膦化合物对加氢催化剂的影响

丁辛醇装置丁醛加氢催化剂在装置扩能投产以后热点上移 (失活 )的速率较快 ,针对催化剂老化的原因进行分析、判断 ,找出原因 ,采用相应的解决措施 ,可延长催化剂使用寿命 ,增加装置效益     

配置抗冲切钢筋的混凝土异形柱-板柱连接试验研究

在9个柱截面为三种典型异形柱(十字形、T形和L形) -板柱连接未配置抗冲切钢筋时的冲切特性试验基础上,以十字形柱-板柱连接为代表,通过三个配置抗冲切钢筋试件与三个未配抗冲切钢筋试件的对比试验,研究了异形柱-板柱连接配置抗冲切钢筋后的冲切特性,同时将锚栓和箍筋的抗冲切性能进行了对比。试验结果表明,抗冲切钢筋可以有效地提高板的受冲切承载力和延性,在改善延性方面,锚栓比箍筋更有效。另外,将国外几个主要规范ACI3 18、BS8110及MC90 ,关于对非矩形荷载面冲切临界截面周长的规定进行了比较,从试验结果看,ACI3 18规范的取法更合理。     

气相色谱毛细管柱对木糖醇产品的测定

本文提供了一种采用小口径毛细管柱测定木糖醇产品中各组分含量的气相色谱法。该方法采用氢火焰离子化检测器（FID），并用面积归一化法进行计算。实验结果表明该方法分离度高，色谱峰对称，平均回收率在95％以上，相对标准偏差均在1％之内，方法的重现性好。另外，该方法简单、方便、快速、准确，能满足分析检测的要求。     

弹性直杆热膨胀状态下的非线性振动

以ＫＢＭ法为基础，引进谐波平衡观点来研究弹性直杆热膨胀状态下的非线性振动．通过实例计算表明，弹性直杆热膨胀状态下非线性振动的频率对温度的变化非常敏感．     

多层住宅砖混房屋设计中两点问题的探讨

浅议多层住宅砖混房屋中构造柱的作用及设置方法；探讨了砖混结构墙下条形基础底面积重复利用问题及其解决方法。     

热场致发射电子源曝光系统的技术现状和应用前景

高亮度、长寿命的热场致发射(Thermal field emitter)阴极自七十年代中期已受到人们的关注和重视,历经十多年在理论分析、工艺制备和实验研究上做了大量工作之后,于1988年在电子束曝光机上的应用中取得了突破性进展。用晶向为(100)的钨和具有低逸出功的锆制成的(Zr/O/W)热场致发射阴极在四千小时的使用寿命下亮度值超过六硼化镧阴极一个数量级以上,最近的实验结果表明:在工件台上小束斑下能得到接近两千安培每平方厘米的束流密度,而且四十小时内束流稳定度接近千分之一。显然,这几个表征曝光系统综合技术性能的重要指标,说明多年困扰于各种电子束曝光系统(特别是高斯圆斑电子束系统)在高分辨率情况下生产率较低的技术难题已经得到了比较圆满的解决。 八十年代末期,当热场致发射电子源曝光系统的技术关键解决后,这项技术就成为技术发达国家,特别是美国和日本,在电子束曝光领域进行技术竞争的热点;九一年五月底在美国召开的国际三束会议上有关场致发射阴极和MEBES—4型机已经采用TFE的最新报道充分证实了这项技术在电子束曝光技术应用中的重要地位和发展潜力。     

Interaction between bubbles and fibre optic probes in a bubble column

Spherical bulb fibre optic probes, developed and applied for bubble characterization in a bubble column and a slurry bubble column at high temperature, were investigated. The principle of operation of these new optical fibre probes is based on the difference in refractive indices between the gas and the liquid phases. The interaction between the gas bubbles and the fibre optic probes in a bubble column was studied using photographic techniques. The first objective of these experiments was to study the response of the sensors upon contact with gas bubbles of various sizes. The second objective of this study was to establish, under controlled situations, the optical probe bubble detection performance and ability for local quantitative measurements of the bubble rise velocity and the gas hold-up.     

Kinetics of oxygen absorption in aqueous sodium dithionite solutions

The absorption and reaction of oxygen in aqueous alkaline solutions of sodium dithionite has been experimentally investigated in a novel gas-liquid contactor. The novel gas-lift bubble column contactor was used to study the kinetics over wide ranges of reactant concentrations, temperature, and pH. The oxygen-sodium dithionite reaction was found to be first-order with respect to dithionite in the range of dithionite concentration < 0.1 M, and second-order in the range of dithionite concentration > 0.1 M. The reaction with respect to oxygen was found to be zero-order for all dithionite concentrations. These results and experimental investigations of the effect of solution alkalinity and temperature on the reaction rate are consistent with previous findings obtained in different gas-liquid contactors. The results thus confirm the feasibility of using the gas-lift bubble column for the kinetics of gas-liquid reactions.     

异丁醛氧化制丙酮热导气相色谱分析

本工作用２米４０１有机担体填充柱，在带四臂热导检测器的国产１０３型气相色谱仪上，仅８分钟将原料异丁醛、产物丙酮及水进行良好分离，并采用内标法定量，其最大平均偏差在±２％以内。方法简单、快速、准确     

Erosion-corrosion of a stainless steel distillation column in food industry

Unusual extended corrosion phenomena were detected in a distillation column made in AISI type 316 stainless steel (UNS S31600) of a plant for natural pectins extraction from citrus. The column was the first of a series of two distillation columns representing the unit core. Corrosion problems were observed only in that column and mainly along the surface of the trays located in the lower section of the column. The phenomenon was observed subsequently to a modification of the original plant layout that caused an increase of the operating temperatures and turbulence of the process stream inside the column.