Secure authentication scheme for passive C1G2 RFID tags

Privacy and security concerns inhibit the fast adaption of RFID technology for many applications. A number of authentication protocols that address these concerns have been proposed but real-world solutions that are secure, maintain low communication cost and can be integrated into the ubiquitous EPCglobal Class 1 Generation 2 tag protocol (C1G2) are still needed and being investigated. We present a novel authentication protocol, which offers a high level of security through the combination of a random key scheme with a strong cryptography. The protocol is applicable to resource, power and computationally constraint platforms such as RFID tags. Our investigation shows that it can provide mutual authentication, untraceability, forward and backward security as well as resistance to replay, denial-ofth-service and man-in-the-middle attacks, while retaining a competitive communication cost. The protocol has been integrated into the EPCglobal C1G2 tag protocol, which assures low implementation cost. We also present a successful implementation of our protocol on real-world components such as the INTEL WISP UHF RFID tag and a C1G2 compliant reader.     

车载多层减振平台的主动控制及仿真

为了研究被动悬架车载主动减振平台的低成本控制策略及其减振效果,针对一种新型长宽比较大的多层减振平台,建立了车辆被动悬架与主动减振平台的一体化全系统动力学分析模型。进而,设计了"线性被动、旋转主动"的平台控制策略,并应用MATLAB及ADAMS软件,在三种典型路面激励下,进行了仿真测试。结果表明:采用垂向线性振动的多层被动减振、旋转振动的低成本主动控制策略,被动悬架车载减振平台的减振效果明显,实现了车载减振平台的高性价比设计。     

A Strategy of Liquid-Grafted Slippery Sponges with Simultaneously Enhanced Absorption and Desorption Performances for Crude Oil Spill Remediation

Crude oil spill accidents pose a worldwide environmental threat. Oleophilic and hydrophobic absorbents that can selectively absorb oil from water have shown promising application potential in oil spill remediation. Simultaneous optimization of the absorption and desorption speed of absorbents towards oil is highly desirable for their recyclable usage, but remains a great challenge, because these two properties are generally conflicting. Here, a facile and ingenious strategy is proposed to tackle the above challenge via surface modification of porous sponges with highly flexible linear polydimethylsiloxane (LPDMS) brushes. The LPDMS brushes feature liquid-like properties at room temperature owing to its extremely low glass transition temperature, and act as a covalently-grafted lubrication layer throughout the 3D network channels of the sponge, which can minimize contact angle hysteresis and reduce friction between oil and sponge channel. Compared to the prevalent cross-linked polydimethylsiloxane (CPDMS) modification strategy, sponges modified with LPDMS brushes not only shows significantly enhanced absorption speed, but also exhibits superior desorption dynamics towards viscous crude oils. The design strategy of slippery sponges with liquid-like molecules may open a new avenue for developing advanced absorbents with simultaneously enhanced absorption and desorption performances for liquid separation and purification applications.     

Influence of molybdenum on passivation of polarised stainless steels in a chloride environment

Polarised specimens of AISI 304L and 316L stainless steels (SS) were studied using X-ray photoelectron spectroscopy in conjunction with Ar⁺-ion sputtering. A 5% NaCl test solution was used at room temperature. The polarised passive films formed consist mainly of chromium oxide and hydroxide and a small proportion of iron oxides. The composition of the films depend strongly on the potential. Chloride and molybdenum ions appear when the AISI 316L SS alloy is polarised at a potential close to pitting potential.     

Passivation of Fe-Cr alloys studied with ICP-AES and EQCM

The response of sputter deposited Fe-15Cr and Fe-25Cr alloys to a rapid potential increase in the passive region was studied using two in situ methods: electrochemical quartz crystal microbalance and inductive coupled plasma-atomic emission spectroscopy (ICP-AES). Both methods indicated an increase in the dissolution rate of iron following the potential change; the total amount of material dissolved being higher for the Fe-15Cr alloy. For both alloys, about 10% of the total dissolved material was Cr. This result compared well with experiments on a 430 stainless steel. ICP-AES is shown to be useful for the in situ determination of partial currents of metal dissolution using solution analysis in a flow cell.     

