Isomerization of n-hexane over mono- and bimetallic Pd–Pt catalysts supported on ZrO2–Al2O3–WOx prepared by sol–gel

The catalytic performance of mono- and bimetallic Pd (0.6, 1.0 wt.%)–Pt (0.3 wt.%) catalysts supported on ZrO₂ (70, 85 wt.%)–Al₂O₃ (15, 0 wt.%)–WO_x (15 wt.%) prepared by sol–gel was studied in the hydroisomerization of n-hexane. The catalysts were characterized by N₂ physisorption, XRD, TPR, XPS, Raman, NMR, and FT-IR of adsorbed pyridine. The preparation of ZrW and ZrAlW mixed oxides by sol–gel favored the high dispersion of WO_x and the stabilization of zirconia in the tetragonal phase. The Al incorporation avoided the formation of monoclinic-WO₃ bulk phase. The catalysts increased their S_BET for about 15% promoted by Al₂O₃ addition. Various oxidation states of WO_x species coexist on the surface of the catalysts after calcination. The structure of the highly dispersed surface WO_x species is constituted mainly of isolated monotungstate and two-dimensional mono-oxotungstate species in tetrahedral coordination. The activity of Pd/ZrW catalysts in the hydroisomerization of n-hexane is promoted both with the addition of Al to the ZrW mixed oxide and the addition of Pt to Pd/ZrAlW catalysts. The improvement in the activity of Pd/ZrAlW catalysts is ascribed to a moderated acid strength and acidity, which can be correlated to the coexistence of W⁶⁺ and reduced-state WO_x species (either W⁴⁺ or W⁰). The addition of Pt to the Pd/ZrAlW catalyst does not modify significantly its acidic character. Selectivity results showed that the catalyst produced 2MP, 3MP and the high octane 2,3-dimethylbutane (2,3-DMB) and 2,2-dimethylbutane (2,2-DMB) isomers.     

气提式双锥干燥机的开发

介绍了双锥回转真空干燥机的一种改良型机种——气提式双锥干燥机。这种干燥机不但具有原机的优点，并且有效地解决了原机在干燥中易结块成团和大型化困难等问题     

热塑性聚合物/UP树脂混合体系的研究

采用本体聚合法合成具有一定转化率的热塑性聚合物TP ,并将其与不饱和聚酯 (UP)树脂混合 ,对所得混合树脂体系的流变性能、收缩性能、力学性能等进行了研究 ;利用动态力学方法分析了体系中热塑性聚合物与UP树脂的相容性 ,并对混合树脂体系进行了光学微观结构和红外光谱分析。结果表明 :TP与UP树脂间有一定的相容性 ,但并不完全相容 ;当UP树脂中加入TP 5份时 ,体系的粘度由 3Pa·s降为 2 5 5Pa·s ,收缩率由 1 77%降为1 45 % ;而加入 10份的TP ,树脂粘度降为 1 8Pa·s ,收缩率降为 1 3 9%。另外 ,体系的弯曲强度随TP加入量的提高而增加 ,但冲击强度的变化却呈先增加后降低的趋势。     

pH玻璃电极的现状与发展

对pH玻璃电极的结构、原理以及特性进行了综述.与液体充填式玻璃电极比较,固体接触式pH玻璃电极有明显的优点.叙述了固体接触式pH玻璃电极膜的成分及其响应机理,并指出固体接触式pH玻璃电极的发展方向.     

大力推进辽宁省石化工业结构优化升级

介绍了辽宁省石化工业中的结构性矛盾，提出了走新型工业化道路，推进石化产业结构优化升级的思路。     

我国节能减排的现状、问题与解决路径-一个文献综述

我国的节能减排问题日趋突出。本文从文献梳理角度对我国节能减排的现状、存在的问题以及解决路径进行了述评。研究显示,我国节能减排潜力巨大,节能减排效率低下。直接原因是由于我国产业结构、外贸结构、FDI 结构以及技术结构不合理造成的,但其背后更深层次的原因主要体现在：（1）GDP锦标赛下政治晋升制度的不合理导致了环境的负外部性;（2）激励与约束机制不完善导致政府缺乏节能减排的动力;（3）分税制的不完善导致了我国产业结构的不合理。为此,我们需要从优化产业结构、调整外贸结构、弱化 FDI的“污染避难所”效应以及增强技术进步效应入手,通过改革 GDP 锦标赛下政治晋升制度、完善激励与约束机制、调整财税体制等途径解决我国节能减排问题。     

Investigation of relaxation of nanodiamond surface in real and reciprocal spaces

The structure of a nanodiamond powder with an average grain size of 5 nm was investigated using large-Q neutron diffraction. Both Bragg scattering and PDF analysis were employed. The effect of annealing under vacuum at temperatures up to 1200 °C was studied. The studies lead to a tentative model of nanocrystalline diamond, where the core with a perfect diamond lattice is surrounded by a shell of compressed diamond lattice, and this core–shell structure is enveloped in a non-diamond carbon. The non-diamond envelope of nanograins, a “gas-like” carbon, is stable up to 1000 °C and transforms into a graphite phase (an onion-type structure) at about 1200 °C. The amount of non-crystalline carbon in the powder annealed below 1000 °C is about 10%. In the sample annealed at 1200 °C a graphite-type carbon, with a total of about 15% of sp² bonds is formed.     

Studies of structure and cycleability of LiMn2O4 and LiNd0.01Mn1.99O4 as cathode for Li-ion batteries

Lithium manganese oxides LiMn₂O₄ and rare earth elements doped LiNd_0.01Mn_1.99O₄ were synthesized by microwave method. The structure and the electrochemical performances of the samples were characterized. XRD data shows both samples exhibit the same pure spinel phase. But due to the introduction of Nd³⁺ ion into the unit cell, the lattice parameter of the Nd-doped spinel was larger than that of the undoped one. The two samples had a similar morphology including small particle size and homogeneous particle distribution as tested by SEM. The cyclic voltammmetry and constant-current charge-discharge tested that Nd-doped spinel displayed a better reversibility and cycleability.     

计算机网络入侵检测技术概述

防止网络入侵是网络安全中最重要的问题,网络黑客的入侵导致很多政府机关、企事业单位信息的泄露,因此,提高网络入侵检测的能力被提上了日程。本文对网络入侵检测从理论到实际进行了阐述,重点讨论了入侵检测系统的结构,使其有了很大的实用性。入侵检测是一种动态安全策略,文章从入侵检测技术的发展、检测系统的通用模型和分类以及检测方法四个方面对当前入侵检测的研究进行技术性综述,讨论了现有的入侵检测体系结构,详细分析了各种入侵检测方法,并在文中指出了当前入侵检测研究中存在的问题和今后发展的趋势。     

EH-4电磁成像系统在热储构造勘查中的应用研究

地热区的地球物理勘查工作主要是探测地热系统周边的热储构造情况,EH-4电磁成像系统具有不受高阻层屏蔽、轻便、探测深度大等优点。根据地热区热储构造的特点,研究了该套系统在热储构造勘查中的几个关键技术,重点分析了平行试验的重要性、过渡带数据特征及其校正方法。通过在江西某温泉已知热储构造上的实验研究,分析总结了EH-4电磁成像系统在热储构造勘查中应用的可行性及有效性。