架空在“云”端的网络体系结构

随着近年来云技术的飞速发展,常规的数据网络在扩展性、带宽、规模、成本等方面都明显处于劣势地位,已经无法适应未来的发展需求。在这种情况下,云端网络技术在节约运算成本、提升公司运行效率方面有很好的效果。受到了企业的青睐。基于此本文对架空在“云”端的网络体系结构进行探讨。     

Pattern-induced multi-sequence alignment (PUMA) algorithm employing secondary structure-dependent gap penalties for use in comparative protein modelling

A multiple sequence alignment algorithm is described that usesa dynamic programming-based pattern construction method to aligna set of homologous sequences based on their common patternof conserved sequence elements. This pattern-induced multi-sequencealignment (PUMA) algorithm can employ secondary-structure dependentgap penalties for use in comparative modelling of new sequenceswhen the three-dimensional structure of one or more membersof the same family is known. We show that the use of secondarystructure information can significantly improve the accuracyof aligning structure boundaries in a set of homologous sequenceseven when the structure of only one member of the family isknown     

Heat Induced Structure Modifications in Polymer‐Layered Silicate Nanocomposites

Summary: The success of the use of layered silicates in polymer nanocomposites, to improve physical and chemical properties is strictly related to a deeper knowledge of the mechanistic aspects on which the final features are grounded. This work shows the temperature induced structural rearrangements of nanocomposites based on poly[ethylene‐co‐(vinyl acetate)] (EVA) intercalated‐organomodified clay (at 3–30 wt.‐% silicate addition) which occur in the range between 75 and 350 °C. In situ high temperature X‐ray diffraction (HT‐XRD) studies have been performed under both nitrogen and air to monitor the modifications of the nanocomposite structure at increasing temperatures under inert/oxidative atmosphere. Heating between 75 and 225 °C, under nitrogen or air, causes the layered silicate to migrate towards the nanocomposite surface and to increase its interlayer distance. The degradation of both the clay organomodifier and the VA units of the EVA polymer seems to play a key role in driving the evolution of the silicate phase in the low temperature range. The structural modifications of the nanocomposites in the high temperature range (250–350 °C), depended on the atmosphere, either inert or oxidizing, in which the samples were heated. Heating under nitrogen led to deintercalation and thus a decrease of the silicate interlayer space, whereas exfoliation was the main process under air leading to an increase of the silicate interlayer space.

Heat induced structural modification of EVA‐clay nanocomposite under nitrogen and air.     

银企互联中对账文件动态生成机制

针对银企互联中格式多样的对账文件,该文提出了两种动态文件生成机制。一种是基于结构体的动态文件生成机制,它利用了C语言中的结构体成员内存连续的原理,适用于对账明细数据源表固定的情况,但不适合多数据表的联合处理。另外一种是与动态SQL结合的文件生成机制,该机制不再局限于同一个数据源表,可以多表联合查询处理,同时又具备文件格式灵活配置的优点,适应范围更广,灵活度更高。     

γ‐Irradiation effects on the thermal and structural characteristics of modified,grafted polypropylene

The effects of both the degree of grafting and γ irradiation on the thermal stability and structural characteristic of polypropylene‐graft‐polyvinylpyrrolidone and polypropylene‐graft‐polyvinylpyrrolidone modified with α‐cyano‐δ‐(2‐thienyl) crotononitrile were investigated. The employed techniques were thermogravimetric analysis, differential thermogravimetry, and X‐ray diffraction. The thermal stability of various polymeric substrates was investigated through the determination of the degradation temperature and activation energy of degradation. The effects of different parameters on the structural characteristics of different films were investigated through the determination of possible changes in the degree of ordering of the polymeric substrates. The results revealed that the thermal stability of the trunk polymer, grafted polymer, and polymer modified by α‐cyano‐δ‐(2‐thienyl) crotononitrile increased progressively with an increasing degree of grafting. The increase was, however, more pronounced for the sample undergoing the lowest degree of grafting. The activation energy of the thermal degradation process remained almost unchanged, and this indicated that the degradation processes of the different films followed almost the same mechanism. The γ irradiation at a dose of 60 kGy of the sulfur‐treated polymeric films [i.e., the polymeric films treated with α‐cyano‐δ‐(2‐thienyl) crotononitrile] reduced their thermal stability. This conclusion was reached by the consideration of the changes observed in the pre‐exponential factor of the Arrhenius equation due to different chemical and γ‐irradiation treatments. The degree of ordering, evidenced by X‐ray diffraction measurements of the trunk polymer, grafted polymer, and modified polymer, suffered a significant drop. This drop was much more pronounced for the sulfur‐containing polymeric materials. The observed drop in the degree of ordering of the polymeric substrates was taken as a measure of the structure collapse due to a certain treatment (degree of grafting and sulfur inclusion). The γ irradiation of the sulfur‐containing polymeric materials greatly increased their degree of ordering, which reached a value greater than that measured for the trunk polymer. Therefore, it was concluded that the thermal stability increased as the degree of ordering decreased. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 506–515, 2006     

有机硅改性无皂丙烯酸酯类水分散体的合成技术及其产业化实践

介绍了以特殊结构的纳米无机体材料为骨架,采用无皂工艺合成的以有机硅材料进行改性的具有LIPN结构的丙烯酸酯类水分散体的性能及其产业化实践的情况,并对以该水分散体开发的水性木器涂料的性能作了对比说明。实践表明,以该丙烯酸水分散体开发的水性木器涂料较好地解决了目前水性木器涂料在硬度、光泽度、丰满度、回粘温度等方面不如溶剂型涂料的弱点,且该分散体的合成工艺独特、成本低廉,利于产业化和下游厂家开发使用。     

DaWson型磷钨钒杂多酸催化合成苹果酯的研究

制备了Dawson型磷钨钒杂多酸催化剂，用Fr—IR分析方法对催化剂进行了结构表征，并以乙酰乙酸乙酯与乙二醇为原料催化合成了苹果酯。实验结果表明，磷钨钒杂多酸是合成苹果酯的理想催化剂，其较优反应条件为：乙酰乙酸乙酯0．1 mol，n（乙酰乙酸乙酯）：n（乙二醇）=1．0：1．5，催化剂的用量为反应物总质量的1．5％，12mL甲苯，回流反应3．0h，苹果酯的收率可达83．0％以上。     

Pro／E软件在精密注射模具设计中的应用

利用三维软件进行设计代表了模具设计的发展方向,它有利于对模具进行实体造型、成型过程模拟以及模具缺陷检测分析的研究。在分析研究ProE进行精密注射模设计的基础上,介绍了应用Pro/Engineer2001进行模具设计的基本流程,应用软件中的一些功能对所设计的模具进行了检测分析,并通过一个具体的实例演示了该过程。     

Pore structure of bulk tungsten carbide powder catalysts

Bulk tungsten carbide catalysts are prepared by direct carburization/reduction of tungsten trioxide in methane-hydrogen mixtures. The catalytic properties of such catalysts have been studied by several authors. The porous structure of these catalysts is studied by adsorption of N₂, Kr, CF₄ and neohexane. Adsorption isotherms and hysteresis loops for the catalysts suggest the presence of a microporous structure made of parallel plates distant approximately by 20 Å. These results are compared to those obtained using such catalysts for hydrogen oxidation and where condensation in the porous structure was observed.