The time dependent strain potential function for a polymeric glass

Torsion and normal force measurements were made during single step stress relaxation experiments on a polymeric glass (PMMA). Isochronal data were analysed using an approach adapted from that developed by Penn and Kearsley¹ (for incompressible elastic materials) to determine the derivatives $\text{?W}\text{?I}{}_1$, and $\text{?W}\text{?I}{}_2$ of the time dependent strain potential function. $\text{?W}\text{?I}{}_1$ and $\text{?W}\text{?I}{}_2$ are determined from existing solution to the torsion of an incompressible cylinder. A special solution to the torsion of a compressible cylinder is presented and it is shown that the values of $\text{?W}\text{?I}{}_1$ and $\text{?W}\text{?I}{}_2$ obtained using this solution to analyse the data do not differ greatly from those obtained using the incompressible solution. It is found from both solutions that $\text{?W}\text{?I}{}_1$ is negative and increases towards zero with increasing time and deformation while $\text{?W}\text{?I}{}_2$ is positive, greater in magnitude than $\text{?W}\text{?I}{}_1$ and decreases towards zero with increasing time and deformation. These results were unexpected and a full understanding of their meaning has yet to be reached.     

带谐波抑制策略的三电平脉冲整流器仿真研究

以城轨牵引供电系统中网侧变流器为研究对象,根据单相三电平脉冲整流器等效数学模型,应用瞬态电流控制策略,加入中点电位平衡策略,给出控制策略数学模型和控制方程.并根据脉冲整流器低次谐波消除原理,对该控制策略下,加入整理器低次谐波消除策略前后,脉冲整流器网侧和直流侧输入输出状态进行仿真研究.     

Effects of a strong polyelectrolyte on the rheological properties of concentrated cementitious suspensions

Strong polyelectrolytes, referred to as superplasticizers, are known to improve the initial fluidity of concentrated cement suspensions. To quantify how the polyelectrolytes affect the fluidity, we have studied the effect of a strong anionic polyelectrolyte, melamine formaldehyde sulfonate (MFS), on the zeta potential of cement particles and on the steady-shear and low-amplitude rheological properties of cement suspensions. Adsorption of low concentrations of MFS onto the cement particles leads to an inversion in the sign of the surface potential, causing the electrostatically flocculated particles to become electrostatically dispersed and giving rise to a corresponding decrease in the steady-shear viscosity and storage modulus. At an intermediate MFS concentration, the steady-shear viscosity and the storage modulus each display a minimum. This concentration corresponds to that at which the zeta potential becomes constant. Larger concentrations of MFS result in an increase in the viscosity and storage modulus, which is attributed to depletion flocculation. These results thus relate the interaction between particles to the suspension fluidity through the analysis on the surface potential of particles and microstructure of suspension.     

HOW LIQUIDS SPREAD ON SOLIDS

A theory of the wetting of solids by liquids is put forward. The theory accounts for capillary pressure gradient, gravitational potential gradient, surface tension gradient, disjoining pressure gradient driving forces of flow in thick thin-films and of surface diffusion in thin thin-films. Disjoining pressure stems from the way intermolecular forces aggregate in submicroscopically thin films. For thick thin-films of slowly varying thickness the lubrication approximation to velocity distributions is appropriate. With this approximation the spontaneous, unsteady, two-dimensional spreading of liquid is shown to be governed by a nonlinear convective-diffusion equation for the evolution of the film thickness profile. The predictions of the theory agree with Marmur and Lelah's (1980, 1981) observations of water drops spreading on glass and with Bascom, Cottington and Singleterry's (1964) and Ludviksson and Lightfoot's (1971) observations of oils spreading on high energy surfaces. The theory is used to analyze Derjaguin and co-workers' (1944, 1957, 1970) blowing-off experiments designed to measure thin-film rheology. The theory is also used to buttress the proposition that much contact angle hysteresis is due simply to slow attainment of equilibrium.     

