炭黑对丁苯橡胶耐热氧和紫外老化性能的影响

研究了填充不同量炭黑对丁苯橡胶耐热氧和紫外老化性能的影响,测试了各试样的交联密度及物理机械性能,并用扫描电镜观察了其表面形貌.结果表明,丁苯橡胶在热氧老化开始时内部发生了以交联为主的反应,表面氧化缓慢;而在紫外老化开始时表面的变化较大,在老化过程中交联密度出现峰值;热氧和紫外老化120 h后,橡胶的硬度增加,表面变得致密,使热氧和紫外线侵入至橡胶内部变得困难,邵尔A硬度等物理机械性能的变化趋势减缓;炭黑填充量大于20份(质量)时SBR的耐紫外老化性能得到改善,老化360 h后物理机械性能保持率仍然较高,这是因为炭黑对紫外线有很好的屏蔽作用,而炭黑对SBR耐热氧老化性能的影响却相反.     

Probing molecular mobility during crosslinking process of commercial resins by NMR multiexponential relaxation data analysis

In this study, we present the experimental results for the crosslinking process of a commercial polyester resin based on measurements of the spin lattice relaxation time T₁ of protons, as function of the crosslinking time evolution. Multiexponential decomposition of the evolution of magnetization measured in inversion‐recovery experiments is performed. The population of “rigid” and “mobile” nuclear spin sites was estimated as function of time evolution. In analogy to the usual monomer conversion u, site conversion from “mobile” to “rigid” sites u_M were also estimated as a function of time evolution and initial concentrations of the reagents. The multiexponential decomposition approach of T₁ relaxation data allows one to follow crosslinking processes. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Physical properties of ethylene vinyl acetate copolymer (EVA)/natural rubber (NR) blend based foam

In this study an attempt was made to improve the rebound resilience and to decrease the density of ethylene‐vinyl acetate copolymer (EVA) foam. For this purpose, EVA was blended with natural rubber (NR), and EVA/NR blends were foamed at 155°C, 160°C, and 165°C. To investigate the correlation between crosslinking behavior and physical properties of foams, crosslinking behavior of EVA/NR blends was monitored. The physical properties of the foams were then measured as a function of foaming temperatures and blend compositions: 165°C was found to be the optimal temperature for a crosslinking of EVA/NR foam. As a result, the density of EVA/NR blend foamed at 165°C was found to be the lowest. EVA/NR (90/10) blend, foamed at 165°C, showed lower density, better rebound resilience, and greater tear strength than EVA foam. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2212–2216, 2004     

Modeling of distribution parameter,void fraction covariance and relative velocity covariance for upward steam-water boiling flow in vertical rod bundle

In order to improve the prediction accuracy of one-dimensional interfacial force formulated by ‘Andersen’ approach, the distribution parameter in a drift–flux correlation, void fraction covariance, and relative velocity covariance has been modeled for dispersed boiling two-phase flow in a vertical rod bundle. The distribution parameter has been derived by a bubble-layer thickness model. The correlations of void fraction covariance and relative velocity covariance have been developed based on prototypic 8 × 8 rod bundle data. The correlation of void fraction covariance agrees with the bundle data with the mean absolute error, standard deviation, mean relative deviation, and mean absolute relative deviation being 0.00120, 0.0415, ?0.173%, and 1.80%, respectively. The correlation of relative velocity covariance agrees with the bundle data with the mean absolute error, standard deviation, mean relative deviation, and mean absolute relative deviation being ?0.00241, 0.0452, ?0.0316%, and 2.52%, respectively. In view of the great importance of void fraction covariance and relative velocity covariance on the one-dimensional interfacial drag force formulation, it is highly recommended to include the void fraction covariance and relative velocity covariance in the one-dimensional formulation of interfacial drag force used in nuclear thermal-hydraulic system analysis codes.     

