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排序方式: 共有2879条查询结果,搜索用时 15 毫秒
11.
Influence of pH on the passivation behavior of 254SMO stainless steel in 3.5% NaCl solution 总被引:1,自引:0,他引:1
C.T. Liu 《Corrosion Science》2007,49(5):2198-2209
The potentiodynamic polarization measurement of 254SMO stainless steel (UNS 31254) was conducted in 3.5% NaCl solutions with pH ranging from 0.1 to 5. The results indicated that this stainless steel offered excellent pitting corrosion resistance in corrosive environments. Further, it also exhibited various features on the polarization curves in different pH solutions. The electrochemical constant-potential passivation treatment performed at different pH followed by XPS analysis revealed that the primary constituents of the outermost layer of the passive films formed in the weak (pH 5) and strong (pH 0.8) acid solutions are iron oxides and Cr2O3 and Cr(OH)3, respectively. Molybdenum oxides, primarily in the six-valence state, existed in the outermost layer of the passive film. Only very weak signals corresponding to that of nickel oxides were detected in the film formed in the weak acid (pH 5) solution. The ICP-MS analyses indicated selective dissolution of a significant amount of Fe and a few Mo and Ni ions during the passivation treatment in the strong acid (pH 0.8) solution. No Cr dissolution was observed; this indicated that the Cr in the film is relatively stable. XPS depth profiling results showed that a similar bilayer-structured film was formed in both the solutions (pH 0.8 and 5); the outer layer of this film is primarily composed of Cr(OH)3 and Mo(VI), and the inner layer, Cr2O3 and Mo(IV). The results of the examinations of passive film formations and dissolution by XPS and ICP-MS were consistent with the polarization curves. 相似文献
12.
光纤接入一直是多年来人们不断追求的梦想和探索的技术方向,但由于成本、技术、需求等方面的障碍,至今还没有得到大规模推广与发展。然而,这种局面最近有了很大的改观,出现可迅速发展的势头。主要是因为一些国家政策的扶持、运营商竞争的需要、对收入的追求,以及设备本身价格的下降,光纤接入技术由于各种原因,至今尚未在全球广泛应用,但在日本、美国、瑞典和意大利等国都获得了较多的应用。在中国,光纤接入也有了良好的开端,将在大城市广泛应用,并逐渐推广到全国。 相似文献
13.
Six materials (stainless steel, nickel-base alloy, titanium, chromium, nickel and admiralty brass) are tested in chemical and biochemical synthetic seawaters. The biochemical seawater contains enzymes catalyzing oxidation of glucose (glucose oxidase), simulating the action of natural biofilms. The evolutions of free corrosion potential (Ecor) versus time, and of cathodic and anodic reactions are compared with those obtained in natural seawater. Then, electrochemical behavior is related to semi-conducting properties of passive films. When glucose oxidase is present, increase of Ecor versus time is only reported for materials presenting a n-type semi-conductor passive film, and whose cathodic reaction current is increased. On the contrary, when passive layers are p-type semi-conductors, cathodic and anodic reactions are increased, and lead to a global Ecor constant with time of immersion. It appears that interaction between bacteria, medium and materials includes evolution of semi-conducting properties of passive layers. 相似文献
14.
对于采用三相不控整流桥作为前级的变换器,自然条件下其输入电流波形系数不高,使得输入功率因数委低,降低了电源的利用率。为此需要采用功率因数提高技术,其中无源PFC是一类重要的功率因数校正技术,在某些场合非常具有应用价值。本文介绍了几种三相无源AC-DC变换器的高功率因数方案,如采用LC滤波器、移相电抗器,谐振电抗器,移相变压器,相间变压器,相间电抗器等,在进行简单的工作原理描述后,给出了部分方案的MATLAB/SIMULINK仿真结果。 相似文献
15.