塔里木河“二源一干”生态供水潜力研究

为解决塔里木河干流水资源短缺、流域损失水量过大、用水效率低下、农业灌溉用水挤占生态用水等问题,基于“节水优先”的治水方针,以塔里木河二源流(阿克苏河、叶尔羌河)及其干流(“二源一干”)的山区水库群和平原水库群为研究对象,兼顾塔里木河干流的农业灌溉用水、生态用水、工业用水、生活用水等多目标,构建并求解了现状水平年和远景规划年的山区与平原水库群联合调度优化模型,分析了塔里木河干流的生态供水潜力和山区水库群联合调度的贡献。结果表明：仅通过干流平原水库群联合调度,农业灌溉用水和生态用水的供水保证率难以满足设计要求;通过山区与平原水库群优化调度,在远景规划年各行业均满足设计保证率要求,体现了山区水库群显著的调控性能和“节水优先”治水方针的合理性和可靠性;远景规划年塔里木河干流的生态供水潜力为2.84亿m³,可为塔里木河下游生态保护与修复提供了坚实的水量基础。     

基于客户喜好的双向个性化推荐算法

为了解决现有推荐算法仅考虑同类产品间单向推荐所缺乏的灵活性,提升产品的销量及用户的购物体验,提出一种基于客户喜好的双向个性化推荐算法,不仅可以为客户精准推荐产品,还可以为商家推荐潜在客户.首先,基于产品购买网络中客户及其邻居的购买信息,扩展客户购买信息;其次设计客户产品喜好权重计算办法,分析客户的购买喜好,并在客户喜好的指导下为客户提供个性化的产品推荐;最后,基于商家提供的样本客户,挖掘与样本客户相似的客户构成社区,为商家提供潜在客户推荐以及精准客户维护.在真实数据集上的实验验证了算法的有效性.该算法从客户和商家两个维度出发实现了产品与客户的双向推荐,为个性化推荐领域的研究提供有益的帮助.     

基于功率分配的空间耦合数据传输性能分析

通过研究功率分配对空间耦合数据传输的性能影响,在空间耦合数据流间干扰完全消除的情况下,利用密度进化与势能函数证明了等功率传输性能最优.为了以较少的性能损失为代价,减少等功率传输引起的高检测复杂度,提出了一种功率分配算法实现非等功率传输.外信息转换图分析和仿真结果证实了理论分析的正确性和所提算法的可行性.     

基于集对分析联系数的合肥市水资源承载力评价

为科学指导合肥市水资源综合规划与管理,在综合分析水资源承载力与水资源-社会经济-生态环境系统相互关系的基础上,从支撑力、压力、调控力子系统选取13项指标,建立合肥市水资源承载力评价指标体系,运用集对分析联系数评价模型对合肥市2011-2016年水资源承载力进行综合评价。结果表明:合肥市2011-2015年水资源承载力评价等级为3级,2016年为2级,整体形势严峻,承载能力较差,但已有所改善,发展趋势良好;运用减法集对势理论,确定指标人均水资源量、产水模数、植被覆盖率、人口密度、水资源开发利用率、生态用水率是导致合肥市水资源承载力不足的主要因素。     

砾石土质条件下葡萄滴灌生育期土壤含水率变化规律研究

为探究酿酒葡萄在砾石土质条件下的土壤含水率变化规律及合理灌溉制度,选取贺兰山东麓砾石土典型试验区,以五年生赤霞珠品种为研究对象,设计2 550、2 850、3 225、3 600 m3/hm24个不同定额的灌水处理,应用TDR土壤水分剖面仪和土壤水势仪,监测生育期滴灌前后不同土层含水率与水势变化,针对监测数据从灌水处理整体与单个生育期不同角度进行分析,研究酿酒葡萄在砾石土条件下不同滴灌定额土壤含水率变化规律,最终提出生育期适宜灌溉制度。研究结果表明:随着灌溉定额的增加,土壤含水率在0~40cm土层范围内变化较明显;不同深度土层土壤水势变化规律与灌溉定额的大小有关;1m深土壤水分蓄存比并不是随着灌水量的增加而增大,而是当灌水量达到某一定额时,随着灌水量的增加,土壤水分蓄存比减小,砾石土单次灌水量高于300 m3/hm2时,土壤水分蓄存比较低,易产生深层渗漏。     

镁质低品位铁镍硫化矿的活化工艺及机理

细菌浸出是镁质低品位铁镍硫化矿的潜在处理方案之一。针对该矿石浸出活性较低的问题,研究了硫酸预浸出和硫酸铵焙烧预浸出2种活化方案,并与细菌直接浸出(空白试验)做了比较。结果表明,2种活化方案都有利于金属回收,但硫酸铵焙烧预浸出方案的活化效果更优:浸出时间为8 d时,Ni、Cu和Mg的浸出率分别为90.2%、89.56%和61.19%,分别高于硫酸预浸出方案2.08%、12.2%和8.95%。矿石中的Mg主要在硫酸铵焙烧预浸出阶段进入溶液,细菌对Mg浸出的影响不大。XRD和能谱分析表明:浸出渣中Ni和Cu的残留量很低,Mg主要存在于难浸出的蛇纹石之中。