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121.
试验用00Cr18Ni10N钢(/%:0.018C,0.41Si,1.68Mn,18.18Cr,10.38Ni,0.16N)经1t EAF-AOD-ESR冶炼,锻成Φ30 mm材和1 050℃固溶处理,进行了00Cr18Ni10N钢200~600℃光滑(Kt=1)、缺口(Kt=3)的轴向高周疲劳性能研究,绘制了疲劳S-N曲线、计算了疲劳极限,并对疲劳试样的典型断口进行了SEM观察。结果表明,光滑试样的疲劳极限随试验温度升高而降低,缺口试样的疲劳极限对试验温度变化不敏感。当应力集中系数由Kt=1提高到Kt=3时,00Cr18Ni10N钢的200、400、600℃下107周次条件疲劳极限分别从530、506、410 MPa,降低到323、370、392 MPa。表明在高温下00Cr18Ni10N钢存在疲劳极限对应力集中敏感,且应力集中敏感性随着试验温度的升高而降低。疲劳试样的断口形貌由疲劳源区、疲劳裂纹扩展区和瞬断区组成,疲劳起源于表面加工刀痕的不连续位置,呈韧性断裂特征。 相似文献
122.
叙述了新型双相不锈钢-WSD钢的组织及其耐蚀性能。试验结果表明,WSD钢在氯化物介显示出优异耐蚀性能,其抗点蚀性能远超过Cr13,18-8Ti,316L等钢种,达到国外Al-6X,SAF2205等钢种的水平。 相似文献
123.
轴对称与非轴对称截面冷拔棒材表面残余应力的比较 总被引:1,自引:0,他引:1
用物理测定法测定了矩形截面冷技型钢表面的残余应力,并与圆形截面冷拔型钢表面残余应力进行比较。提出用高温近火方法来改善矩形截面冷拔型钢表面残余应力的工艺探索。 相似文献
124.
125.
介绍高强度、大直径、低松弛预应力钢丝用高碳钢盘条在标准型斯太尔摩控制冷却线的生产实践。内容包括作业线概况、原料准备、工艺制度及实际结果和分析。 相似文献
126.
Rust layers formed on steel sheet piles immersed 1 m above the mud line for 25 years were analysed by Raman spectroscopy, scanning electron microscopy and elemental X-ray mappings (Fe, S, O). They consist of three main strata, the inner one mainly composed of magnetite, the intermediate one of iron(III) oxyhydroxides and the outer one of hydroxysulphate green rust GR(SO42−). Simulations of GRs formation in solutions having large [Cl−]/[SO42−] ratios revealed that the hydroxysulphate GR(SO42−) was obtained instead of the hydroxychloride GR(Cl−), as demonstrated by X-ray diffraction and transmission Mössbauer spectroscopy analyses. Measurements of the [S], [Fe] and [Cl] concentrations allowed us to establish that GR(SO42−) formed along with a drastic impoverishment of the solution in sulphate ions; the [Cl−]/[SO42−] ratio increased from 12 to 240. The GR, acting like a “sulphate pump”, may favour the colonisation of the rust layers by sulphate reducing bacteria. 相似文献
127.
The short term (∼100 h) oxidation behaviour of the 9%Cr steel P91 was studied at 650 °C in N2-O2-H2O gas mixtures containing a relatively low oxygen level of 1%. The oxidation kinetics were measured thermogravimetrically and the oxide scale growth mechanisms were studied using H218O-tracer with subsequent analyses of oxide scale composition and tracer distribution by MCs+-SIMS depth profiling. The corrosion products were additionally characterised by light optical microscopy, SEM-EDX and XRD. It was found that the transition from protective, Cr-rich oxide formation into non-protective mixed oxide scales is governed by the ratio H2O(g)/O2 ratio rather than the absolute level of H2O(g). The results of the tracer studies in combination with the data obtained from experiments involving in situ gas changes clearly illustrated that under the prevailing conditions the penetration of water vapour molecules triggers the enhanced oxidation and sustains the high growth rates of the poorly protective Fe-rich oxide scale formed in atmospheres with high H2O(g)/O2 ratios. The experimental observations can be explained if one assumes the scale growth to be governed by a competitive adsorption of oxygen and water vapour molecules on external and internal surfaces of the oxide scales in combination with the formation of a volatile Fe-hydroxide during transient oxidation. The formation of the non-protective Fe-rich oxide scales is suppressed in atmospheres with low H2O(g)/O2 -ratios, and the healing of any such scale is promoted. 相似文献
128.
129.
The corrosion inhibition of cold rolled steel in 0.5 M sulphuric acid in the presence of o-phenanthroline and sodium chloride (NaCl) has been investigated by using weight loss and electrochemical techniques. The experimental data suggest that the inhibition efficiency increases with increasing NaCl concentration in the presence of 0.0002 M o-phenanthroline, but decreases with increasing temperature. A synergistic effect is observed when o-phenanthroline and chloride ions are used together to prevent cold rolled steel corrosion in 0.5 M sulphuric acid. The polarization curves showed that the complex of o-phenanthroline and NaCl acts as a mixed type inhibitor. The experimental results suggested that the presence of chloride ions in the solution stabilized the adsorption of o-phenanthroline molecules on the metal surface and improved the inhibition efficiency of o-phenanthroline. The adsorption of the complex accords with the Langmuir adsorption isotherm. Some thermodynamic parameters such as adsorption heat, adsorption entropy and adsorption free energy have been calculated by employing thermodynamic equations. Kinetic parameters such as apparent activation energy and pre-exponential factor have been calculated and discussed. 相似文献
130.
5Cr21Mn9Ni4WNb2N奥氏体耐热钢晶界碳化物 总被引:1,自引:0,他引:1
5Cr21Mn_9Ni_4WNb_2N耐热钢锻造后在1200℃以上加热时,NbC聚集成大块,在1200℃以下加热时,NbC薄膜(片)的析出倾向随加热温度降低而增大,1130℃及其以下加热时,粒状和细片状M_(23)C_6随加热温度降低而增多,而且NbC块可作为碳源退化成M_(23)C_6颗粒,过高或过低温度的锻造加热,因晶界NbC块过大或晶界NbC薄膜(片)过多而不利于锻造加工。 相似文献