超高纯铜的制备方法和应用

简要介绍了超高纯铜(UHPC)的几种精炼方法，以及它在工业方面的应用。并对超高纯铜的研究开发趋势及应用前景进行了展望。     

Production of biodiesel from waste fryer grease using mixed methanol/ethanol system

Transesterification of waste fryer grease (WFG) containing 5–6 wt.% free fatty acid (FFA) was carried out with methanol, ethanol, and mixtures of methanol/ethanol maintaining the oil to alcohol molar ratio of 1:6, and initially with KOH as a catalyst. Mixtures of methanol and ethanol were used for transesterification in order to use the better solvent property of ethanol and rapid equilibrium using methanol. Formation of soap by reaction of FFA present in WFG with KOH instigated difficulty in the separation of glycerol from biodiesel ester. To untangle this problem, two-stage (acid and alkali catalyzed) method was used for biodiesel synthesis. More than 90% ester was obtained when two-stage method was used compared to ∼ 50% ester in single stage alkaline catalyst. In the case of mixed alcohol, a relatively smaller amount of ethyl esters was formed along with methyl esters. Acid value, viscosity, and cetane number of all the esters prepared from WFG were within the range of the ASTM standard. Esters obtained from WFG showed good performance as a lubricity additive.     

提高特高含水期油藏采收率的方法及应用效果

针对胜索油田二区9-10单元的层间非均质和平面非均质性，运用水动力学方法，采用周期注水及增压注水改善单元的水驱油效果。经过6a的实施，单元的开发形势趋好，单元采收率提高9.62%，增加可采储量341.5kt，对同类型非均质性油藏改善水驱油效果，提高最终采收率具有借鉴意义。     

对氧化物熔体浮区中重力对流的数值模拟

利用有限元分析方法数值模拟了界面形状对氧化物高温熔体碟形浮区中的温度分布和重力对流速率的影响，发现界面形状对重力对流速率有较大的影响，对于凸面，相对于炉圈平面5％的偏离使重力对流速率增大25％，偏离越大，重力对流速度越大，对于凹面，5％的偏离使重力对流速率减小15．7％，偏离越大，重力对流速度越小。     

Differentiation between epigeic and hypogeic fauna in gravel streams

The ‘hyporheic zone’ is described. According to the classical definition, water below the sediment surface is groundwater and the hyporheic interstitial zone is part of the phreatic system. This ignores the vertical distribution of the epigeic benthic fauna. The uppermost layer of the sediment (bed sediments) of the hyporheic zone is dominated by epigeic faunal elements and is therefore part of the surface system. In contrast to hypogeic species, the depth penetration of epigeic species is limited. Possible explanations are discussed.     

改进的FD—TD法分析二维理想导体TM近区散射问题

本文针对一般ＦＤ－ＴＤ方法分析计算二维理想导体散射问题所遇到散射体边角处难以精确处理的缺点进行了改进。将边角处总场近似解析解直接引入ＦＤ－ＴＤ法差分公式，得到了有关修正系数，为了检验此方法的有效性，有无限长导体方柱为例分别用一般ＦＤ－ＴＤ法和本文的ＦＤ－ＴＤ方法进行了分析研究，并与ＭＯＭ法进行了比较，所得结果说明改进后的ＦＤ－ＴＤ方法对分析计算导体边角附近电流分布特性是较有效的。     

Radiation-laminar free convection in a square duct with specular reflection by absorbing-emitting medium

The purpose of this work is to study the effects of specularly reflecting wall under the combined radiative and laminar free convective heat transfer in an infinite square duct. An absorbing and emitting gray medium is enclosed by the opaque and diffusely emitting walls. The walls may reflect diffusely or specularly. Boussinesq approximation is used for the buoyancy term. The radiative heat transfer is evaluated using the direct discrete ordinates method. The parameters under considerations are Rayleigh number, conduction to radiation parameter, optical thickness, wall emissivity and reflection mode. The differences caused by the reflection mode on the stream line, and temperature distribution and wall heat fluxes are studied. Some differences are observed for the categories mentioned above if the order of the conduction to radiation parameter is less than order of 10^-3 for the range of Rayleigh number studied. The differences at the side wall heat flux distributions are observed as long as the medium is optically thin. As the top wall emissivity decreases, the differences between these two modes are increased. As the optical thickness decreases at the fixed wall emissivity, the differences also increase. The difference of the streamlines or the temperature contours is not as distinct as the side wall heat flux distributions. The specular reflection may alter the fluid motion.     

Microstructural transformations of heat affected zones in duplex steel welded joints

The influence of the welding thermal conditions exemplified by heat input and heat treatment after welding on the structure of the heat affected zone (HAZ) UNS S31803 has been analysed. The post weld treatment was used to create the precisely defined thermal conditions for the decomposition of primary phases in the HAZ, by a multi-layer welding thermal cycle stimulation. Detailed analyses of the microstructure and chemical composition of the phases in the different post welded conditions were performed by scanning electron microscopy (SEM) combined with energy dispersive spectrometry (EDS) and transmission electron microscopy (TEM). Three types of secondary precipitates have been observed: secondary austenite (γ₂), carbides: M₂₃C₆ and M₇C₃. The dependence of the secondary austenite volume fraction and morphology in the HAZ on thermal cycle have been interpreted. The eutectoid decomposition of the primary phases in the analysed thermal conditions was confirmed.     

Analysis of crack tip plasticity for microstructurally small cracks using crystal plasticity theory

Crack tip plastic zone sizes and crack tip opening displacements (CTOD) for stationary microstructurally small cracks are calculated using the finite element method. To simulate the plastic deformation occurring at the crack tip, a two-dimensional small strain constitutive relationship from single crystal plasticity theory is implemented in the finite element code ANSYS as a user-defined plasticity subroutine. Small cracks are modeled in both single grains and multiple grains, and different crystallographic conditions are considered. The computed plastic zone sizes and CTOD are compared with those found using conventional isotropic plasticity theory, and significant differences are observed.