Importance of initial surface film in the degradation of stainless steels by atmospheric exposure

The surface compositions of stainless steels types 304, 316, 430, and 444 combined with four types of surface finishes, 2B finish, hairline polishing, mirror polishing, and bright annealing, were measured by ICP-AES, EPMA, and XPS before exposure. The surface finish that most enriched the chromic species in the surface film was mirror polishing, followed by bright annealing, 2B finish, and hairline polishing. The order of corrosion-resistance was type 444, type 316, type 304, and type 430. The surface compositions were correlated with the rating number and pitting depth after exposure to atmospheric environments. The rating number had a high positive correlation with the concentration of Cr in the surface film, and had a slight correlation with the near-surface composition measured by EPMA at 12 kV, but did not show any correlation with bulk composition within the composition range covered in the present work. This same trend was observed for pitting depth. It was concluded that the cationic concentration of Cr in the surface film before atmospheric exposure is the prime factor in controlling the resistance of stainless steels to atmospheric corrosion.     

Behavior of laser welded steel in chloride solution studied using difference imaging

In situ imaging techniques in conjunction with electrochemical measurements were used to study the behavior of steel surfaces in simple chloride solutions. The imaging method detected the presence of significantly thicker uniform layers than the original passive oxide. The layers were found to form in chloride after the steel was anodically polarized following reduction of the passive oxide film. The growth of the layer depended on the degree of prior passive oxide reduction. Formation of the layer was also sensitive to underlying structure and enabled rapid location of regions of higher corrosion rate across laser welds in steels.     

Current transients of passive iron observed during micro-indentation in pH 8.4 borate buffer solution

Micro-indentation test of passive iron electrode in deaerated pH 8.4 borate buffer solution was carried out to investigate the rupture and repair of passive film. During driving a conical diamond micro-indenter with a load of 0.1 N order downward to the electrode and driving upward from the electrode, a couple of anodic current peaks were observed. The first current peak spiked during loading was responsible for partial exposure of iron substrate to the solution due to rupture of the passive film when the indenter tip contacted. The second peak emerged during unloading when elastic deformation recovered, which was ascribed to repair at the ruptured sites. The second peak current was larger than the first one. Both peaks were sensitively influenced by electrode potential or concentration of sulfate ions containing in solution. The model for a series of rupture and repair processes of the passive film by micro-indentation was proposed to discuss the current transients.     

Regional mass flux balancing for controlling gentle soil remediation operations

Extraction of heavy metals by accumulating plants is a method which is currently in development for the "gentle" remediation of contaminated agricultural soils (phytoremediation, see [2]). Areal contaminant mass flux balances are basic criteria for the design of such remediations and their control. A framework for the integration of contaminant balances relating the field scale of remediation with the regional scale of soil monitoring networks is provided by the recently developed method PROTERRA [3]. The objective of the study presented in this paper was to test the suitability of PROTERRA for planning and monitoring gentle soil remediations. For this purpose we applied the PROTERRA method to the contaminated agricultural land in and around Dornach, Switzerland, to assess copper flux balances.The calculations showed that atmospheric deposition and the application of pesticides and manure are important pathways for the inputs of copper. The copper export with a special maize cultivar accumulating heavy metals would be about three times higher than the average metal export with crops. A moderate increase of sewage sludge application would lead to a substantial increase of the copper input. Decisions to remediate the soil should take the uncertainty of mass flux balances both on field scale as well as on regional scale into account. Therefore, an important need of further development of the PROTERRA method is the integration of uncertainty analysis on both scales.     

修复土壤,腐植酸能做些什么

我国土壤污染形势严峻,已成为农产品安全和农业可持续发展的一大障碍."十一五"期间已将防治土壤污染列入重要议事日程,"全国土壤污染状况调查和防治项目"业已启动,2006年11月<农产品质量安全法>也开始实施.腐植酸学术界及行业又面临新的机遇和挑战.介绍了我国土壤污染的现状及其治理技术,阐述了腐植酸类物质(HS)修复污染土壤的研究进展、存在问题及应用的可行性,并对今后的研究开发及应用方向提出若干建议.