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121.
Hong-Bing Tsai Da-Kong Lee Hsien-Wen Chen Jia-Yeh Chang Jung-Liang Liu Chih-Huey Chang I-Chung Du Sheng-Yuan Lei Jiang-Wen You 《Journal of Polymer Research》1996,3(1):59-63
The liquid crystalline transitions of two kinds of smectic polyesters with different molecular weights were investigated by DSC, polarized microscopy and X-ray diffraction. The molecular weight affects the transitions significantly for these two kinds of polyesters. With a high enough molecular weight, both poly (pentamethylenep,p-bibenzoate) and poly(hexamethylenep,p-bibenzoate) exhibit an enantiotropic smectic phase, but the two endothermic transition peaks of the DSC heating curve seem to overlap. The polyesters tend to exhibit a monotropic smectic phase as the molecular weight decreases. From the DSC cooling curve, the isotropic-smectic transition can be seen more clearly. As the molecular weight decreases, the smectic order decrease significantly. The molecular weight affects the transitions in a different way for these two different kinds of polyesters. 相似文献
122.
A new and effective liquid membrane process to achieve both separation and enrichment simultaneously of weak organic acids or bases was developed. The process utilizes effectively the difference in the apparent partition coefficient of the constituent species between the aqueous and organic phases, and uses the change of the apparent partition coefficients with the hydrogen ion concentration of the aqueous phase. For such a fundamental model apparatus as a diaphragm diffusion cell being operated batch wise, the effects of pK value of solutes, permeability of solutes through the membrane, volume ratio of liquids in two aqueous phases, and pH value of aqueous phase on enrichment factor and selectivity for the solute to be concentrated were discussed analytically. Separation and enrichment were demonstrated using aqueous mixed solutions of fumaric acid and L-malic acid. The results were in good agreement with the theoretical predictions. 相似文献
123.
124.
Novel side-chain liquid crystalline (LC) ionomers containing d-metals Co(II) and Ni(II) were synthesized and characterized. Both families of the ionomers are characterized by the same influence of charged group content in polymer on their phase behavior. The incorporation of 2-3 mol% of metal ions in the nematic polymer matrix leads to the induction of SmA phase and rise in the clearing point. The peculiarity of their phase behavior in comparison with the earlier investigated LC ionomers with alkaline or alkali-earth metals is the full destruction of the mesophase at the concentration of d-metal higher than 12 mol%. This phenomenon was associated with the well-known ability of the transition metal ions to form various complexes that, in the case of LC ionomers, can negatively influence the ordering of the side mesogenic groups. The proposed structure of the LC ionomers is discussed in comparison with the metallomesogenic polymer systems. 相似文献
125.
针对油水气三相流研究试验平台液体流量调节范围宽、范围度大的问题,提出采用3条主回路与3条旁通回流调节支路来覆盖所有的流量范围,设计了液相系统原理图及管路布置图,对3条旁通回流调节支路中调节阀的计算流量、计算压差及Kv值进行了计算,并对调节阀的开度及实际可调比进行了验算,结果表明选定的调节阀性能满足油水气三相流研究试验的要求。 相似文献
126.
A theory of chromatography of eight-shaped, trefoil-shaped and daisy-like polymers is developed. For a model of an ideal chain in a slit-like pore exact equations and a number of approximate formulae for the distribution coefficient K of these polymers are derived. All modes of chromatography of complex macrocycles of arbitrary molar mass in both narrow and wide pores are covered by the theory. It is shown that complex macrocycles always elute after linear polymers and rings of the same contour length. The effective chromatographic radius of eight-shaped and daisy-like macromolecules, which determines retention in size-exclusion chromatography are calculated. The increase in the retention with molar mass is predicted for all types of macrocycles at the critical interaction condition. Non-monotonous molar mass dependences of K are found at pre-critical interaction. We simulate separation of complex cyclic polymers from linear and ring precursors, discuss possibilities to separate symmetric and asymmetric eights, and speculates on the use of chromatography for separating knotted and unknotted polymer rings. According to the theory, the chromatography under the critical and pre-critical interaction conditions is expected to be especially efficient in these and similar problems. Boundary conditions for the theory and its applicability to real systems are discussed. 相似文献
127.
液晶聚酯由于具有特异的液晶行为和高强高模性能而越来越受到人们的关注。本文对液晶聚酯的液晶态形成原因、液晶态类型与链结构的关系、液晶态热稳定性及其成型加工性能进行了讨论,指出了提高液晶态热稳定性的方法及液晶聚酯的发展趋势。 相似文献
128.
Yong?An?Jung Du?Young?Choi Seung?Bum?Hong Kyung?Ho?RowEmail author 《Korean Journal of Chemical Engineering》2003,20(4):705-708
Reversed-phase high-performance liquid chromatography was successfully developed for the simultaneous and rapid separation for the main whey proteins, α-Lactalbumin and β-Lactoglobulin. This method consisted of a linear gradient of the two mobile phases of 0.1% trifluoroacetic acid in water and 0.1% trifluoroacetic acid in acetonitrile. The total run time for this separation was approximately 30 min, and α-Lactalbumin was eluted followed byβ- Lactoglobulin. The injection volume was fixed at 20 μl and the flow rate was 1 ml 1/min. The optimum mobile phase composition and gradient conditions to separate α-Lactalbumin and β-Lactoglobulin (A+B) were experimentally obtained at the 15 μm particle with a pore size of 300 Å on the linear-gradient mode. 相似文献
129.
合成了以2—氨基—5—巯基—1,3,4—噻二唑为吸附基团,4,4—二甲基—1—苯基—3—吡唑啉酮为增强基团的新型功能性显影促进剂,其结构经IR、^1H—NMR、MS和元素分析等得到确证.由于其结构的独特性,可望在促进显影的同时而不导致灰雾增大.可将其直接用来促进显影,或者将其与卤代成色剂母体反应得到DAR成色剂后再用于促进显影。 相似文献
130.
Effects of the boundary layer and interfacial reaction on the time lag in supported liquid membranes
Jongheop Yi 《Korean Journal of Chemical Engineering》1995,12(3):391-395
A mathematical model is proposed to describe the effects of boundary layer resistance and interfacial reaction on the time
lag in supported liquid membranes for metal ion separation. The model shows that the presence of boundary layer resistance
and interfacial reaction delays the time-lag, compared with the limiting case that rapid equilibrium at the interfaces and
negligible boundary layer resistance are assumed. Calculated result describes the expected trend and the model equation allows
one to predict the lumped parameters which represent the ratios of the diffusion time in the membrane to the characteristic
time for boundary layer transfer and interfacial reactions. 相似文献