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961.
962.
S. Mahimairaja N. S. Bolan M. J. Hedley A. N. Macgregor 《Nutrient Cycling in Agroecosystems》1990,24(3):141-148
Kjeldahl nitrogen (N), total N and forms of inorganic N (ammoniacal (NH4)-N, nitrate (NO3)-N and nitrite (NO2)-N) were measured in a range of animal manures. The manures include fresh samples of poultry manure, sheep manure, horse manure, dairy slurry and pig slurry and composted poultry manure. Kjeldahl N was measured by standard micro-Kjeldahl digestion. For total N measurements, NO3-N and NO2-N were recovered during Kjeldahl digestion by pretreatments with various oxidizing and reducing agents. Inorganic forms of N were measured by extraction with 2M KCl solution.Kjeldahl digestion alone allowed measurement only of organic N and NH4-N. Amongst various modifications to the Kjeldahl, pretreatment with either acidified (H2SO4) Zn-CrK(SO4)2 or acidified (H2SO4) reduced Fe achieved complete recovery of NO3-N. Nitrite N was only recovered by first oxidising the NO
2
-
to NO
3
-
with KMnO4 followed by reduction to NH4-N with acidified (H2SO4) reduced Fe.More than 95% of the total N in fresh animal manure was present as organic N and NH4-N which were recovered by the standard Kjeldahl digestion. In the case of fresh manures there was no difference between the amount of total N measured by the Kjeldahl digestion and its modified methods. However composting of poultry manure or drying of poultry manure, pig slurry and dairy slurry resulted in an increase in NO3-N which was not recovered during Kjeldahl digestion alone. Under these conditions the total N could be measured by pretreating the samples with KMnO4 and reduced Fe prior to Kjeldahl digestion.Drying of animal manures caused a decrease in organic N and NH4-N, especially in poultry, pig and dairy manures. There was a slight increase in NO3-N; but most of the decrease in N content with drying was attributed to the volatilization loss of ammonia (NH3). Amongst various drying methods examined air drying caused maximum loss of N as NH3 whereas freeze drying caused minimum loss of N. This suggests that fresh animal manures can be freeze dried for analysis of N which causes minimum loss of N. 相似文献
963.
介绍研制的题示混合器结构及其混合机理。在分析球窝流场各节点速度分布的基础上,用加权平均总应变和分流混合度作为评定指标,对球窝型混合器的混合行为进行分析。通过对比实验证明球窝型混合器对于高粘流体具有良好的混合功效。 相似文献
964.
This paper examines the three dimensional approach of a neutrally buoyant sphere of any size to a circular hole in a plane wall at very low Reynolds number. The analysis differs from previous studies, largely applied to the multipore filter, in that the authors investigate the three dimensional hydrodynamic interaction of the sphere with the entrance geometry of the pore in the limit of zero inertia. The problem is first exactly formulated as the linear superposition of fundamental Stokes flows for rotation and translation of the sphere and flow past a stationary sphere. Approximate solutions are then obtained for the deviation of sphere trajectories from fluid stream lines and the results compared with laboratory model experiments in a low Reynolds number settling tank. The theory and experiment show that because of the hydrodynamic interaction sphere trajectories and fluid streamlines deviate significantly as the opening is approached, that all spheres eventually enter the pore regardless of their initial position, but that a non-uniform concentration profile develops with large increases in concentration near the walls of the orifice in the vicinity of the opening. The results provide a basic mechanism to explain the onset of Fahraeus phenomenon for red cells entering small blood vessels and glass tubes. 相似文献
965.
966.
