Determination of molecular weight and molecular sizes of polymers by high temperature gel permeation chromatography with a static and dynamic laser light scattering detector

Flow-mode static and dynamic laser light scattering (SLS/DLS) studies of polymers, including polystyrene, polyethylene, polypropylene and poly(dimethylsiloxane) (PDMS), in 1,2,4-trichlorobenzene (TCB) at 150 °C were performed on a high temperature gel permeation chromatography (GPC) coupled with a SLS/DLS detector. Both absolute molecular weight (M) and molecular sizes (radius of gyration, R_g and hydrodynamic radius, R_h) of polymers eluting from the GPC columns were obtained simultaneously. The conformation of different polymers in TCB at 150 °C were discussed according to the scaling relationships between R_g, R_h and M and the ρ-ratio (ρ=R_g/R_h). Flow-mode DLS results of PDMS were verified by batch-mode DLS study of the same sample. The presented technique was proved to be a convenient and quick method to study the shape and conformation of polymers in solution at high temperature. However, the flow-mode DLS was only applicable for high molecular weight polymers with a higher refractive index increment such as PDMS.     

复合材料空心飞轮多环套装整体变形及应力简化精细分析

采用多环过盈装配是解决复合材料飞轮径向强度过低的有效途径之一。本文作者采用平面应力简化模型,提出了计及过盈配合后变形导致实际过盈量增大计算飞轮套装后的初终应力分布的方法;提出了基于叠加原理计算多环过盈装配旋转飞轮应力的方法;提出了保证飞轮旋转时配合界面不脱离的相关临界转速的概念和计算方法。算例分析表明:过盈配合后的变形对初终应力的影响不能忽略;过盈量和套装环数与飞轮的初终应力和相关临界转速有密切的关系。     

堆石料与基岩面直剪试验

介绍了堆石料与基岩面的现场直剪试验方法，6个组次的直剪试验结果表明，堆石料与基岩面的抗剪强度指标随基岩面坚硬度的增大而增加，并随基岩面粗糙度的加大而加大。     

Micro assembly injection moulding

Injection moulding is established as one of the most common manufacturing processes of thermoplastics due to its high degree of automation and the short cycle times. Micro injection moulding is a rapidly growing technology that allows for the efficient production of very complex micro parts in high series. The “Market Analysis for Microsystems II 2002–2005” of the Nexus Task Force anticipates a yearly growth in the field of micro system technology of about 20% (Wechsung et al. 2002). This study identifies in addition to the continuous miniaturization the growing use of polymers in micro systems (Schneider et al. 2001). No other material group offers this wide range of material properties and permits to choose processing parameters and application properties according to necessities (Gächter 2000). While the production processes of micro technical components are mainly controllable, the assembly of these components to hybrid micro systems is a bottleneck to the industrial large scale production. The assembly itself represents a large fraction of the added product value and gains in importance with growing complexity and miniaturization of the systems.     

Effects of diacrylate monomers on the bond strength of polymer concrete to wet substrates

The bond strengths of polymer concretes containing up to 15% (based on polymer resin) of diacrylate (DA) monomers were examined and compared with those without DA. A change occurring with the addition of DA monomers was an increase in the bond strength of polymer concrete to wet substrates. Zinc diacrylate (ZDA) and calcium diacrylate (CDA) were each used as an additive to monomers and resins [methyl methacrylate (MMA), polyester, and two kinds of epoxies]. The variables were amount of the DA monomers and surface conditions (wet or dry and smooth or rough). Bond strengths were measured by tension bond. ZDA was found to improve the bond strength of MMA and polyester, whereas CDA improved the bond strength of epoxies. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 991–1000, 2003     

An investigation into the effect of various chemical and physical treatments of a South African phosphogypsum to render it suitable as a set retarder for cement

The work describes various physical and chemical treatments to eliminate the deleterious effects of impurities in phosphogypsum on the delayed setting time and impaired strength development behaviour of cement to which it was added as a set regulator. The physical treatments included washing, milling, and ultrasonic treatment of the material, while the chemical treatments dealt with acidic and basic additions to the phosphogypsum during the washing stage. It was found that chemical treatment with a milk of lime solution, which is often recommended in literature, was ineffective in reducing set retardation. Treatment with ammonium hydroxide or sulphuric acid was more effective in this regard. Intergrinding phosphogypsum with slaked lime improved its effectiveness in reducing set retardation, but the use of unslaked lime was less effective and also resulted in marked reductions in compressive strengths. A combined treatment of wet milling phosphogypsum with a lime slurry in a ball mall was derived from these experiments and is recommended for full-scale plant applications.     

滚动式冷床在高钢级油管生产线中的应用

根据石油开采业对石油机械产品的需求 ,利用机械理论基础知识 ,通过实践设计 ,提出了对几何尺寸长的金属管类进行调质处理后的均匀冷却方法 ,以满足其性能要求。     

δ－Al_2O_3纤维／Al－12Si复合材料室温拉伸强度分析

对δ－Ａｌ２Ｏ３纤维／Ａｌ－１２Ｓｉ复合材料室温拉伸强度的分析表明，在实验条件下该复合材料存在δ－Ａｌ２Ｏ３纤维的最小体积分数Ｖｍｉｎ和临界体积分数Ｖｃｒｉｔ，并求出其基体强度σ＇ｍ和室温强度σｃ－δ－Ａｌ２Ｏ３纤维体积分数Ｖｆ直线方程及纤维的临界长度ｌｃ和复合材料的剪切应力τｉ．确定复合材料的ＲＯＭ预测曲线，应首先判断σ＇ｍ是否等于未增强合金的强度σｕｍ才能得出正确的结论     

非饱和土的抗剪强度理论研究

从孔隙水的存在状态出发 ,围绕Bishop抗剪强度公式中存在的几个疑点展开讨论 .认为非饱和土中支配强度和变形的应力之所以不同 ,是因为非饱和土中存在一种性质与有效应力不同的应力———内部应力 ,它不传递 ,仅影响土的塑性变形 .同时还对Bishop ,Fredlund和卢肇钧提出的抗剪强度公式中的参数测试方法进行分析 ,指出 :各种抗剪强度理论在概念上都是相同的 ,其区别仅在于确定由吸力产生的那部分有效应力时采用的参数和测试方法不同     

Microstructure-Property Correlation in AI_4C_3 Dispersion Strengthened Al Composite

The microstructure and tensile properties of Al_4C_3 dispersion strengthened Al composite fabricatedby reaction milling technique were investigated.It is indicated that the rod-like Al_4C_3 dispersoidshaving a diameter of 0.02-0.03 μm and a length of 0.1-0.3μm are formed by reaction of C with Al,and uniformly distributed in the Al matrix.The interface between Al_4C_3 and Al is clean and theinterfacial bonding is good.The matrix consists of the subgrains which have the size of 0.3-0.4μm,and most of the Al_4C_3 dispersoids are distributed on the subgrain boundaries.The 11 vol.-%Al_4C_3/Al composite exhibits an UTS (ultimate tensile strength) of 400 MPa and anelongation-to-failure of 8.0%.