TiO2/CdS composite hollow spheres with controlled synthesis of platinum on the internal wall for the efficient hydrogen evolution

Solar driven semiconductor photocatalytic water splitting to produce hydrogen is an extremely charming process by storing photon energy in chemical bonds. In the present study, composite semiconductor TiO₂/CdS was structured into uniform and porous double-shelled hollow sphere with cocatalyst platinum selectively loaded onto the internal wall. The SEM, TEM, STEM, XRD, BET and EDS elemental distribution etc. were employed to evidence the formation of the targeted photocatalyst. It was demonstrated that the material has a high efficiency of visible-light-driven hydrogen evolution (296 μmol·h⁻¹/10 mg) with an apparent quantum efficiency (QE) of 14.5% at wavelength of 420 nm. Comparative experiment analysis and time-resolved infrared absorption study suggested that the high photocatalytic activity of the catalyst is attributed to the vectorial electron transfer (CdS → TiO₂ → Pt) and the spatial separation of reduction and oxidation active surfaces achieved by the special morphology.     

低密度BMC复合材料性能的研究

研究了四种不同种类的空心玻璃微珠的加入对团状模塑料(BMC)密度及性能的影响,观察空心玻璃微珠在BMC中的分散及破损情况以及空心玻璃微珠S38含量的变化对BMC密度及性能的影响。结果表明,随着微珠含量的增加密度及拉伸强度逐渐下降;微珠含量为5%时弯曲及冲击强度达到最大值。研究微珠的表面处理对BMC性能的影响,结果表明,微珠的表面处理能有效提高BMC的力学性能。     

Preparation of platinum-doped hollow spheres and their electrocatalytic activity in water electrolysis

Pure TiO₂ hollow spheres were prepared by using poly(styrene-methacrylic acid) latex particles as template; thereafter, titania hollow spheres were coated by platinum with an appropriate amount of choloroplatinic acid solution to obtain Pt/TiO₂ catalysts. The morphology and structure of nonstructural Pt/TiO₂ hollow spheres were characterized by BET, XRD, TGA, SEM and TEM analysis. In the samples, a remarkably uniform layer of Pt consisting of particles from 5 to 70 nm in size was formed over TiO₂ hollow spheres. We found the electrocatalytic nature of the samples by cyclic voltammetric experiment in acidic solution. The anodic peak current density of 20 wt% Pt-loaded TiO₂ hollow particles was observed 2.5 times higher than that of 5 wt% Pt/TiO₂ in the same experimental condition. Also, the anodic current density of 20 wt% Pt/TiO₂ hollow spheres calcined at various temperatures followed the order: 400 °C≈500 °C>600 °C. The electrocatalytic activity of the Pt-loaded TiO₂ hollow spheres depends on the amount of atomic platinum present in the sample; a higher concentration of platinum results in a larger current density value in anodic sweep, resulting in more oxygen production during electrolysis. Pt/TiO₂ hollow sphere catalysts have also shown long term electrocatalytic stability in acidic media.     

芯板厚度对超塑成形的影响

根据超塑成形的工艺要求,利用ANSYS/LS-DYNA有限元软件对空心风扇叶片成形过程进行数值模拟分析,以此研究不同的芯板厚度对超塑成形结果的影响.分析的结果表明:选取的三种厚度的芯板里,当厚度为0.8mm时,塑性变形最均匀,成形效果最好.     

TC4合金空心可调叶片的钎焊工艺研究

某机压气机的空心可调节叶片组件是由钛合金材料TC4合金通过钎焊制成的,每个叶片都是由叶片主体和2个叶形板组成,叶片主体与叶形板之间采用钎焊连接。本文针对空心叶片组件的结构特点和使用要求开展了真空钎焊工艺研究,进行了钎料钎焊接头力学性能测试,同时,就钎焊热循环对TC4合金性能的影响、钎焊工艺路线程序、叶片焊后变形校正等工艺问题进行了深入研究,所确定的真空钎焊工艺程序可以钎焊出合格的可调叶片组件,钎焊质量稳定。     

无帽口钢锭的推广应用

分析了常规钢锭与无帽口钢锭制作筒类锻件的特点。明确指出无帽口钢锭锻件的优势:提高了钢锭利用率和锻件合格率,有效降低了冶炼和锻造成本,生产效率显著提高。     

冷拔螺旋钢筋预应力空心板结构性能试验研究

本文通过对 10块冷拔螺旋钢筋预应力空心板的弯曲破坏试验 ,分析了这种空心板的强度、挠度、裂缝等特点 ,并和现行《钢筋混凝土结构设计规范》中的计算公式作了比较 ,结果发现这种空心板的开裂弯矩和极限弯矩用现行《规范》计算的结果和试验值相差不多 ,而挠度的计算结果和试验值相差较多 ,且偏于不安全。本文根据试验结果的分析给出了冷拔螺旋钢筋预应力空心板的挠度计算公式。     

Synthesis and in vitro bioactivity of novel mesoporous hollow bioactive glass microspheres

The remarkable tissue-repairing bioactivity and biocompatibility of bioactive glass make it suitable for a wide range of applications. Here, novel mesoporous hollow bioactive glass microspheres (MHBGMs) with a uniform diameter range of 2-5 µm were prepared by a sol-gel method. Structural characterization indicated that the shell of hollow sphere had a mesopore size range between 2 and 10 nm and a thickness about 500 nm. The in vitro bioactivity test indicated that the novel structure exhibited high in vitro bioactivity. The uniform microspherical morphology and mesoporous hollow structure of MHBGMs, together with their high bioactivity, turn them into a good candidate as an injectable and drug-loading biomaterial for in vivo tissue regeneration and drug control release.     

A three-dimensional soil–water coupled FE analysis of hollow cylinder test concerning non-uniform deformation

The hollow cylinder shear test is somewhat controversial due to its non-uniform stresses and strains, and has been analyzed by simple theoretical methods and two-dimensional FE calculations. In this paper, the hollow cylinder test under strain control was carried out numerically by treating the specimen as a three-dimensional initial-boundary value problem considering the inertial forces. At first, besides the known nonuniform strain, the non-uniformities of excess pore water pressure and overconsolidation ratio have been shown to benefit from a soil–water coupled analysis that employs the SYS Cam-clay model. Then, the influence of the specimen geometries, including wall thicknesses, heights and outer diameters on the non-uniformity was investigated sequentially. A new method for evaluating non-uniformity was proposed, which is suitable for the three-dimensional analysis. The response under a uniform deformation field, which is indicated by “the perfect path”, was presented to draw a comparison with the apparent behaviors, with non-uniformities taken into consideration. It should be noted that there is a critical height to prevent failure at the specimen ends according to the apparent behavior. Finally, the torque-controlled experiment indicated that 4 ribs could not transfer the torque reliably while 6 or 8 ribs were feasible.