An experimental study on the effect of thinning band on the sheet formability in negative incremental forming

In negative incremental forming, a characteristic thinning band occurs on the parts when wall angles approach the maximum obtainable [D. Young, J. Jeswiet, Wall thickness variations in single point incremental forming, Proceedings of the Institute of Mechanical Engineers, Part B, Journal of Engineering Manufacture 218 (2004) 1453–1459]. The effect of this ultra-thin band on the fracture occurrence of part was studied in the current investigation. It was found that the occurrence of a thinning band on the test specimen of a formability test does not mean an effect on the test result. A reduction in the formability due to the occurrence of the thinning band occurs only if the specimen fractures in the flange area. In order to evaluate the real forming limit of a sheet metal, a condition regarding the occurrence of part fracture is proposed.     

Layered lithium cobalt nitrides: A new class of lithium intercalation compounds

Lithium cobalt nitrides Li_3−2xCo_xN (0.1 ≤ x ≤ 0.44) have been prepared and investigated as negative electrode in the 1/0.02 V potential window. The evolution of the unit cell parameters and unit cell volume with the Co content show a solid solution behaviour. Whatever the Co content, all these nitrides are electroactive with a single step around 0.6 V/0.7 V for the discharge and charge processes, respectively. The electrochemical behaviour observed is typical of a Li intercalation compound and involves the Co²⁺/Co⁺ redox couple in the interlayer plane combined with the reversible accommodation of Li⁺ ions in the cation vacancies located in Li₂N⁻ layers. XRD experiments performed after discharge, charge and cycling tests clearly indicate the hexagonal layered structure of the host lattice is maintained. This intercalation process explains the excellent capacity retention found after 50 cycles. A specific capacity of 180 mAh g⁻¹ at C/20 and 130 mAh g⁻¹ at C/5 rate (100 mA cm⁻²) is achieved for Li_2.23Co_0.39N. ac impedance measurements have allowed to characterize the kinetics of the reaction.     

A glow discharge unit to render electron microscope grids and other surfaces hydrophilic

We describe the design, construction, and operation of a simple glow discharge unit that can be used to make surfaces such as carbon-coated electron microscopy grids and glass coverslips hydrophilic. The use of a vacuum leak detector (Tesla coil) in place of a conventional high-voltage power supply and a small plastic desiccator for the vacuum chamber make the unit very inexpensive. Owing to the small volume of the chamber and the simplicity of the unit, the whole glow discharge process can be carried out in only 2 to 3 min, a time considerably shorter than that required for conventional vacuum evaporators. The hydrophilic surface improves adsorption of particles by several orders of magnitude in preparation for negative staining, freeze-drying, and other procedures.     

Rheological Properties of Quaternary Ammonium Gemini Surfactants in Aqueous Solution

The rheological properties and time effect of a quaternary ammonium salt gemini surfactant C_n‐s‐C_n?2Br solution were measured. The rheological properties were markedly different at various concentrations of the surfactant C₁₂‐2‐C₁₂?2Br solutions. When the alkyl chain of C_n‐2‐C_n?2Br solution is 14 or 16, the rheological properties of the solution exhibit fluid dilatancy very similar to C₁₂‐2‐C₁₂?2Br solutions. However, when the length of the spacer is four or six, C₁₂‐s‐C₁₂?2Br solutions exhibit Newtonian fluid behavior and are quite different from the C₁₂‐2‐C₁₂?2Br solution. A C₁₂‐2‐C₁₂?2Br solution at a high concentration shows negative thixotropy and time dependency.     

Lithium polyacrylate as a binder for tin-cobalt-carbon negative electrodes in lithium-ion batteries

A lithium polyacrylate (Li-PAA) binder has been developed by 3M Company that is useful with electrodes comprising alloy anode materials. This binder was used to prepare electrodes made with Sn₃₀Co₃₀C₄₀ material prepared by mechanical attrition. The electrochemical performance of electrodes using Li-PAA binder was characterized and compared to those using sodium carboxymethyl cellulose (CMC) and polyvinylidene fluoride (PVDF) binders. The Sn₃₀Co₃₀C₄₀ electrodes using Li-PAA and CMC binders show much smaller irreversible capacity than the ones using PVDF binder. Poor capacity retention is observed when PVDF binder is used. By contrast, the electrodes using Li-PAA binder show excellent capacity retention for Sn₃₀Co₃₀C₄₀ materials and a specific capacity of 450 mAh/g is achieved for at least 100 cycles. The results suggest that Li-PAA is a promising binder for electrodes made from large-volume change alloy materials.     

