Unique structural and magnetic traits of Nd3+-substituted Co–Zn nanoferrites

Because of the technological potential of magnetic spinel nanoferrites, we prepared neodymium ion (Nd³⁺)-substituted cobalt-zinc ferrites (CZFs) with the form Co_0.5Zn_0.5Nd_xFe_2–xO₄ (0.0 ≤ x ≤ 0.05) via a hydrothermal method. The as-prepared samples were thoroughly characterized using various analytical techniques. XRD, FTIR and FESEM analyses confirm the formation of a cubic spinel phase of the CZFNPs (CZF nanoparticles). A decrease in the lattice parameter due to the substitution of Fe³⁺ by Nd³⁺ in the lattice structures is manifested in the XRD refinement data. The magnetic properties of the proposed CZFNPs were evaluated in terms of the saturation magnetization, remanence, coercivity, squareness ratio and magnetic moment. These CZFNPs exhibit superparamagnetic behaviors at room temperature. Moreover, the Nd³⁺ inclusion does not significantly affect the measured magnetizations and coercivities of the CZFNPs. Samples containing 0.01 and 0.03 Nd³⁺ exhibit lower saturation magnetizations than that of the pristine product. The squareness ratios much less than 0.53 are ascribed to surface spin disordering. The unique magnetic traits of the synthesized CZFNPs are primarily attributed to the substitution of Fe³⁺ ions, with smaller ionic radii, by Nd³⁺ ions, with larger ionic radii. The proposed CZFNPs may be useful for diverse magneto-optic applications.     

Impact of repeated loading on mechanical response of a reinforced sand

Pavements constructed over loosely compacted subgrades may not possess adequate California bearing ratio(CBR)to meet the requirements of pavement design codes,which may lead to a thicker pavement design for addressing the required strength.Geosynthetics have been proven to be effective for mitigating the adverse mechanical behaviors of weak soils as integrated constituents of base and sub-base layers in road construction.This study investigated the behaviors of unreinforced and reinforced sand with nonwoven geotextile using repeated CBR loading test(followed by unloading and reloading).The depth and number of geotextile reinforcement layers,as well as the compaction ratio of the soil above and below the reinforcement layer(s)and the compaction ratio of the sand bed,were set as variables in this context.Geotextile layers were placed at upper thickness ratios of 0.3,0.6 and 0.9 and the lower thickness ratio of 0.3.The compaction ratios of the upper layer and the sand bed varied between 85% and 97% to simulate a dense layer on a medium dense sand bed for all unreinforced and reinforced testing scenarios.Repeated CBR loading tests were conducted to the target loads of 100 kgf,150 kgf,200 kgf and 400 kgf,respectively(1 kgf = 9.8 N).The results indicated that placing one layer of reinforcement with an upper thickness ratio of 0.3 and compacting the soil above the reinforcement to compaction ratio of 97%significantly reduced the penetration of the CBR piston for all target repeated load levels.However,using two layers of reinforcement sandwiched between two dense soil layers with a compaction ratio of 97%with upper and lower thickness ratios of 0.3 resulted in the lowest penetration.     

Microwave dielectric properties and infrared reflectivity spectra analysis of two novel low-firing AgCa2B2V3O12 (B = Mg,Zn) ceramics with garnet structure

Two Ag-containing microwave dielectric ceramics AgCa₂B₂V₃O₁₂ (B?=?Mg, Zn) with garnet structure were prepared through solid-state reaction method. Dense ceramics were obtained at low sintering temperatures, 665?°C for AgCa₂Zn₂V₃O₁₂ and 730?°C for AgCa₂Mg₂V₃O₁₂. Their microwave dielectric properties were characterized for the first time and analyzed by means of packing fraction, bond valence, octahedral distortion, Raman spectra and infrared reflectivity spectra. Both compounds displayed high chemical compatibility with Ag electrodes. Additionally, thermally stable ceramics with near-zero temperature coefficients of resonance frequency (τ_f) were achieved by forming ceramic composites with CaTiO₃.     

