酸性锌空电池中锌在钛电极上沉积与溶出研究

为研究开发酸性电解质可充式二次锌空电池,实验研究了以钛板为基体的锌电极,通过线性扫描曲线、SEM、金相、以及充电等方法来测试其性能,考察酸度、电流密度对锌沉积性能的影响程度,探索在酸性环境下最佳的溶液配比和最适宜的电流密度。在常温、酸浓度为1.0 mol/L,沉积锌适宜的电流密度为50～60 mA/cm2,沉积在钛板上锌的槽电压平台为3.0～3.1 V,沉积上的锌均匀致密,没有明显的枝晶和变形问题;六次循环沉积溶出实验后,电流效率高于85%,说明钛板是可行的新型可充式酸性锌空电池的锌载体材料。     

热处理对TC4合金中厚板组织及性能的影响

研究了不同热处理制度对TC4合金中厚板的显微组织和力学性能的影响。结果表明,经800 ℃×1 h/AC(空冷)退火后,组织为球状α+少量的长条状α+少量β组织,其拉伸性能比热轧态略有下降;热轧后的TC4合金板材经960 ℃×80 min/AC固溶处理后,组织为双态组织,即初生α+针状（α+β）,其横向抗拉强度和屈服强度与普通退火态的相比分别降低了35 MPa和75 MPa。固溶后的TC4合金板经700 ℃×120 min/AC时效后,初生α相的含量变少,β晶粒尺寸变大,片状次生α相拉长并粗化,与800 ℃×1 h/AC退火相比,虽然拉伸性能有所降低,但性能更加均匀,各向异性不明显。热轧后的TC4合金板经1000 ℃×20 min/WQ（水冷）后,β相发生马氏体转变,组织为非常细小的针状组织,抗拉强度比普通退火略有提高,但屈服强度和塑性急剧下降。     

6061铝合金板料的成形性能及数值模拟研究

通过单向拉伸试验获得了6061铝合金原始T6态和退火态板材的基本力学性能,进而得出了6061铝合金的真实应力应变曲线。在此基础上,用不同本构方程对实验数据进行拟合,然后与材料应变硬化曲线相比较。结果表明,采用含有幂函数的本构方程对两种状态的板材试验数据拟合较好,基于单向拉伸试验获得两种状态板材在真应变为8%时的塑性应变比分别为0.996和0.712。此外,用有限元软件Dynaform对6061铝合金管材进行绕弯模拟,对获得的成形性能参数进行了验证。     

新型阻溶促溶酚醚化树脂的合成及表征

为提高热敏CTP(Compute To Plate)版材的显影性和成像性,合成了一种新型阻溶促溶酚醚树脂。通过红外光谱、GPC及1H-NMR对其结构进行了表征。从催化剂、溶剂、反应温度、反应时间及反应物的物质的量比这5个方面对该反应进行了研究,得到了最佳合成条件:1,2-二氯乙烯为溶剂,氨基磺酸作催化剂,乙烯基乙醚与酚羟基物质的量比为3∶1,反应温度40℃,反应时间12 h。将新型阻溶促溶酚树脂用于热敏CTP版材,其综合成像性能优良。     

铜/铝异质金属层状复合板搅拌摩擦焊接技术研究

本文选用复层占比约23%的6.5 mm厚铜（复层）/铝（基层）金属层状复合板作为焊接对象,研究对其进行搅拌摩擦焊接（FSW）的可行性;同时重点研究焊接工具的作用位置（复层在上和基层在上）对于焊接过程的影响;此外,结合有限元模拟技术,分析FSW过程中焊接工具的热力耦合作用对于铜复层流动行为的影响,以及接头中微观组织,尤其是界面区组织的变化。结果表明,在下压量为0.2 mm、焊接速度为150 mm/min和旋转速度为900 r/min的焊接参数下,当采用铝基层在上的焊接方式时,铜复层侧受焊接工具热机作用影响较弱,向上迁移作用较小,并且由于底部作用温度较低、铜复层熔点较高以及导热性较强,因此容易导致在接头底部形成明显的隧道缺陷;当铜复层在上时,可以获得成形良好的FSW接头,由于焊接过程中后退侧和前进侧温度存在差异,在温度较低的后退侧中的铝-铜界面区域,仅形成了少量的Al-Cu金属间化合物层;在温度较高的前进侧中铝-铜界面区域,则由较厚的脆性Al-Cu金属间化合物层组成,该FSW接头的平均抗拉强度为85.2 MPa,约为母材抗拉强度的62.7%。     

