Shear-induced crystallization of poly(phenylene sulfide)

The crystalline morphology of poly(phenylene sulfide) (PPS) isothermally crystallized from the melt under shear has been observed by polarized optical microscope (POM) equipped with a CSS450 hot-stage. The shish–kebab-like fibrillar crystal structure is formed at a higher shear rate or for a longer shear time, which is ascribed to the tight aggregation of numerous oriented nuclei in the direction of shear. The crystallization induction time of PPS decreases with the shear time, indicating that the shear accelerates the formation of stable crystal nuclei. Under shear, the increase of spherulite growth rate results from highly oriented chains. The melting behavior of shear-induced crystallized PPS performed by differential scanning calorimetry (DSC) shows multiple melting peaks. The lower melting peak corresponds to melting of imperfect crystal, and the degree of crystal perfection decreases as the shear rate increases. The higher melting peak is related to the orientation of molecular chains. These oriented molecular chains form the orientation nuclei which have higher thermal stability than the kebab-like lamellae that are developed later. A new model based on the above observation has been proposed to explain the mechanism of shish–kebab-like fibrillar crystal formation under shear flow.     

Evaluation of improvement of physical and mechanical properties of bamboo fibers due to alkali treatment

Bamboo strips treated with caustic solutions of different concentrations, e.g., 5%, 10%, 15%, 20%, 25%, and 50%, were subjected to mechanical testing giving stresses on tensile strength, percent elongation at break, flexural strength, flexural modulus, and toughness. The change in average density was ?15%, and the weight loss value shows a maximum of 21.94% at 50% alkali treatment. The mechanical properties of bamboo strips increase steadily with increasing concentration of caustic soda, showing a comparable increased value at 15 and 20%, and then exhibiting a gradual fall. The percent elongation at break corroborates these observations showing a continuous decreasing trend. The properties under investigation exhibit a clear transition in between 15 and 20% alkali concentration. The morphology of strips was studied by scanning electron microscope and polarizing light microscope. The crystal structure of both untreated and treated strips was compared by XRD analysis. In both cases, the breakdown of the crystal structures of the cellulose fibers and the recrystallization or reorientation of the degraded chains that are devoid of hemicellulose are quite apparent. However, at a very high concentration (to the extent of 25%) the breakdown of structure predominates much more over the reorientation or recrystallization. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Mapping urban change in the UK using satellite radar interferometry

A multitemporal sequence of ERS interferometric coherence data acquired between 1993 and 1999 are utilised for automatically mapping urban change within South Wales, UK. Validation of the change map derived from the coherence data is performed using independent, multidate, digital survey data of the city of Cardiff, UK. All major building developments that have occurred within the study area are located. There is evidence to suggest that this approach is generalisable for a wide range of coherence data and to other regions with similar landscapes.     

Synthesis, Characterization, and Cytotoxicity Analysis of a Biodegradable Polyurethane

A polyester urethane was synthesized for use in a biodegradable scaffold. The polyurethane was synthesized in a two-step process: first, ester diol was synthesized from lactic acid and polyethylene glycol 400 (PEG 400), then it was polymerized with toluene diisocyanate using dibutyl tin dilaurate (DBTDL) as a catalyst to form a polyester urethane. Polyester urethane has tensile strength of 51-59 MPa and elongation at fracture of 369-439%. FTIR and XRD were used to confirm the formation and structure of the polymer. Hydrolytic degradation was studied in different alkali solutions and in saline water. In order to assess the cellular response of this material, cytotoxicity analysis was carried out against the cell line.     

Modeling the effect of pigment morphology on the dynamic compression of coating layers using DEM

In the present paper, discrete element method (DEM) was employed to investigate the effect of pigment morphology on packing dynamics and compressive behavior of paper coating layers in calendering process. Spherical, platy, and needle-like particles, representing GCC, delaminated clay, and aragonite PCC pigments, were considered in this study. For each particle shape, the compression of coating structures formed by mono-sized and poly-dispersed pigments were modeled. Stress–strain behavior of the coating layers and in-plane and out-of-plane movements of the pigment particles during the compression were computed under the same maximum compressive stress. Simulation results revealed that the in-plane movements of the pigment particles during compression in the calender nip were small in magnitude (<0.35 μm). These findings help to better understand the smoothening phenomena of coating structures during the calendering process.     

A unified framework of opening and closure operators with respect to arbitrary fuzzy relations

 This paper is devoted to a general concept of openness and closedness with respect to arbitrary fuzzy relations – along with appropriate opening and closure operators. It is shown that the proposed framework unifies existing concepts, in particular, the one for fuzzy preorderings as well as the triangular norm-based approach to fuzzy mathematical morphology. The author acknowledges support of the K _plus Competence Center Program which is funded by the Austrian Government, the Province of Upper Austria, and the Chamber of Commerce of Upper Austria.     

形态学边缘检测的新算法及其应用

提出了一种基于数学形态学的边缘检测的所算法，该算法具有简便和灵活可编程控制等优点，比原来主算法更国完善，在实际应用中有着很好的前景，并给出了实验结果。     

河流地貌特征多样性的保护

河流作为一个有机的生态整体与生物多样性共存,构成了一种相互耦合的生态系统.河流丰富的地貌形态为流域生物多样性创造了很好的条件,是生物群落多样性的基础.现代水利工程应该克服对河流形态的多样化重视不足和忽略生态环境的缺陷,在治河过程中,尊重河流流域的自然状况,尊重各类生物的生存权利;认识并遵循河流地貌演变的客观规律,逐步完善河流生态工程建设措施;保护河流地貌形态特征多样性,为生物的生长、繁殖、栖息提供条件,达到保护河流生态系统多样性,维持河流系统健康的目的.     

Pulsed laser deposition of indium antimonide

Single crystalline oriented films of indium antimonide have been grown on cadmium telluride substrates by the pulsed laser deposition technique. The films were (111) oriented which is the substrate orientation. The composition of the grown films were found to deviate from that of the target owing to loss of antimony during evaporation. This deviation from stoichiometry led to film-substrate reaction, resulting in mixed interface. The antimony deficiency in the films were controlled by correcting the stoichiometry, which led to avoiding mixed interfaces. The stoichiometric films showed good surface morphology and well defined sharp interfaces. The IR transmission spectrum showed sharp band to band absorption and effective detection in the MWIR. Paper presented at the poster session of MRSI AGM VI, Kharagpur, 1995     

Film morphology and reaction rate for the CVD of tungsten by the WF6—SiH4 reaction

Journal of Electronic Materials - Low pressure chemical vapor deposition (LPCVD) of tungsten (W) by SiH4 reduction of WF6 on Si(100) surfaces was studied in a single-wafer, cold-wall reactor over a...