Fused deposition modeling of mullite structures from a preceramic polymer and γ-alumina

Thermoplastic filaments for Fused Deposition Modeling fabrication of mullite ceramic components were produced from a polymethylsiloxane ceramic precursor, γ-Al₂O₃ powder and ethylene vinyl acetate (EVA) as an organic, elastomeric binder. Two micron-sized γ-Al₂O₃ powders with different particle size distributions were used. Both type of powders could be successfully 3D printed, however γ-Al₂O₃ with finer particle size resulted in better quality of printed parts with much smoother surface.Sintering experiments showed that mullite starts forming already at 1250 °C, but a final sintering of 1550 °C is necessary to achieve pure mullite using the coarse powder, while some residual α-Al₂O₃ was present when using finer powder.Results demostrate that Fused Deposition Modeling can be used to shape preceramic polymers to generate large scale components with a complex shape in which, during firing, the siloxane produces highly reactive silica that allows for the in-situ formation of silicate ceramic phases, such as mullite.     

A genome-wide association study for susceptibility and infectivity of Holstein Friesian dairy cattle to digital dermatitis

Selection and breeding can be used to fight transmission of infectious diseases in livestock. The prevalence in a population depends on the susceptibility and infectivity of the animals. Knowledge on the genetic background of those traits would facilitate efficient selection for lower disease prevalence. We investigated the genetic background of host susceptibility and infectivity for digital dermatitis (DD), an endemic infectious claw disease in dairy cattle, with a genome-wide association study (GWAS), using either a simple linear mixed model or a generalized linear mixed model based on epidemiological theory. In total, 1,513 Holstein-Friesian cows of 12 Dutch dairy farms were scored for DD infection status and class (M0 to M4.1) every 2 wk for 11 times; 1,401 of these cows were genotyped with a 75k SNP chip. We performed a GWAS with a linear mixed model on 10 host disease status traits, and with a generalized linear mixed model with a complementary log-log link function (GLMM) on the probability that a cow would get infected between 2 scorings. With the GLMM, we fitted SNP effects for host susceptibility and host infectivity, while taking the variation in exposure of the susceptible cow to infectious herd mates into account. With the linear model we detected 4 suggestive SNP (false discovery rate < 0.20), 2 for the fraction of observations a cow had an active lesion on chromosomes 1 and 14, one for the fraction of observations a cow had an M2 lesion on at least one claw on chromosome 1 (the same SNP as for the fraction of observations with an active lesion), and one for the fraction of observations a cow had an M4.1 lesion on at least one claw on chromosome 10. Heritability estimates ranged from 0.09 to 0.37. With the GLMM we did not detect significant nor suggestive SNP. The SNP effects on disease status analyzed with the linear model had a correlation coefficient of only 0.70 with SNP effects on susceptibility of the GLMM, indicating that both models capture partly different effects. Because the GLMM better accounts for the epidemiological mechanisms determining individual disease status and for the distribution of the y-variable, results of the GLMM may be more reliable, despite the absence of suggestive associations. We expect that with an extended GLMM that better accounts for the full genetic variation in infectivity via the environment, the accuracy of SNP effects may increase.     

Coupled numerical and experimental analyses of load transfer mechanisms in granular-reinforced platform overlying cavities

A numerical model based on Finite Element Method (FEM) - Discrete Element Method (DEM) coupling is used to reproduce well controlled laboratory experiments that simulate circular cavity openings under granular embankments reinforced by a geotextile. The numerical deflection of the geotextile, the surface settlement and the soil expansion factor were investigated for various embankment heights, diameter ratios, cavity-opening modes, soil properties, and geotextile stiffnesses, and then compared to the results of laboratory tests. The load transfer mechanisms were also investigated. Good agreement between numerical and experimental results is shown, thus demonstrating the relevance of the numerical model. Complementary to the experiments, a numerical sensitivity analysis, that allows highlighting the influence of the main parameters and improving experimental observation, was also performed.     