夹层板的稳定性分析方程

本文用Reissner理论构造了一种八节点等参单元，对于表层较薄、夹芯剪切模量较大的复合材料夹层板，提供了一种相对简单的有限元计算方法。给出了详细的理论推导，分析了材料性质参数和板的几何参数变化的情况下，夹层板的稳定性情况，为实际的结构设计提供参考依据。     

无铬及含铬电镀锌耐指纹钢板的性能对比研究

为满足环保需求,宝钢冷轧厂在国内率先成功实现了电镀锌无铬耐指纹薄板的产品稳定化生产.首先简要介绍了宝钢电镀锌耐指纹有机膜钢板的生产状况、主要用途.为了解产品性能,采用多种实验方法重点研究了宝钢新型无铬耐指纹钢板的特性,并与原有含铬产品进行了对比.结果表明,宝钢无铬耐指纹有机膜产品各项性能与原含铬产品性能基本相当,满足用户的使用需求.     

Application of detonation coatings to design a new metal cutting tool

This paper presents the results of a research and development study of a new metal-working tool using detonation spray hard alloy coating. The influence of a heat-insulating sublayer on thermal flows occurring at flow drilling has been studied. New design and technology to manufacture punches for plastic drilling with heat-insulating ceramic sublayer aimed at decreasing a parasitic thermal flow through the tool to the lathe’s spindle have been developed. In addition, a new design and manufacturing technology for replaceable cutting plates for lathe working involving the use of detonation spray hard alloy coating have been created. The proposed application of the new tool allows reduction of its conversion cost and improving of performance characteristics.     

Binding property of Al/Mg/Al thin plates fabricated by one-pass hot rolling with different reduction ratios,temperatures and annealing treatments

In this study, Al-Mg-Al trilaminated thin plates were fabricated by one-pass hot rolling to improve the processing capacity and bonding strength of magnesium alloy plates. The effects of processing parameters were investigated. The results show that the optimal bonding strength is up to 20 MPa with a reduction ratio of 40 % and rolling temperature of 400 ℃, superior than that in other one-pass rolling studies with regard to thin laminated plates. In addition, a favorable property is achieved with the annealing temperature of 250-300 ℃ or annealing time of 1.5 h. When the annealing temperature exceeds300 ℃ or annealing time exceeds 1.5 h, respectively, the bonding strength of Al/Mg/Al plate decreases. The scanning electron microscopy(SEM) and energy-dispersive spectroscopy(EDS) analyses suggest that the appearance of thin diffusion layers between A1 and Mg interfaces is helpful to improve the bonding strength, while the presence of thick diffusion layer would reduce the bonding strength greatly.     

Experimental fire analysis of steel‐to‐timber connections using dowels and nails

The paper describes and discusses the results of an extensive testing programme on the structural behaviour of timber connections under ISO‐fire. The results of reference tests performed at normal temperature are also presented. From the variety of timber connections multiple shear steel‐to‐timber connections with dowels and slotted‐in steel plates and connections with steel side plates and annular ringed shank nails were experimentally studied. Particular attention was given to the analysis of the efficiency of different strategies in order to increase the fire resistance of the timber connections. The test results showed that unprotected multiple shear steel‐to‐timber connections with dowels designed for normal temperature reached a fire resistance of about 30 min. A reduction of the load level applied during the fire did not lead to a significant increase of the fire resistance. By increasing the side timber members as well as the end distance of the dowels by 40 mm the connections reached a fire resistance of more than 70 min. Connections protected by timber boards or gypsum plasterboards showed a fire resistance of around 60 min. Thus, from a fire design point of view these strategies were favourable in order to increase the fire resistance of the connections significantly. Unprotected connections with steel side plates and annular ringed shank nails failed already after about 12 min due to large deformations of the nails and the steel side plates directly exposed to fire. By protecting the steel side plates using an intumescent paint the fire resistance of the connections was increased to around 30 min. The test results enlarged the experimental background of timber connections in fire significantly. Copyright © 2009 John Wiley & Sons, Ltd.