离子色谱法测定城市生活垃圾渗沥水中阴离子

介绍了离子色谱法测定城市生活垃圾渗沥水中的阴离子(氯离子、亚硝酸根离子、硝酸根离子、磷酸根离子和硫酸根离子).避免了样品中复杂组分对分析体系的干扰及对色谱系统的污染,该方法快速、灵敏、准确.当以10mmol/LNa2CO3作淋洗液,流速为1.0mL/min时,分离效果良好,阴离子的检出限分别为0.18,0.45,0.67,1.02和0.85mg/L,回收率为95.85%～106.5%.     

Poly(ethylene oxide)–LiX rubbery electrolytes with X–X disulfonamide anions having two or three ether groups in their structures

This work deals with poly(ethylene oxide), PEO–MX (M=Li, K and Cs) amorphous electrolytes with ⁻X–X⁻, [CF₃SO₂NCH₂(CH₂OCH₂)₂CH₂NSO₂CF₃]²⁻ (EDSA) and [CF₃SO₂NCH₂CH₂(CH₂OCH₂)₃CH₂CH₂NSO₂CF₃]²⁻ (TTSA) disulfonamide anions. These dianions have X⁻ end-groups identical to anions [CF₃SO₂N(CH₂)₂OCH₃]⁻ (MESA) and [CF₃SO₂N(CH₂)₃OCH₃]⁻ (MPSA), one of which (MPSA) was reported to yield chelate-like associated species (presumably LiX₂⁻ triplets) at concentrations above EO/Li=20 in PEO. This feature of LiMPSA, evidenced through glass transition temperature (T_g) measurements, does not apply to Li₂EDSA and Li₂TTSA. Though none of these lithium salts form crystalline intermediate compounds with PEO, the limit of solubility of LiMESA (EO/Li=16) does not allow a clarification of this point for this salt. At lower concentrations, however, a conductivity comparison with the potassium and caesium salts shows that the apparent degree of dissociation (=C_Li+/C_Li) of LiMESA is comparable to that of LiMPSA. As opposed to both these salts and to some extent to Li₂EDSA, a much greater dissociation takes place for Li₂TTSA, the anion of which contains an inner, third ether group in its structure.     

Progressively Type-II censored competing risks data from Lomax distributions

A competing risks model based on Lomax distributions is considered under progressive Type-II censoring. Maximum likelihood estimates for the distribution parameters are established. Moreover, the expected Fisher information matrix is computed and optimal Fisher information based censoring plans are discussed. In particular, it turns out that the optimal censoring scheme depends on the particular parametrization of the Lomax distributions.     

A unified view on lifetime distributions arising from selection mechanisms

In this paper, we formulate a flexible density function from the selection mechanism viewpoint (see, for example, Bayarri and DeGroot (1992) and Arellano-Valle et al. (2006)) which possesses nice biological and physical interpretations. The new density function contains as special cases many models that have been proposed recently in the literature. In constructing this model, we assume that the number of competing causes of the event of interest has a general discrete distribution characterized by its probability generating function. This function has an important role in the selection procedure as well as in computing the conditional personal cure rate. Finally, we illustrate how various models can be deduced as special cases of the proposed model.     

The relationship between organizational culture and the deployment of agile methods

Context

Systems development normally takes place in a specific organizational context, including organizational culture. Previous research has identified organizational culture as a factor that potentially affects the deployment systems development methods.

Objective

The purpose is to analyze the relationship between organizational culture and the post-adoption deployment of agile methods.

Method

This study is a theory development exercise. Based on the Competing Values Model of organizational culture, the paper proposes a number of hypotheses about the relationship between organizational culture and the deployment of agile methods.

Results

Inspired by the agile methods thirteen new hypotheses are introduced and discussed. They have interesting implications, when contrasted with ad hoc development and with traditional systems development methods.