Culturally adapted mobile technology improves environmental health literacy in Laurentian,Great Lakes Native Americans (Anishinaabeg)

The presence of persistent bioaccumulative toxics (PBT) in aquatic food chains complicates decision processes of people with a strong culture of fish consumption. This environmental contamination is especially problematic for Native American populations in the Laurentian Great Lakes region (Anishinaabeg). Pursuing the growing discipline of environmental health literacy (EHL) may help reduce toxic exposures, support healthy decision-making, and combat health deficits. Our goals for this research were first to improve environmental health literacy using novel technologies and second to help define environmental health literacy metrics that can be tracked over time, especially regarding culturally-contextualized health interests. We recently reported that a mobile app (Gigiigoo'inaan App) presenting personalized, culturally-contextualized fish consumption advice may improve EHL for the Anishinaabeg. Gigiigoo'inaan App safely supports desired fish consumption rates by putting local data into the hands of the Anishinaabeg. We conducted a pre-test post-test evaluation with 103 Aninishinaabe adults. Participants estimated their current fish meal consumption over a hypothetical month before exposure to the software and then planned their future consumption of fish meals in a month after using the mobile app. Significantly more monthly traditional fish meals on average (Median: 4 vs 2, p = 0.0005) were selected when using the app versus pre-exposure to the app. Significantly more traditional grams of fish were also selected during use of the app relative to the pretest (Median: 680.39 g vs 453.59 g, p = 0.0007). These increases were accompanied by widespread (97%) adherence to conventional advice that minimizes PBT exposure health effects (ATSDR minimum risk levels).     

A short-term model for extrapolating unconfined creep deformation data for woven geotextiles

This study reports results for creep deformation with data acquired in 72 h of testing. A system capable of performing 8 simultaneous tests was used to test four woven geotextiles of different weights, following all of the recommendations outlined in the standards related to equipment setup. A mathematical model was used to generate time-dependent creep curves for four different load levels up to 40% for each sample and using a database which presented stage II creep conditions (i.e. without rupture) through the end of the tests, up to 10,000 h. The coefficients of variation for the conventional creep tests were below 10%. The compatibility between the experimental data and the model indicates that short-term (72 h) loading tests may be used to extrapolate long-term creep deformation in woven geotextiles.     

Milk polar lipids modulate lipid metabolism,gut permeability,and systemic inflammation in high-fat-fed C57BL/6J ob/ob mice,a model of severe obesity

Dynamic interactions between lipid metabolism, gut permeability, and systemic inflammation remain unclear in the context of obesity. Milk polar lipids, lipids derived from the milk fat globule membrane, could positively affect the aforementioned obesity-related endpoints. This study aimed to test the hypotheses that milk polar lipids will reduce gut permeability, systemic inflammation, and liver lipid levels, and differentially affect the hepatic expression of genes associated with fatty acid synthesis and cholesterol regulation in preexisting obesity. We fed 3 groups of C57BL/6J ob/ob mice (n = 6 per group) for 2 wk: (1) a modified AIN-93G diet (CO) with 34% fat by energy; (2) CO with milk gangliosides (GG) at 0.2 g/kg of diet; and (3) CO with milk phospholipids (PL) at 10 g/kg of diet. The GG and PL were provided as semi-purified concentrates and replaced 2.0% and 7.2% of dietary fat by energy. The GG and PL did not affect total food intake, weight gain, fasting glucose, or gut permeability. The PL decreased liver mass and the mesenteric fat depot compared with the CO. The GG increased tight junction protein occludin in colon mucosa compared with the CO. The GG and PL decreased tight junction protein zonula occludens-1 in jejunum mucosa compared with the CO. Plasma endotoxin increased during the study but was unaffected by the treatments. Compared with the CO and GG, the PL increased plasma sphingomyelin and plasma IL-6. The GG and PL differentially regulated genes associated with lipid metabolism in the liver compared with the CO. Regarding general effects on lipid metabolism, the GG and PL decreased lipid levels in the liver and the mesenteric depot, and increased lipid levels in the plasma. Diet consumption decreased significantly when the ob/ob mice were kept in metabolic cages, which were not big enough and resulted in unwanted animal deaths. Future studies may keep this in mind and use better metabolic equipment for ob/ob mice. In conclusion, dietary milk polar lipids may have limited beneficial effects on gut barrier integrity, systemic inflammation, and lipid metabolism in the context of severe obesity.