Study of the electrochemical hydrogen storage properties of the proton-conductive perovskite-type oxide LaCrO3 as negative electrode for Ni/MH batteries

LaCrO₃ was prepared by glycine combustion method and investigated as negative electrode for Ni/MH batteries. The structures of the as-calcined powder and the 20th charge-discharge cycle sample were characterized by XRD. The electrochemical experimental results demonstrated that the LaCrO₃ electrode showed excellent electrochemical reversibility and considerably high charge-discharge capacity at various temperatures. Except for the charge-discharge cycle at 298 K, the discharge capacities of LaCrO₃ electrode keep steady at 107.1 mA h g⁻¹and 285 mA h g⁻¹ at 313 K and 333 K after 5 cycles, respectively.     

认知行为综合干预对慢阻肺患者负性情绪的影响

目的探讨认知行为综合干预对慢性阻塞性肺疾病患者负性情绪的影响效果。方法对2008年1～8月在本院治疗的84例COPD患者,根据就诊时间编号,分观察组和对照组,2组患者均按医嘱予以治疗,并给予一般的COPD知识宣教。对观察组选择治疗时与患者及家属进行有效沟通,并采取认知行为综合干预。结果1年后,病人各观察项目经统计学处理,研究组各观察因子明显优于对照组,其中病人生活质量、症状自评量表各因子、药物治疗依从性等因数,除生理功能外,皆有显著意义(P<0.05)。2组患者戒烟情况,研究组为90.5%,对照组为36.4%。结论认知行为综合干预有效控制COPD病人病情进展,减少患者负性情绪,提高COPD患者治疗依从性和生活质量。     

Preparation of In0.5Sc1.5Mo3O12 nanofibers and its negative thermal expansion property

Orthorhombic In_0.5Sc_1.5Mo₃O₁₂ nanofibers were prepared by electrospinning followed by a heat treatment. The effects of post-annealing temperatures on the phase composition, microstructure and morphology were investigated by XRD, SEM, HRTEM and XPS. Negative thermal expansion (NTE) behaviors of the In_0.5Sc_1.5Mo₃O₁₂ nanofibers were analyzed by high-temperature XRD. Results indicate that the as-prepared In_0.5Sc_1.5Mo₃O₁₂ nanofibers show an amorphous structure with smooth and homogeneous shape. The average diameter of the as-prepared In_0.5Sc_1.5Mo₃O₁₂ nanofibers is around 515 nm. Well crystallized orthorhombic In_0.5Sc_1.5Mo₃O₁₂ nanofibers could be prepared after post-annealing at 550 °C for 2 h with an average diameter of about 192 nm. The crystallinity of In_0.5Sc_1.5Mo₃O₁₂ nanofibers gradually improved with the increase of annealing temperature. However, too high post-annealing temperature leads to a damage of sample's fiber structure. The high-temperature XRD results reveal that In_0.5Sc_1.5Mo₃O₁₂ nanofibers show an anisotropic NTE, and the coefficients of thermal expansion (CTEs) along a-axis and c-axis were −5.95 × 10⁻⁶ °C⁻¹ and -3.54 × 10⁻⁶ °C⁻¹, while the one along b-axis is 5.61 × 10⁻⁶ °C⁻¹. The volumetric CTE of In_0.5Sc_1.5Mo₃O₁₂ nanofibers is −3.90 × 10⁻⁶ °C⁻¹ and the linear one is 1.3 × 10⁻⁶ °C⁻¹ in 25–700 °C.     

多功能负氧离子纤维纱的开发

介绍了多功能负氧离子纤维的性能特点,结合生产实践,通过工艺试验,分析了纤维性能,纺纱工艺参数对多功能负氧离子纤维纯纺和混纺纱质量的影响,探讨了提高成纱质量的技术措施.     

Combining renewable sources towards negative carbon emission hydrogen

Multi-energy systems that combine different energy sources and carriers to improve the overall technical, economic, and environmental performance can boost the energy transition. In this paper we posit an innovative multi-energy system for green hydrogen production that achieves negative carbon emissions by combining bio-fuel membrane-integrated steam reforming and renewable electricity electrolysis. The system produces green hydrogen and carbon dioxide, both at high purity. We use thermo-chemical models to determine the system performance and optimal working parameters. Specifically, we focus on its ability to achieve negative carbon emissions.The results show that in optimal operating conditions the system can capture up to 14.1 g of CO₂ per MJ of stored hydrogen and achieves up to 70% storage efficiency. Therefore, we prove that a multi-energy system may reach the same efficiency of an average electrolyzer while implementing carbon capture. In the same optimal operating conditions the system converts 7.8 kg of biogas in 1 kg of hydrogen using 3.2 kg of oxygen coming from the production of 6.4 kg of hydrogen through the electrolyzer. With such ratios we estimate that the conversion of all the biogas produced in Europe with our system, could result in the installation of additional dedicated 800 GWp - 1280 GWp of photovoltaic power, or of 266 GWp - 532 GWp of wind power, without affecting the distribution grid and covering yearly the 45% of the worldwide hydrogen demand while removing from the atmosphere more than 2% of the European carbon dioxide emissions.