共聚物水凝胶的合成及其溶胀性能研究

以过氧化二苯甲酰(BPO)为引发剂，合成了N-乙烯基吡咯烷酮(NVP)-甲基丙烯酸肛羟乙酯(HEMA)-甲基丙烯酸丁酯(BMA)共聚物水凝胶，可作为软性角膜接触镜材料。探讨了不同比例的NVP、HEMA、BMA对材料溶胀性能的影响。     

基于贝叶斯模型加权平均方法的水文模型不确定性分析

贝叶斯模型加权平均（BMA）方法是通过综合几个模型预报值的后验分布来推断预报量的更可靠概率分布分析工具。它不仅能提供一个综合的预报值,还能提供一个综合的预报区间。本文采用3个水文模型,统一用SCE-UA算法率定参数,得到3组不同的预报值用于BMA方法的综合,着重分析比较BMA和单个模型的预报不确定性区间,来检验贝叶斯模型加权平均方法是否能提高预报的可靠性。结果表明,BMA方法不仅能提高预报精度,还能推求出性质更为优良的预报区间,提高预报的可靠性。     

BMA系列射频同轴连接器插座簧片结构的改良

通过对BMA系列射频同轴连接器插座的簧片结构进行改良,使产品经过500次寿命试验后,仍具有稳定的分离力,提高产品的可靠性。     

基于颜色融合的交互式图像二次着色方法*

针对灰度图像彩色化技术应用于彩色图像二次着色时往往忽略掉原始图像所带的色彩信息的问题,提出了一种基于最短距离颜色融合的交互式彩色图像二次着色方法,通过有效利用原始图像中的色彩信息降低用户交互复杂度。计算过程中采用分层采样与随机采样相结合的策略,确保种子像素合理分布,在颜色融合过程中增加动态权值调整,减少笔画位置对着色结果的影响。实验结果说明该方法与现有颜色扩展着色方法相比较,其结果不再过度依赖于初始用户标记的位置,不需要用户进行复杂的彩色线条标记就能够得到不错的着色效果。     

Self-diffusion in Solutions of Carboxylated Acrylic Polymers as Studied by Pulsed Field Gradient NMR. 1. Solvent Diffusion Studies

The diffusion constants of solvent in solutions of carboxylated acrylic random copolymers in isopropanol (IPA) have been investigated using the PFG NMR technique. The copolymers are composed of butyl methacrylate and methacrylic acid with a range of molar ratios (BMA/MAA 100/0 through to 60/40 in 10 mol% steps). It was found that the echo attenuation function depended on the diffusion time, and experiments with short and long diffusion times have been analysed separately. Two questions are addressed: the first concerns the influence of concentration on the polymer aggregation in solution, and the second concerns the influence of the BMA/MAA molar ratio on the diffusion constants of the solvent. The data obtained have been discussed using established physical models for diffusion. Using the model of Wang gave the relative mass of bound solvent per mass of polymer which increased with the mol% of MAA in the copolymer.     

棉纤维-甲基丙烯酸丁酯的合成工艺

研究以甲基丙烯酸丁酯(BMA)为单体,以H2O2-Fe2+为引发剂对棉纤维接枝的工艺。接枝产品的SEM表征证明此工艺可以使BMA接枝到棉纤维上。采用正交试验来确定各试验因素对接枝效果的影响,数据分析显示:时间、FeSO4、温度三因素对接枝效果的影响作用较大,而BMA、PVA、H2O2对接枝效果的影响作用则较小。经试验分析和实际验证后确定棉纤维接枝BMA的最佳工艺条件为:在预处理工艺一定时,各试验因素分别取80min、0.05g、40℃、2mL、0.35g、1mL。     

Synthesis of well-defined star-branched polymers by stepwise iterative methodology using living anionic polymerization

This article reviews the synthesis of regular and asymmetric star-branched polymers with well-defined structures by methodologies using living anionic polymerization, especially focusing on the synthetic approaches accessible for precisely controlled architectures of star-branched polymers concerning molecular weight, molecular weight distribution, arm number, and composition. The reason for selecting living anionic polymerization from many living/controlled polymerization systems so far developed is that this living polymerization system is still the best to meet the strict requirements for the precise structures of star-branched polymers. Furthermore, we herein mainly introduce a novel and quite versatile stepwise iterative methodology recently developed by our group for the successive synthesis of many-armed and multi-compositional asymmetric star-branched polymers. The methodology basically involves only two sets of the reaction conditions for the entire iterative synthetic sequence. The reaction sequence can be, in principle, limitlessly iterated to introduce a definite number of the same or different polymer segments at each stage of the iteration. As a result, a wide variety of many-armed and multi-compositional asymmetric star-branched polymers can be synthesized.     

Preparation of organic–inorganic nanocomposites with core‐shell structure by inorganic powders

Organic–inorganic nanocomposites with core‐shell structure were prepared in two steps. In the first step, the latex particles in the semibatch emulsion polymerization of butyl methacrylate (BMA), in the presence of methacrylic acid (MAA), were prepared. Small amounts of acrylic acid incorporated into the latex to have better interaction between the surface of particles and inorganic phase. MAA also increased the latex stability and decreased the amount of coagulum. In the second step, the core‐shell structures were prepared by coating the latex particles with three types of inorganic powders. Pectin coated precipitated calcium carbonate, alumina, and silica. The examinations show that pectin‐coated calcium carbonate has the best response than other types of calcium carbonate. Alumina was the second type of inorganic powder that was used for coating the core particles. Silicagel and fumed silica (Aerosil) were used for coating by silica. Scanning electron microscopy and transmission electron microscopy showed the particle morphology and the core‐shell structure, respectively. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci, 2006     

甲基丙烯酸正丁酯（BMA）的聚合及动力学研究

研究了以4-氰基戊酸二硫代苯甲酸为链转移剂的甲基丙烯酸正丁酯（BMA）的RAFT聚合动力学,聚合物通过1HNMR和GPC来表征。制得的BMA均聚物可作为大分子链转移剂。