The Effect of Polymer Optoelectronic Properties on the Performance of Multilayer Hybrid Polymer/TiO2 Solar Cells

We report a study of the effects of polymer optoelectronic properties on the performance of photovoltaic devices consisting of nanocrystalline TiO₂ and a conjugated polymer. Three different poly(2‐methoxy‐5‐(2′‐ethylhexoxy)‐1,4‐phenylenevinylene) (MEH‐PPV)‐based polymers and a fluorene–bithiophene copolymer are compared. We use photoluminescence quenching, time‐of‐flight mobility measurements, and optical spectroscopy to characterize the exciton‐transport, charge‐transport, and light‐harvesting properties, respectively, of the polymers, and correlate these material properties with photovoltaic‐device performance. We find that photocurrent is primarily limited by the photogeneration rate and by the quality of the interfaces, rather than by hole transport in the polymer. We have also studied the photovoltaic performance of these TiO₂/polymer devices as a function of the fabrication route and device design. Including a dip‐coating step before spin‐coating the polymer leads to excellent polymer penetration into highly structured TiO₂ networks, as was confirmed through transient optical measurements of the photoinduced charge‐transfer yield and recombination kinetics. Device performance is further improved for all material combinations studied, by introducing a layer of poly(ethylene dioxythiophene) (PEDOT) doped with poly(styrene sulfonic acid) (PSS) under the top contact. Optimized devices incorporating the additional dip‐coated and PEDOT:PSS layers produced a short‐circuit current density of about 1 mA cm^–2, a fill factor of 0.50, and an open‐circuit voltage of 0.86 V under simulated AM 1.5 illumination (100 mW cm^–2, 1 sun). The corresponding power conversion efficiency under 1 sun was ≥ 0.4 %.     

Treatment of Humic Waters By Ozone

Two different generators for ozone were tested, a traditional electrical discharge generator and a generator based upon UV–irradiation of air at 150–180 nm. It was demonstrated that the traditional generator gave slightly higher reductions in levels of color for equivalent ozone dosages. Both gases affected the molecular weight distribution in the way that the bigger molecules were broken down to smaller ones. No significant difference between the molecular weight reduction efficiency of the gases was found.     

太阳能热管的研制和应用

介绍了太阳能热管发展的社会背景和历史沿革、太阳能热管单管的工质选择和管壳结构、热管式真空集热管的结构特点及太阳能热管在热水器中的应用     

PEO-b-PBA对天然橡胶/高吸水树脂共混体系增容作用的研究

通过扫描电子显微镜观察了天然橡胶和高吸水树脂共混体系的微观相态结构 ,研究了两亲性嵌段共聚物PEO b PBA结构本身的吸水能力对天然橡胶和高吸水性树脂共混体系吸水性能及力学性能的影响。结果表明 ,PEO b PBA结构本身的吸水强弱对共混体系的吸水能力贡献很小 ,但却可以显著提高共混体系的吸水膨胀能力和力学性能 ,对特殊的增容作用进行了探讨     

南水北调工程与管理

随着南水北调规划论证工作的深入，管理正成为南水北调工程的一个约束性课题。南水北调工程的建设管理应以各方利益的均衡为基础，投资分摊应适应公司化运作的建设管理体制，管理中应广泛借助外部力量；南水北调工程未来的运营管理必须结合建设提前考虑，在事权划分明晰的基础上，以现代科技手段为保障的合同化管理将是有效的手段。     

Continuous formation of slurry ice by cooling water–oil emulsion in a tube

Water-silicone oil emulsion with an additive, (C₂H₅O)₃SiC₃H₆NH₂, was examined as a heat storage material. A spiral tube used as a heat exchanger was immersed in a low temperature bath and the emulsion was circulated in the tube to make ice continuously. Ice was separated from the ice–liquid suspension in an outlet tank. The amount of formed ice, the temperatures of the inlet and the outlet of the heat exchanger, and the temperatures in the tube wall were measured and the overall heat transfer coefficient and the heat flux through the tube were calculated. Experiments were carried out, varying the flow rate, the temperature of cooling brine, and the thickness of tube wall. The condition under which slurry ice was formed continuously without adhesion of ice to the cooling wall was clarified. Though decrease in the thermal resistance of the tube increased the rate of ice formation or raised the brine temperature, it narrowed the range of the flow rate and of the brine temperature in which slurry ice was formed continuously.     

反向阳光间被动式太阳能空气采暖系统

介绍一种多层建筑中反向阳光间被动式太阳能空气采暖系统。它通过置于屋顶和地面的风管实现公寓中南部阳光间的太阳能得热向北部阳光间的自然传递。南部阳光间受热的空气上升，进入置于屋顶的风管，并通过这些风管流向北部阳光间；同时，南部阳光间置换出的空气被由北部阳光间的通过置于地面风管流向南部阳光间的较冷的空气所代替。由于系统还可用于东西阳光间之间，建筑物不受相对于太阳朝向的限制。     

腐植酸用于中央空调定期水质稳定处理

通过对腐植酸的应用试验 ,阐述了腐植酸有良好的阻垢、缓蚀性能 ,应用于中央空调循环水系统能取得良好的经济效益。     

填充料细度对水工沥青混凝土性能的影响

近年来沥青混凝土作为防渗材料，在我国水工建筑中得到了广泛应用。与道路工程的沥青混凝土不同的是，水工沥青混凝土具有良好的粘弹性及抗渗性。目前，国家规范对填充料的细度尚无明确规定，通过调整沥青混凝土的填充料细工，对沥青混凝土的各项性能进行了系统的试验和分析，研究表明：适宜的填充料细度及掺量，能有效地改善沥青混凝土性能，提高其抗渗性。     

基于空间平滑的矩阵分解算法

本文研究了协方差矩阵分解算法解相关的问题,提出了一种修正的矩阵分解算法-基于空间平滑的矩阵分解（SSMD）算法。SMMD算法能在低信噪比条件下的估计相干信源,且估计精度比原修正的算法高,计算量比原修正算法小,最后通过大量的计算机仿真实验来说明矩阵修正算法的性能。