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31.
To investigate the effects of introducing the iron compound on the carbonization behavior polyacrylonitile (PAN)-based electrospun nanofibers were carbonized with or without iron(III) acetylacetonate (AAI) over the temperature range of 900–1500 °C in nitrogen atmosphere. The morphological characteristics of the carbon nanofibers were investigated using X-ray diffractometer (XRD), Raman spectroscopy, field emission scanning electron microscopy, and transmission electron microscopy. The electrical conductivity of the carbon nanofiber web was measured by four-point probe method. The iron catalyst had a profound effect on the crystal structure of the carbonized nanofiber. In the presence of AAI the nanofibers carbonized at 1300 °C developed graphite structure, which could be obtained at the temperature higher than 2000 °C in the absence of the catalyst. The in-plane size of the graphite crystals (La) was measured to be about 6.5 nm by Raman spectroscopy and the (0 0 2) spacing by XRD was 0.341 nm. 相似文献
32.
The use of graphite modified polymer films has been investigated, on stainless steel. Polythiophene and polypyrrole films have been synthesized electrochemically on stainless steel, and then very thin graphite layers were realized on polymer films. Since the graphite layer is not applicable as a top coat, polymeric top films were also electrosynthesized on graphite layers. Following this procedure, polypyrrole-graphite-polypyrrole and polythiophene-graphite-polythiophene coatings have been obtained on stainless steel. The corrosion behaviours of coated samples have been investigated in 0.1 M H2SO4 solution, by means of electrochemical impedance spectroscopy (EIS) and anodic polarization curves. The intercalation of graphite layer altered the performance and properties of coatings significantly. Especially, polypyrrole coating system was found to exhibit almost an excellent coating behaviour that hindered the attack of corrosive environment within 96 h exposure time. The EIS results of polypyrrole coating system were indicating to almost a perfect capacitive behaviour that the response was reflecting capacitive behaviour in a wide frequency region. This property was also examined with successive cyclic voltammograms in a potential range between 0.10 and 0.40 V (vs. Ag/AgCl). The charge densities involved in oxidation and reduction regions were determined for successive cycles and it was shown that coated sample was able to exhibit charge-discharge (i.e. oxidation and reduction) behaviour successfully, without any degradation. 相似文献
33.
针对某些承受热循环工况的铸件,采用实验室手段,研究了不同石墨形态铸铁──灰铁、蠕铁、球铁在>50~40℃循环温度下的热疲劳性能。结果表明,在本试验条件下,以球铁的热疲劳抗力最好,灰铁次之,蠕铁最差,研究结果可供实际生产中,选材时的参政。 相似文献
34.
Al4C3的生成会影响Gr-Al-Si复合材料的界面反应,然而研究证明在原料中少量的Al4C3存在,有利于提高石墨分布的均匀性,又不影响该材料的高温抗拉强度等综合性能。Al4C3的形成温度以550~600℃为宜,Al4C3的含量可用X射线定量分析来确定。 相似文献
35.
内壁激冷气缸套的组织研究 总被引:1,自引:0,他引:1
离心铸造气缸套采用内壁激冷新方法,可细化气缸套的内层组织:使硬质相的网孔直径从3级提高到1~2级,石墨片长度从4级提高到6级。实践证明,这种方法不会出现中间夹杂层现象。 相似文献
36.
采用消失模铸造工艺生产蠕铁排气出口管 总被引:2,自引:0,他引:2
介绍了消失模法生产蠕铁排气出口管的工艺过程.试验发现,采用反直浇道结合侧注的模组形式为佳,每组8件、管口朝下;涂料直接影响铸件表面积碳及皱皮倾向;并采用消失模法批量生产了蠕铁排气出口管,材料性能及金相组织达到要求,铸件壁厚均匀,表面光滑,已用于红旗轿车的部分车型. 相似文献
37.
Everaldo Carlos Luiz Henrique Capparelli Paulo Srgio de Paula Alan Graham 《Sensors and actuators. B, Chemical》2008,130(2):723-729
A new simple method (“line patterning technique”) using only standard office equipment is described whereby clearly defined, electrically conducting patterns of graphite can be deposited on polymer (plastic) or paper substrates. The properties of the conductive patterns have been characterized by electrical conductivity and SEM measurements. Sensors were constructed by using interdigitated patterns of graphite deposited on plastic and paper, and coated with a thin film of conducting electronic polymer, e.g. polyaniline emeraldine salt. 相似文献
38.
Amanpreet Kaur 《Fullerenes, Nanotubes and Carbon Nanostructures》2017,25(5):318-326
We have demonstrated a fast, versatile, and scalable approach to synthesize high-quality few layer graphene sheets with low defect ratio and high crystallinity produced from exfoliation of graphite flakes in DMF by using probe sonication. The effect of sonication time on degree of exfoliation and number of graphene layers has been fully investigated. The degree of exfoliation of graphene sheets as a function of sonication time has been successfully analyzed by XRD, UV-Vis spectroscopy, TEM, and BET studies. The morphological changes at different sonication times have also been observed by SEM. A structural and defect characterization of graphene sheets has been discussed in detail by Raman spectroscopic technique. The shift in position of 2D Raman band and its de-convolution provided information about formation of multi to few layer graphene sheets with sonication. Moreover, Raman results are highly consistent with TEM studies as per number of graphene layers is concerned. 相似文献
39.
Shuntao Xu Jinkun Liu Yuan Xue Tianya Wu 《Fullerenes, Nanotubes and Carbon Nanostructures》2017,25(1):40-46
Oxidation time and exfoliated conditions of graphite oxides (GOs) were investigated to prepare few–layer graphene oxide and reduced graphene oxide via a modified Hummers approach. Different oxidative degree of GOs was prepared by changing oxidation time, and the effects of oxidative degree of GOs in different oxidation time were studied by XRD, FT-IR. Afterwards, highly oxidized GOs were used as precursor to prepare graphene oxide and reduced graphene oxide by ultrasonic dispersion method and thermal expansion method. The exfoliated conditions (ultrasonic power and ultrasonic time, thermal exfoliated temperature) were investigated to prepare few-layered graphene oxide and reduced graphene oxide. 相似文献
40.