Adsorption and decomposition of H2S on Pd(1 1 1) surface: a first-principles study

Gradient-corrected density functional theory was used to investigate the adsorption of H₂S on Pd(1 1 1) surface. Molecular adsorption was found to be stable with H₂S binding preferentially at top sites. In addition, the adsorption of other S moieties (SH and S) was investigated. SH and S were found to be preferentially bind at the bridge and fcc sites, respectively. The reaction pathways and energy profiles for H₂S decomposition giving rise to adsorbed S and H were determined. Both H₂S_(ad) → SH_(ad) + H_(ad) and SH_(ad) → S_(ad) + H_(ad) reactions were found to have low barriers and high exothermicities. This reveals that the decomposition of H₂S on Pd(1 1 1) surface is a facile process.     

利用低轨卫星星座的移动通信系统

本文介绍两种利用低轨地理卫星星座进行移动通信的系统。一种是英法联合研究提出的利用24颗低轨卫星组成的移动通信；另一种是美国研究提出的利用192颗低轨卫星组成的移动通信系统。最后将低轨卫星移动通信系统与同步卫星移动通信系统及高轨卫星移动通信系统进行了比较。     

低铁耗条件下转炉高碳低磷工艺实践与应用

对转炉炼钢实现低铁耗和高碳低磷工艺进行了分析，介绍了南钢公司转炉炼钢实践低铁耗条件下高碳低磷工艺的具体应用措施。     

羊二庄油田二断块NgI3小层低阻油层识别

在精细地层对比的基础上 ,细分目的层段。利用 40多口井的测井数据 ,建立了纯水层以及NgI3潜力层的“RT -RXO”与“RT -AC”关系图版 ,消除了钻井液侵入对冲洗带电阻率和地层电阻率的影响 ,并以此为油层复查的标准 ,识别出 3个潜力层。经补孔证实 ,消除钻井液侵入的影响可以识别出电阻率值在 3Ω·m以上的薄油层。     

三代微光管均匀性测试与分析

利用自行研制的“光电阴极多信息量测试系统”首次对国产三代微光管中的GaAs光电阴极的均匀性进行了光谱响应测试 ,结果表明该国产三代微光管存在明显的非均匀性。利用曲线拟合方法估算了GaAs光电阴极的材料性能参数 ,发现表面逸出概率不一致是非均匀性的主要原因 ,GaAs材料的少子扩散长度 (1 1 2～ 1 82 ) μm ,与阴极厚度相当 ,后界面复合速率在 (1× 1 0 5～ 1× 1 0 6 )cm/s之间 ,它限制了阴极灵敏度的提高     

Analytical modeling and experimental study of tensile strength of asphalt concrete composite at low temperatures

In this study, analytical modeling of the tensile strength of hot-mix asphalt (HMA) mixtures at low temperatures was developed. To do this, HMA mixtures were treated as a two-phase composite material with aggregates (coarse and fine) dispersed in an asphalt mastic matrix. A two-phase composite model, which was similar to Papanicolaou and Bakos's [J. Reinforced Plast. Compos. 11 (1992) 104] model with a particle embedded in an infinite matrix, was proposed. Unlike Papanicolaou and Bakos's model, an axial stress was introduced to the fiber end to consider the load transferred from the asphalt mastic the aggregate. Efforts were also made to consider the effect of aggregate gradation, asphalt mastic degradation, and interfacial damage between the aggregates and asphalt mastic matrix on the tensile strength of the HMA mixtures. Experimental investigations were conducted to validate the developed theoretical relations. A reasonable agreement was found between the predicted tensile strength and the experimental results at low temperatures. Parameters affecting the tensile strength of asphalt mixtures were discussed based on the calculated results.     

LOW-CYCLE FATIGUE UNDER NON-PROPORTIONAL LOADING

A series of strain-controlled, low-cycle fatigue experiments have been conducted on 42CrMo steel under various loading paths including circular, square, cruciform, and rectangular paths. Present experiments have shown that there is additional hardening under non-proportional cyclic loading. Non-proportional cyclic additional hardening also results in a shorter life for multiaxial low cycle fatigue. A non-proportionality measure of strain path based on both a physical basis and macromechanical phenomena is proposed. The loading path effect on additional hardening is also described well. Low-cycle fatigue damage accumulation and the evolution process under non-proportional loading is analysed via the Continuum Damage Mechanics Model of Chaboche. A non-proportinality measure is introduced in the damage evolution equation and a modified Coffin-Manson type formula is derived. A novel fatigue life prediction approach based on the critical-plane concept of Brown and Miller is proposed.     

低渗透挥发性油藏注烃类气驱室内实验研究

通过注烃类气驱实验研究，了解文留油田低渗透挥发性油藏注气开发的一般机理和开发特点。采用PVT分析方法分析地层流体的物理性质、注入溶剂的组份；通过细管实验研究地层流体同注入溶剂在130℃时的最小混相压力；长岩心驱替实验分析气驱、水驱、水气交替注气的采收率、压力的变化规律。细管实验研究表明，最小混相压力为47．1MPa，长岩心注天然气驱替实验表现出近混相的特征。天然气驱注气压力低，采收率高，适合于文南油田低渗透挥发性油藏。     

低荧光阳离子防塌剂WFT─666的合成与性能

ＷＦＴ－６６６是由磺甲基腐殖酸钾、有机硅聚合物、低分子阳离子有机化合物、苯酚、甲醛缩聚而成的一种新型阳离子低荧光防塌剂。本文介绍了ＷＦＴ－６６６的合成及室内性能评定结果。ＷＦＴ－６６６可抗盐至饱和盐水，抗钙和镁，耐２００℃高温，荧光显示低。用该剂处理的钻井液性能稳定，流变参数合理，页岩回收率高，页岩相对膨胀率低，页岩稳定指数高，与其它处理剂的配伍性好。     

Solar ponds in alkaline lake and oil well regions

Solar ponds are probably the simplest technology available for the useful conversion of solar energy. The basic technology is proven. Solar ponds have been shown to be technically feasible and economically viable for many applications, particularly for thermal use. The electrical conversion and use of solar energy via solar ponds is still questionable, in general, for economic viability. By putting the untapped sources together in the South Plains region, it looks promising economically both for thermal and electrical conversions and applications. There are a number of alkaline lake basins randomly scattered in the South Plains region of the U.S.A. In that area, there are thousands of crude oil producing wells that produce brine in abundance. The selection of suitable alkaline lake basins as a solar pond site and as depository sites of brine from oil wells and the using of this brine and salty water from alkaline lakes makes the solar pond economically viable for both thermal and electrical demands in the area.