PC／TPU共混物的流变性能

用毛细管流变仪研究了聚碳酸酯（ＰＣ）及聚碳酸酯／热塑性聚氨酯弹性体（ＰＣ／ＴＰＵ）共混物的流变性能。实验结果表明：ＰＣ熔体粘度对剪切速率（γ）不敏感，而对温度（Ｔ）敏感。温度升高，ＰＣ粘度降低。加入ＴＰＵ大大改善了共混物的流动性能，使共混物的成型加工变得容易进行。当ＴＰＵ含量为４０份时，共混物的熔体粘度出现一极小值。加入不同第三组分对于降低共混物的熔体粘度效果不同，第三组分Ｅ对共混物有增粘作用     

VCM／VAC共聚掺混树脂的合成及性能研究

本文介绍用特殊悬浮法合成共聚掺混树脂的方法,并讨论了粒经、掺混树脂含量等因素对糊性能的影响.结果表明,通过使用多元混合引发剂和悬浮剂及加入适量的助分散剂、界面活性剂、调粒剂等,并通过控制搅拌速率、温度等工艺条件能有效地控制粒子的粒径、粒度分布及粒子形状,从而制得具有良好性能和粒度均匀的掺混树脂;在一定的粒径范围内(25～40μm),掺混树脂的平均粒径越大,对降低糊粘度的效果越好;增加掺混树脂的含量对降低初始糊粘度更为有利,在PVC糊树脂中加入一定量的掺混树脂可降低塑化温度,缩短塑化时间,从而改善了PVC糊树脂的加工性能.     

Miscibility, crystallization and morphologies of syndiotactic polystyrene blends with isotactic polystyrene and with atactic polystyrene

Two-component blends of differing polystyrene (PS), one syndiotactic (sPS) and the other isotactic (iPS) or atactic (aPS), were discussed. The phase behavior, crystallization and microstructure of binary polystyrene blends of sPS/iPS and sPS/aPS with a specific composition of 5/5 weight ratio were investigated using optical microscopy (OM), differential scanning calorimetry, wide-angle X-ray diffraction, scanning and transmission electron microscopy (SEM and TEM). Based on the kinetics of enthalpy recovery, complete miscibility was found for the sPS/aPS blends where a single recovery peak was obtained, whereas phase separation was concluded for the sPS/iPS blends due to the presence of an additional recovery shoulder indicating the heterogeneity in the molten state. These findings were consistent with OM and SEM observations; sPS/iPS exhibits the dual interconnectivity of phase-separated phases resulting from spinodal decomposition.Both iPS and aPS have the same influence on the sPS crystal structure, i.e., dominant β-form sPS and mixed α-/β-form sPS obtained for melt-crystallization at high and low temperatures respectively, but imperfect α-form sPS developed when cold-crystallized at 175 °C. Co-crystallization of iPS and sPS into the common lattice was not observed regardless the thermal treatments, either cold or melt crystallization. Due to its slow process, crystallization of iPS was found to commence always after the completion of sPS crystallization in one-step crystallization kinetics. Segregation of rejected iPS component during sPS crystallization was extensively observed from TEM and SEM images which showed iPS pockets located between sPS lamellar stacks within spherulites, leading to the interfibrillar segregation, which was similar with that observed in the sPS/aPS blends. The addition of iPS (or aPS) component will reduce the overall crystallization rate of the sPS component and the retardation of crystal growth rates can be simply accounted by a dilution effect, keeping the surface nucleation intact. The phase-separated structure in the sPS/iPS blend shows a negligible effect on sPS crystallization and the signature of phase separation disappears after sPS crystallization. Depending on the relative dimensions of the segregated domains and iPS lamellar nucleus, subsequent crystallization of iPS can proceed to result in a crystalline/crystalline blend, or be inhibited to give a crystalline/amorphous blend morphology similar with that of sPS/aPS blends.     

多糖类生物降解材料的研究进展

本文在参考二十八篇文献及专利报道的基础上详述了以多糖类天然高分子为原料的生物降解材料的研究发展。淀粉、纤维素、壳聚糖及其它多糖，是自然界中大量存在的天然高分子材料，来源丰富，价格低廉、且易被微生物分解。多糖类降解材料可用通用的加工方法和设备加工成型，产品性能优良，可完全生物降解，其开发和应用是解决目前世界范围内的塑料产生的污染问题的理想途径。     

PC/ABS共混体系的研究进展

综述了PC/ABS共混体系相结构的分析结果、增容技术以及影响PC/ABS合金性能的主要因素。     

Dynamic mechanical properties of three different combinations taken from styrene-co-itaconate, styrene-co-methacrylate, and styrene-co-sulfonate ionomers

Dynamic mechanical properties of three different styrene-based ionomer blends containing ca. 5 mol% of ionic repeat units were investigated; the three ionic units were itaconate (ITANa), methacrylate (MANa), and styrenesulfonate (SNa). For SNa-MANa ionomers, it was observed that this ionomer system showed only two loss tangent peaks, implying that this ionomer system resembles a typical miscible system. When the ion content increased, however, the ionomer blend showed two cluster loss tangent peaks, indicating the presence of phase-separated cluster regions. This suggests that, with increasing ion content, the role of ionic units becomes more important than that of host non-ionic units to determine ionomer properties. In the case of ITANa-MANa and ITANa-SNa ionomers, however, it was suggested that the multiplets of the MANa and SNa ionomers might be disrupted upon the addition of the ITANa ionomers. In addition, the SEM images showed that the fracture surfaces of ionomers changed upon blending.     

PPO/PP及PPO/PA合金

PPO与PA,PP是不相容的,制造PPO PA及PPO PP合金需要提高合金中两组分的相容性。本文叙述改善相容性的原理和途径、两种合金的特点及其重要性能。     

我国文化与科技融合机理研究——基于高新技术开发园区视角

文化与科技融合的研究是当前文化科技领域的热门话题。推进文化与科技深度融合,是促进文化产业大发展大繁荣的必要条件,也是文化体制改革的必然要求。本文立足于高新技术开发园区视角,从融合动因、融合模式、融合效果等三个方面探究文化与科技融合的机理,并从政策、文化产业融资、人才培养和文化产业集群等方面对如何实现文化与科技的充分融合,提出了塑造文化品牌、增加文化产品科技含量和附加值的相关对策建议。     

基于民族文化探讨我国艺术设计的发展

随着对西方艺术设计的学习和借鉴,我国的艺术设计也取得了相应的发展。与此同时,我国的艺术设计也面临着相应的问题,如缺乏自主创新和民族特色。我国的民族文化有着历史悠久,特色鲜明的特点,将我国的民族文化与我国的艺术设计进行有效的结合。是推动我国艺术设计不断发展与创新的有效手段。文章分析了民族文化在我国艺术设计中的价值和应用形式,并就民族文化与艺术设计的融合进行了相关探讨。     

中国汉服饰的主流思想和审美文化研究

汉服饰是汉民族的传统服饰,也是中华民族的优秀文化之一。汉服饰文化的精髓在于它博大宽阔且飘逸洒脱的艺术风格以及汉服背后所承载着的传统礼仪文化。汉服褒衣博带、宽衣大袖的服饰特点体现了传统中国＂天人合一＂的世界观和舒适自然、彬彬有礼、内敛含蓄的东方审美情趣。