纳米SiO_2与有机物分子的亲和性和分散性

介绍纳米SiO2的合成和粒子表面的粗糙形貌以及纳米粒子链具有类似高分子链的弹性力学属性,研究纳米SiO2的亲合性,探讨亲合性对纳米SiO2的分散、改性、应用的影响。研究表明,在极性外加剂(如乙二胺、乙二醇、PEG、PDMS、PTHF、PMMA、PBMA等)存在的情况下,纳米SiO2的弹性粒子链和硅烷醇对SiO2的分散和改性具有显著的影响。带有大烷基侧链的高分子链与SiO2表面的亲合能较低,而带有官能团的高分子链与SiO2表面具有较高的亲合性。     

Frequency domain solution to delay-type Nehari problem

This paper generalizes the frequency-domain results on the delay-type Nehari problem in the stable case to the unstable case. The solvability condition of the delay-type Nehari problem is formulated in terms of the nonsingularity of three matrices. The optimal value γ_opt is the maximal γ∈(0,∞) such that one of the three matrices becomes singular. All sub-optimal compensators are parameterized in a transparent structure incorporating a modified Smith predictor.     

Catalytic reduction of N2O with CH4 and C3H6 over Ag–Rh/Al2O3 bimetallic catalyst in the presence of oxygen

A study of nitrous oxide (N₂O) reduction with methane (CH₄) and propene (C₃H₆) in the presence of oxygen (5%) over Ag/Al₂O₃, Rh/Al₂O₃ and Ag–Rh/Al₂O₃ catalysts, with Ag and Rh loadings of 5 wt% and 0.05 wt% respectively, has been performed. From the results, it was observed that the Ag–Rh bimetallic catalyst was the most active for both nitrous oxide removal (more than 95%) and hydrocarbon oxidation. This high activity seems to be connected with a synergistic effect between Ag and Rh. The findings from X‐ray diffraction and X‐ray photoelectron spectroscopy studies showed also, that there were no strong interactions (eg alloying) between Ag and Rh. Copyright © 2005 Society of Chemical Industry     

Study on Hot Deformation Cracks of Steel D2 Using Procesing Map

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利用多普勒信息的波达方向最大似然估计方法

为了充分利用信号的时域特性来改善信号波达方向（ＤＯＡ）的估计性能，本文从最大似然估计出发，推导出了有限快拍，低信噪比情况下多普勒信号波达方向的迭代估计计算法，为进一步减小运算量，本文还推导了一种简化算法，本文提出的两种算法对低信噪比，少快拍数下多普勒信号的ＤＯＡ估计性能比不利用时域特性的ＭＬ方法有明显改善，Ｍｏｎｔｅ－Ｃａｒｌｏ实验验证了本文方法的有效性。     

Exchange and oxidation of CO on O-predosed Rh---Al2O3 and Rh---CeO2 catalysts

Exchange and oxidation of C¹⁶O were investigated at 450°C on ¹⁸O-predosed Rh and Pt catalysts supported on A1₂O₃, CeO₂ and CeO₂-Al₂O₃. In all cases, a rapid exchange of C¹⁶O with the surface can be observed. CO oxidation leads to C¹⁶O₂, C¹⁶O¹⁸O and C¹⁸O₂. Significant formation of C¹⁶O₂ is due to the relatively high ¹⁶O coverage in reaction resulting from the C¹⁶O exchange and from an exchange between O surface species and ¹⁶O internal atoms. Hydrogen is also formed via a water-gas shift reaction (CO + surface OH) in higher proportion on CeO₂-containing catalysts than on A1₂O₃. Chlorine inhibits all the reactions (exchange, oxidation and WGS) and particularly the internal exchange.     

2,4-二氯氟苯的合成

论述了2，4－二氯氟苯合成的新方法。以对氯硝基苯为起站原料，经氟化反应、硝化反应及氯化反应制得2，4-二氯氟苯，总收率达59．0％。本合成路线工艺简单、操作安全、原料易得、成本低廉，适合于工业化生产。     

CRC计算方法的研究

本文丛面地介绍了ＣＲＣ的基本原理和计算方法，并给出了编程实例。     

Catalytic oxidation of sulfide ions over nickel hydroxides

The catalytic sulfide ion oxidation by oxygen to elemental sulfur over β-Ni(OH)₂ and LiNiO₂ has been studied. As a result of experimental investigation performed, a reaction mechanism is suggested which involves heterogeneous and homogeneous processes. Dioxygen activation in the heterogeneous process proceeds via a redox Ni²⁺ ↔ Ni³⁺ transition and participation of OH⁻ groups. The active HO⁻₂ species thus formed carries on the reaction in homogeneous phase. Nickel hydroxides are promising catalysts for practical application.