L. Rutigliano D. Fino G. Saracco V. Specchia P. Spinelli 《Journal of Applied Electrochemistry》2008,38(7):1035-1041
This paper describes the results obtained from an electrokinetic treatment of a real soil polluted by lead acetate. Powdered
soil samples were pressed with a consolidometer till 100 kPa to obtain cylindrical specimens with the same characteristics
as a subsoil. Tests were carried out in a Perspex electrochemical cell where soil specimens were introduced with a hollow
punch. A low intensity direct current was applied in order to remove contaminants, due to electrophoresis and electroosmosis
phenomena. The water flow, conductivity, apparent electroosmotic coefficient, as well as other characteristic parameters,
were measured throughout the test. The water content and degree of pore saturation were estimated at the beginning and end
of the test. The soil slab was divided into four slices and the Pb concentration profile determined. The main factor governing
the extraction of contaminant was found to be the pH in the acidic range. Indeed, under these conditions high removal efficiencies
could be reached. These results could lead to the design of a new electrochemical treatment cell equipped with a cationic
membrane to expand the region of favourable pH within the soil. 相似文献
16.
机载红外搜索跟踪系统被动定位滤波算法研究 总被引:1,自引:1,他引:0
首先用扩展卡尔曼滤波算法构建了机载红外搜索跟踪系统被动定位滤波模型.然后针对该滤波算法要求先验的噪声统计及存在系统观测模型线性化误差影响滤波精度的特点.利用虚拟噪声技术,提出了适合于红外搜索跟踪系统被动定位的自适应扩展卡尔曼滤波算法。该算法实时地估计了虚拟噪声的统计特性,减小了线性化误差,提高了非线性滤波的精度。仿真结果表明,在完全相同的初始条件下,自适应扩展卡尔曼滤波对目标距离和速度的估计结果明显优于扩展卡尔曼滤波,此算法具有很高的工程应用价值。 相似文献
17.
宽带被动导引头天线系统性能分析 总被引:2,自引:1,他引:1
详细讨论了宽带被动导引头中的关键部件-超宽频带天线的性能,并在此基础上分析了三种具备大视角特性的被动测角方法。由于宽带天线没有确定的相位中心,因此不能采用通常的振幅和差式单脉冲法进行宽频带测角。本文提出的波束运算网络可用于一个宽带螺旋天线同时得到两个交叉波束的振幅-振幅式单脉冲系统中。此外,对比幅相干测向法中的测角模糊问题也进行了研究。 相似文献
18.
Dr GS Yakubu 《Renewable Energy》1996,8(1-4)
This paper presents a study of a user-experience survey about living in passive solar homes. It was carried out at the Energy Park located in the western part of Milton Keynes. The survey focuses on the reality of living in passive solar homes as perceived or experienced by the occupant. It is hoped that the findings would come to bear on strategic passive solar design decisions that would address the improvement of the well-being of the occupant.. The survey is aimed at assessing user satisfaction with the overall performance of their homes as well as a study of some of the problems that are believed to be common in passive solar housing.Results from the survey seem to indicate that the majority of those who buy passive solar homes are motivated to do so by a desire for thermal comfort at low cost. The building aesthetics is the second most important factor, showing that passive solar home lovers are also conscious of the quality of the architectural design. The overall performance of passive solar homes in this study, with regard to thermal and visual comfort, seems to be generally satisfactory. Statistical analysis showed some significant association between some important environmental design parameters. 相似文献
19.
A literature survey on buildings’ life cycle energy use was performed, resulting in a total of 60 cases from nine countries. The cases included both residential and non-residential units. Despite climate and other background differences, the study revealed a linear relation between operating and total energy valid through all the cases. Case studies on buildings built according to different design criteria, and at parity of all other conditions, showed that design of low-energy buildings induces both a net benefit in total life cycle energy demand and an increase in the embodied energy. A solar house proved to be more energy efficient than an equivalent house built with commitment to use “green” materials. Also, the same solar house decreased life cycle energy demand by a factor of two with respect to an equivalent conventional version, when operating energy was expressed as end-use energy and the lifetime assumed to be 50 years. A passive house proved to be more energy efficient than an equivalent self-sufficient solar house. Also, the same passive house decreased life cycle energy demand by a factor of three – expected to rise to four in a new version – with respect to an equivalent conventional version, when operating energy was expressed as primary energy and the lifetime assumed to be 80 years. 相似文献
20.
本文提出一种负载均衡模型,此模型不仅考虑AP的信号强度,而且要考虑现有AP已接入无线工作站的数量还有连接质量因素。除此之外,还讨论了实现此模型的无线协议的扩充。 相似文献