Physico-chemical and dynamic study of oil-drop removal from bare and coated stainless-steel surfaces

We have studied the removal of sessile oil drops from stainless-steel surfaces under the action of water flow. A shear-flow cell is used to compare bare and polysiloxane-coated stainless-steel surfaces. We consider a rectangular channel where initially deposited drops are subjected to drag, gravity and pressure gradient forces. Our results indicate that a drop detachment mode is observed for the bare steel, whereas a sliding mode is observed for the coated steel. The removal of large drops, which requires low critical shear flows, is essentially dominated by the combined action of the lift and gravity forces. However, for small drops with a large critical shear flow, the capillary forces are the key factor. The detachment was also studied with surfactants added to water. It was found that the detachment mode exhibits a 'depinning effect', which results in drops sliding. Due to low pressure near the triple line, an accumulation of the surfactant induces surface tension gradients along the interface (Marangoni effect), which, in turn, facilitates depinning of the contact line. These results underline the crucial role of the capillary forces governed by the physico-chemical nature of stainless steels, a key factor for understanding the cleanability processes of these materials.     

Combined effects of surface roughness and couple stresses on static and dynamic behaviour of squeeze film lubrication of porous journal bearings

Abstract

The combined effects of surface roughness and the couple stresses on the static and dynamic characteristics of squeeze film lubrication in porous journal bearings with no journal rotation are theoretically studied. The Stokes couple stress fluid model is considered to model the lubricants with additives. The surface roughness on the porous journal bearing is mathematically modelled by a random variable with non-zero mean, variance and skewness. The generalised stochastic Reynolds type equation is derived for the problem under consideration. The applied load is considered as a sinusoidal function of time to simulate the bearings operating under cyclic loads. The closed form expressions for the bearing characteristics are obtained for the short porous journal bearings. It is observed that the negatively skewed surface roughness and couple stresses improve the performance of the porous journal bearings as compared to the smooth journal bearings with Newtonian lubricants. However, the presence of positively skewed surface roughness on the bearing surface affects its performance.     

Contact angle and IGC measurements for probing surface-chemical changes in the recycling of wood pulp fibers

The objective of this study was to use dynamic contact angle (DCA) analysis and inverse gas chromatography (IGC) to probe the surface-chemical changes in wood pulp fibers during recycling. A simplified wet-dry-rewet cycle was performed on hardwood bleached kraft fibers to represent the recycling process. The DCA measurements revealed that the overall effect of recycling was an increase in the non-polar (dispersive) component and a corresponding decrease in the polar component of the surface free energy, hence resulting in a total surface free energy that remained essentially unaltered. The DCA experiment also showed that virgin fibers lost both their electronaccepting (γ_S ⁺) and their electron-donating (γ_S ^-) characteristics when converted to paper. Upon rehydration, the fibers recovered some surface acidity (γ_S ⁺) but surface basicity (γ_S ^-) continued to decrease. The changes in polar surface free energy correlate well with the changes in hydroxyl number determined independently using the acetylation method. IGC could not detect changes in the dispersive component of the surface free energy induced by recycling. The acid-base (KA and KB) changes in the IGC measurements were also indistinguishable between virgin fibers and recycled fibers. This research concludes that DCA analysis is preferable to IGC in better reflecting the surface changes in fiber recycling, and γS-can at least be treated as an empirical parameter to complement the hydroxyl availability data in distinguishing among virgin, paper, and recycled fibers.     

DELPHI中动态链接库调用之剖析

本文系统介绍了动态链接库(DYNAMICLINKLIBRARY,简称DLL)的基本概念和对DLL的实现原理进行剖析,使我们对DLL文件的内部结构有一个全面的认识,并通过实例描述如何在DELPHI通过编程实现动态链接库调用过程。     

Contact angle measurements and interpretation: wetting behavior and solid surface tensions for poly(alkyl methacrylate) polymers

Low-rate dynamic contact angles of a large number of liquids were measured on a poly(ethyl methacrylate) (PEMA) polymer using an automated axisymmetric drop shape analysis profile (ADSA-P). The results suggested that not all experimental contact angles can be used for the interpretation in terms of solid surface tensions: eight liquids yielded non-constant contact angles and/or dissolved the polymer on contact. From the experimental contact angles of the remaining four liquids, we found that the liquid-vapor surface tension times the cosine of the contact angle changes smoothly with the liquid-vapor surface tension, i.e. γlv cos ζ depends only on γlv for a given solid surface (or solid surface tension). This contact angle pattern is again in harmony with those from other methacrylate polymer surfaces of different compositions and side-chains. The solid-vapor surface tension of PEMA calculated from the equation-of-state approach for solid-liquid interfacial tensions was found to be 33.6 ± 0.5 mJ/m2 from the experimental contact angles of the four liquids. The experimental results also suggested that surface tension component approaches do not reflect physical reality. In particular, experimental contact angles of polar and nonpolar liquids on polar methacrylate polymers were employed to determine solid surface tension and solid surface tension components. Contrary to the results obtained from the equation-of-state approach, we obtained inconsistent values from the Lifshitz-van der Waals/acid-base (van Oss and Good) approach using the same sets of experimental contact angles.     