Code performance with improved two-group interfacial area concentration correlation for one-dimensional forced convective two-phase flow simulation

In gas–liquid two-phase flow simulation for reactor safety analysis, interfacial momentum transfer in two-fluid model plays an important role in predicting void fraction. Depending on flow conditions, a shape of the two-phase interface complicatedly evolves. One of the proposed approaches is to quantify the gas–liquid interface information using interfacial area transport equation. On the other hand, a more simplified and robust approach is to classify bubbles into two-groups based on their transport characteristics and utilize constitutive equations for interfacial area concentration for each group. In this paper, interfacial drag model based on the two-group interfacial area concentration correlations is implemented into system analysis code, and void fractions were calculated for the evaluation of numerical behaviors. The present analysis includes (1) comparison of one-group and two-group relative velocity models, (2) comparison with separate effect test database, (3) uncertainty evaluation of drag coefficient, (4) numerical stability assessment in flow regime transition, and (5) transient analysis for simulating the prototypic condition. Results showed that utilization of interfacial drag force term using constitutive equations of two-group interfacial area concentration yields satisfactory void fraction calculation results. The proposed solution technique is practical and advantageous in view of reducing the computational cost and simplifying the solution scheme.     

稠油热碱水系统界面张力和乳液特性研究

主要研究了碳酸钠、氢氧化钠、硅酸钠三种碱与稠油的界面张力和碱液-稠油乳状液的特性,讨论了乳状液的驱油机理。结果表明,这三种碱液与稠油的界面张力在一定条件下均能达到10~2mN/m数量级以下;高油水体积比下的碱水-稠油乳液类型由碱浓度决定。     

Morphology effect on the transferred charges in triboelectric nanogenerators: Numerical study using a finite element method

The structural shape of the interface between a metal and dielectric material in a triboelectric nanogenerator (TENG) is an important factor that can improve the device performance. Many interfacial structures have been developed to improve the TENG performance. However, there have been very few studies on the numerical interpretation of various types of contact interfaces. For various interfacial structures on which uniform triboelectric charge density is distributed, the surface charge density (in-plane, out-of-plane, and total) is systematically analyzed to predict the quantity of the transferred charges on the bottom metal under a short-circuit condition. In this work, a numerical study is conducted using a finite element method. The numerical results confirm that the increase in the quantity of the transferred charges collected on the bottom metal via electrostatic induction is related to the increase in the area of the surface structures (i.e., surface enlargement effect due to the formation of complex interfacial morphology). The estimated magnitude of the transferred charges shows the following decreasing trend for the various structural shapes: rectangle > cylinder > pyramid > cone > flat.     

A Click-Chemistry-Based Enrichable Crosslinker for Structural and Protein Interaction Analysis by Mass Spectrometry

Mass spectrometry is the method of choice for the characterisation of proteomes. Most proteins operate in protein complexes, in which their close association modulates their function. However, with standard MS analysis, information on protein–protein interactions is lost and no structural information is retained. To gain structural and interactome data, new crosslinking reagents are needed that freeze inter- and intramolecular interactions. Herein, the development of a new reagent, which has several features that enable highly sensitive crosslinking MS, is reported. The reagent enables enrichment of crosslinked peptides from the majority of background peptides to facilitate efficient detection of low-abundant crosslinked peptides. Due to the special cleavable properties, the reagent can be used for MS² and potentially for MS³ experiments. Thus, the new crosslinking reagent, in combination with high-end MS, should enable sensitive analysis of interactomes, which will help researchers to obtain important insights into cellular states in health and diseases.     

Analysis of mixed-mode dynamic crack propagation by interface element based on virtual crack closure technique

An interface element tailored for the virtual crack closure technique (VCCT) was used to study an example of dynamic crack propagation under mixed mode loading. Through this interfacial element approach, VCCT can be implemented into a commercial finite element analysis (FEA) code having user subroutines without interrupting the main code. Further, with the implementation of relevant fracture criteria, this interface element can be used to simulate a wide range of fracture problems by utilizing the enhanced capabilities available by the commercial FEA codes. For illustration, this element has been implemented with the commercial FEA software ABAQUS^® through the user defined element (UEL). One example of fast crack propagation at constant speed and under mixed-mode loading was examined by comparison to the other’s numerical results using singular moving elements. No convergence difficulty was encountered for all the cases with different values of crack velocity. Neither singular element, nor the collapsed element was required. Therefore, due to its simplicity, the VCCT interface element as demonstrated could be a potential tool for engineers to practice dynamic fracture analysis in conjunction with commercial FEA codes.