The intrinsic viscosities of eleven narrow molecular weight distribution polystyrene samples ranging from number-average molecular weight 1820 to 1 292 000 have been determined in pure solvents of tetrahydrofuran and chloroform with a Ubbelohde No. 1 viscometer at 25°C. By combining the original and modified Fox-Flory viscosity treatments, respectively, with the Flory-Huggins Lattice theory, the interaction parameters were calculated. With the aid of original and modified UNIFAC methods the solvent activity, clustering function of the solvent, and the interaction parameter were computed and compared with the experimental data. It was established that the influence imposed by the polymer molecular weight on the activity of the solvent, the clustering function of solvent, and interaction parameter is insignificant. The modified UNIFAC method satisfactorily predicted the solvent activity as illustrated by previous investigators. However, both UNIFAC methods failed to predict the interaction parameter. 相似文献
967.
The dynamic mechanical relaxation of non-crystalline poly(aryl ether-ether-ketone) PEEK and the one irradiated with electron beam were studied. The three distinct γ, β, α′ relaxation maxima were observed in unirradiated PEEK from low to high temperature. It was revealed from the study on the irradiation effects that three different molecular processes are overlapped in γ relaxation peak, i.e., molecular motion of water bound to main chain (peak temperature; at ?100°C), local motion of main chain (at ?80°C), and local mode of the aligned and/or oriented moiety (at ?40°C). The β relaxation connected with the glass transition occurred at 150°C and it shifted to higher temperature by irradiation. The α′ relaxation which can be attributed to rearrangement of molecular chain due to crystallization was observed in unirradiated PEEK ~ 180°C and its magnitude decreased with the increase in irradiation dose. This effect indicates the formation of structures inhibiting crystallization such as crosslinking and/or short branching during irradiation. A new relaxation, β′, appeared in the temperature range of 40° to 100°C by irradiation and its magnitude increased with dose. This relaxation was attributed to rearrangement of molecular chain from loosened packing around chain ends, which were introduced into the non-crystalline region by chain scission under irradiation, to more rigid molecular packing, From these observations, we proposed that deterioration in mechanical properties of non-crystalline PEEK by high energy electron beam was brought about not only by chain scission but structural changes such as crosslinking and/or branching in the main chain. 相似文献
968.
The stoichiometric association constants, K, the thermodynamic association constant, KA, and the other thermodynamic parameters such as ΔS°, ΔH° and ΔG° for the association between each of the Ca and Mg ions with benzoate, o-toloate, o-chlorobenzoate and salycylate have been determined at 25°C, 35°C and 45°C in aqueous media. Ion-selective electrode technique has been used in the measurements of Ca and Mg ion activitiesThe trend of association behavior of both Ca and Mg aromatic salts could not be explained on the basis of pKa of the mother organic acids but could be explained based on the trend of Hammet function σ of these salts themselves relative to the corresponding benzoate salt. 相似文献
969.
Isotopic transient techniques were applied to study oxidative coupling of methane over lanthanum oxide and strontium promoted La2O3 catalysts. Results of the18O2/16O2 isotopic exchange experiments indicate that Sr promotion increases oxygen uptake from the lattice of the catalyst. Oxygen self diffusion coefficients, which were determined for the series of lanthana catalysts, reach a maximum for the 1% Sr/La2O3. Steps of18O2 in the presence of a steady flow of methane over Sr/La2O3 catalysts, indicate that surface and bulk oxygen appear in the reaction products before gas-phase18O2. Steps of CO2 over catalysts in which lattice oxygen has been exchanged with18O2, show that gas/solid exchange involves over 50% of the lattice oxygen. Under reaction conditions, methane pulses with no gas-phase oxygen yield negligible amounts of products which indicates that methane interacts with lattice oxygen only in the presence of the gas-phase oxygen. 相似文献
970.
吕继臣 《辽东学院学报(自然科学版)》2010,17(2):175-179,F0003
高等学校法人治理结构的关键在于权力分配与权利制衡,目标在于真正落实高等学校的办学自主权。只有以现存的治理制度与组织结构为基础,引入现代企业治理结构和国外高等学校法人治理的经验,对高等学校的科层制管理结构进行改良,建立符合我国国情的高等学校法人治理结构,才是落实办学自主全权,完善自我管理的必要出路。 相似文献