Conclusion

Because of the conceptual richness of organizational culture and the ambiguity of the concept of agility the relationship between organizational culture and the deployment of agile systems development forms a rich and interesting research topic. Recognizing that the Competing Values Model represents just one view of organizational culture, the paper introduces a number of alternative conceptions and identifies several interesting paths for future research into the relationship between organizational culture and agile methods deployment.     

Theory and Applications of Hazard Plotting for Censored Failure Data

This paper presents theory and applications of a simple graphical method, called hazard plotting, for the analysis of multiply censored life data consisting of failure times of failed units intermixed with running times on unfailed units. Applications of the method are given for multiply censored data on service life of equipment, for strength data on an item with different failure modes, and for biological data multiply censored on both sides from paired comparisons. Theory for the hazard plotting method, which is based on the hazard function of a distribution, is developed from the properties of order statistics from Type II multiply censored samples.     

Utility based maintenance analysis using a Random Sign censoring model

Industrial systems subject to failures are usually inspected when there are evident signs of an imminent failure. Maintenance is therefore performed at a random time, somehow dependent on the failure mechanism. A competing risk model, namely a Random Sign model, is considered to relate failure and maintenance times. We propose a novel Bayesian analysis of the model and apply it to actual data from a water pump in an oil refinery. The design of an optimal maintenance policy is then discussed under a formal decision theoretic approach, analyzing the goodness of the current maintenance policy and making decisions about the optimal maintenance time.     

Influence of dams on river water‐quality signatures at event and seasonal scales: The Sélune River (France) case study

Dams and reservoirs are known to disturb river‐water composition, among other impacts, with potential implications for downstream river ecosystems and water uses. Existing studies have emphasized the variable influence of dams on water composition according to the element, its speciation (dissolved vs. particulate), reservoir properties (residence times), reservoir functions (e.g., hydropower, irrigation), and management (water releases). A now common approach to analyzing hydrological, geochemical, and biological controls on element export from unregulated rivers is to study hydrochemical signatures such as concentration‐flow relationships. We investigated a case study to analyze hydrochemical signatures of a regulated river (Sélune River, western France) upstream and downstream of a chain of two hydropower dams, assuming that the dams disturbed the river's signatures, and that those disturbances would provide information about processes occurring in the reservoirs. Both seasonal and event‐scale signatures were analyzed over two contrasting hydrological years and a range of storm events. The dams induced a chemostatic downstream response to storm events whenever elements were diluted or concentrated upstream. Dams did not disturb the seasonality of major anions but did modify silica and phosphorus concentration‐flow relationships, especially during low flow. Such changes in dynamics of river‐water composition may affect downstream biological communities. This study presents an initial state of the hydrochemical signature of the downstream river, before the removal of the two dams.     

Theory and Applications of Hazard Plotting for Censored Failure Data

This paper presents theory and applications of a simple graphical method, called hazard plotting, for the analysis of multiply censored life data consisting of failure times of failed units intermixed with running times on unfailed units. Applications of the method are given for multiply censored data on service life of equipment, for strength data on an item with different failure modes, and for biological data multiply censored on both sides from paired comparisons. Theory for the hazard plotting method, which is based on the hazard function of a distribution, is developed from the properties of order statistics from Type II multiply censored samples.     

炉水中侵蚀性阴离子对碳钢腐蚀的试验研究

为了研究低磷酸盐—低氢氧化钠水处理工艺下侵蚀性阴离子对碳钢的腐蚀 ,通过高压釜静态试验 ,计算在不同浓度下碳钢的腐蚀速度 ,测定溶液中总铁离子浓度以及对表面的 EPMA(Electron probe microanalysis,电子探针微量分析 )分析。结果表明 :高温下 ,Cl-、SO42 -是引起碳钢腐蚀的主要原因。它们能阻碍膜的形成。随着离子浓度的增大 ,当 CCl- >0 .4m g/L 时 ,碳钢的腐蚀速率明显增加 ,蚀孔增多 ,耐蚀性能降低