compression loading, generated under combined internal pressure and axial compression. The role played by the non-linear lamina shear has also been assessed by comparing various shear stress–strain curves for embedded laminae (extracted from tests on ±45° tubes subjected to circumferential: axial stress ratios SR=1:0, 1:−1 and 2.3:−1) with that of an ‘isolated’ lamina (measured from torsion of 90° tubes). Extracted shear failure strains, for embedded laminae, were more than four fold larger than those measured at ultimate failure for an ‘isolated’ lamina. Soft characteristics were observed in the embedded lamina and these were believed to be due to interaction between early matrix damage initiation (and propagation) and shear. Factors affecting the behaviour of the tubes, such as bulging, scissoring, thermal stresses and stress variation through the thickness are discussed.     

Adsorption of H2S or SO2 on an activated carbon cloth modified by ammonia treatment

The aim of this research is to investigate how ammonia treatment of the surface can influence the activity of a viscose-based activated carbon cloth (ACC) for the oxidative retention of H₂S and SO₂ in humid air at 25 °C. Surface basic nitrogen groups were introduced either by treatment with ammonia/air at 300 °C or with ammonia/steam at 800 °C. The pore structure of the samples so prepared was examined by adsorption measurements. Changes in the surface chemistry were assessed by X-ray photoelectron spectroscopy, X-ray absorption spectroscopy and temperature programmed desorption (TPD). The change of ACC activity could not be merely attributed to surface nitrogen groups but to other changes in the support. Ammonia/steam treatment improved ACC performance the most, not only by introducing nitrogen surface groups, but also by extending the microporosity and by modifying the distribution of surface oxygen groups. Successive adsorption-regeneration cycles showed important differences between oxidative retention of H₂S and SO₂ and the subsequent catalyst/support regeneration process.     

Surface structural change of ZnO-coated LiNi0.5Mn1.5O4 spinel as 5 V cathode materials at elevated temperatures

LiNi_0.5Mn_1.5O₄ powder was synthesized via sol-gel method and coated with ZnO in order to test the electrochemical cyclability of the material as a cathode for the secondary Li battery in the 5 V range at 55 °C. The ZnO-coated LiNi_0.5Mn_1.5O₄ powder nearly maintained its initial capacity of 137 mA h g⁻¹ after 50 cycles whereas the uncoated powder was able to retain no more than 10% of the initial capacity after 30 cycles. TEM analysis of the cycled cathodes suggests that the formation of the graphitic surface phase, hindering the Li migration, may be responsible for the rapid capacity loss of the uncoated material while no such phase was observed on the surface of the ZnO coated LiNi_0.5Mn_1.5O₄ powder.     

正压冲固基础海洋平台冰激振动动力响应

正压冲固基础海洋平台是一种新型平台桩基结构形式。采用三维有限元的数值分析方法,建立了正压冲固平台的三维有限元模型。基于冰激强迫振动理论提出动冰载荷的计算方法,根据海冰破碎长度和冰速确定冰载周期,冰强度限制的水平冰力作为冰力峰值,得到的动冰载荷用于正压冲固平台的动力响应分析,并依照规范计算了6倍桩径处刚性固定时的动力响应。三维有限元方法计算得到的动力响应大于6倍桩径刚性固定时的计算结果,结构安全性评估偏于安全。     

Electron transport in InGaO3(ZnO)m (m=integer) studied using single-crystalline thin films and transparent MISFETs

We have investigated the characteristics of transparent metal-insulator-semiconductor field-effect transistors (MISFETs) fabricated using InGaO₃(ZnO)_m (m=integer) single-crystalline thin films as n-channel layers and amorphous alumina as gate insulator films. The MISFETs exhibit good characteristics such as insensitivity to visible light illumination, off-current as low as ∼1 nA with a positive threshold voltage of ∼3 V and on/off current ratio of 10⁵. The field-effect mobility increased from ∼1 to ∼10 cm² (V s)⁻¹ as the m-value increased. Room temperature Hall mobility also increased. However, unexpectedly these values were lower than the field-effect mobility. It is explained by existence of shallow localized state in the homologous compounds.     

五轴铣削加工中心坐标转换数学模型的建立及应用

首先以 HERMLE C1200 U 为例分析了五轴铣削加工中心的基本结构,然后据此给出了涉及多轴铣削加工中心后置处理角度分配和坐标变换的数学模型,最后介绍了以此数学模型为核心,为UG 软件开发的后置处理软件 UG-HERP1.0的解决方案。     

Numerical Modeling of Silicon Photodiodes for High-Accuracy Applications Part I. Simulation Programs

The suitability of the semiconductor-device modeling program PC-1D for high-accuracy simulation of silicon photodiodes is discussed. A set of user interface programs optimized to support high-accuracy batch-mode operation of PC-1D for modeling the internal quantum efficiency of photodiodes is also described. The optimization includes correction for the dark current under reverse- and forward-bias conditions before calculating the quantum efficiency, and easy access to the highest numerical accuracy available from PC-1D, neither of which is conveniently available with PC-1D’s standard user interface.