Dynamic mechanical,mechanical and morphological properties of reactive thermotropic liquid crystalline polymer/unsaturated polyester/glass fibre hybrid composites

Abstract

Unsaturated polyester (UP) reinforced with self-synthesised reactive thermotropic liquid crystalline polymer (TLCP)–methacryloyl copolymer (LCMC) and glass fibre (GF), the hybrid composites of UP/GF/LCMC were prepared by moulding technology. The dynamic mechanical analysis indicated that storage modulus and glass transition temperature (T _g) of hybrid composites increased significantly because of the addition of LCMC. The effect of LCMC content on the mechanical properties of LCMC/UP/GF hybrid composites such as impact strength, specific strength and modulus and load–displacement relationship were also investigated through static mechanical tests. The mechanical properties of hybrid composites increased significantly because of the addition of LCMC. The crystal behaviour analysis of LCMC/UP blend was investigated by X-ray diffraction and polarising optical microscopy. The results showed that the crystal phase and texture structure of LCMC still existed in the blends after blending with UP. The morphology of fracture surfaces of hybrid composites containing different TLCP contents was observed by scanning electron microscopy. The present paper discussed the mechanism for the improvement of dynamic mechanical and mechanical properties.     

Dynamic pressure in mould flux channel during mould non-sinusoidal oscillation

Abstract

Based on the lubrication theory of mould flux, a mathematical model of dynamic pressure in mould flux channel was developed, and the distribution of dynamic pressure and its variation during non-sinusoidal oscillation were investigated. The effects of casting speed and non-sinusoidal oscillation parameters, including the degree of non-sinusoidal operation (non-sinusoidal factor), amplitude and frequency of oscillation on the dynamic pressure in the mould flux channel, were studied. The results indicate that the maximum negative pressure is decreased, and the maximum positive pressure is increased with increasing non-sinusoidal factor. The optimum value of non-sinusoidal factor is ～0·2. With increasing amplitude and frequency of oscillation, both the negative and positive pressure are increased; moreover, the increment of positive pressure is obviously greater than that of negative pressure; especially when the oscillation frequency is increased, the increment of negative pressure is very little. When the casting speed is enhanced, the negative pressure is increased, but the positive pressure is decreased. Therefore, if the casting speed is increased, the oscillation amplitude needs to be increased, as well as the oscillation frequency needs to be decreased properly. With these adjustments, the positive pressure in mould flux channel is nearly unchanged. The actions of strand demoulding and cracks welding are kept effective. Moreover, the negative pressure in mould flux channel is increased properly, which causes the flux consumption to increase, so the mould lubrication is improved. Finally, the strand surface quality is improved greatly, and breakout can be avoided. The applicability of the optimised non-sinusoidal oscillation parameters for the two kinds of casting speed has been proven by industrial practice.     

Temperature dependence of low cycle fatigue of 316(N) weld metals and 316L(N)/316(N) weld joints

Abstract

The low cycle fatigue behaviour of 316(N) weld metals and 316L(N)/316(N) weld joints have been investigated in the temperature range of 300–873 K, at a strain amplitude of ±0·6% and a strain rate 3 6 10^–3 s^–1, to study the influence of dynamic strain aging (DSA). The 316(N) weld metal exhibited better fatigue life than the weld joint, though the weld metal has shown higher cyclic stress response and higher plastic strain accumulation than the weld joint. Significant features observed in the temperature regime of 300–873 K include the maximum in fatigue life at 573 K and DSA in the range of 673–873 K. Occurrence of DSA has been manifested through drastic reduction in fatigue life in the range of 673–873 K, associated with anomalous stress response. Dominant DSA effects have been observed at about 773 K in the weld joint and at 823 K in the weld metal. However, the effect of DSA is found to be nominal beyond 823 K where the reduction in fatigue life is attributed to the combined effects of oxidation and DSA. Secondary crack density measurements (in the range of 300–873 K) in the weld joint specimens revealed the severity of the heat affected zone (HAZ) in inducing fatigue damage. Parameters have been identified to determine the temperature corresponding to dominant DSA effects.     

The Influence of Isopropyl Alcohol and Non-ionic Surfactant Solutions on the Mechanical Properties of Offset Paper

The dynamic mechanical properties of coated offset paper before and after application of isopropyl alcohol and surfactant solutions have been investigated. The mechanical properties of the papers were studied with dynamical mechanical analysis in the tensile mode and the samples were submitted to a uniaxial loading in stress–strain measurements. An increase in the isopropyl alcohol concentration slightly reduced the mechanical strength, while the addition of surfactant clearly made the paper stiffer and weakened the paper strength. As the surface tensions of the liquids were adjusted to the same level, the changes in mechanical properties are ascribed to changes in water-induced wetting and subsequent changes in interfacial properties within the paper constituents. The storage and loss moduli of the paper after application of the surfactant solutions were twice those recorded after isopropyl alcohol treatment. The binder was not affected by the solutions, but there was significant debonding, disrupting the internal or surface structure in the base paper-coating layer interface, especially by surfactant solutions.