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91.
Free radical emulsion polymerization of methyl methacrylate (MMA) and 2‐ethylhexyl acrylate (EHA) results in the synthesis of pressure‐sensitive adhesives (PSAs) with good tack properties. Management of both the copolymer composition and the polymerization process allows one to control the behavior of the PSA. Semicontinuous (SC) processes create polymer particles whose instantaneous composition is close to that of the feed particle The SC Mixture process (continuous feeding with comonomer blends) affords nearly homogeneous latex particles and PSA films. The SC Gradient process (separate feedings at inversely varying rates) affords heterogeneous particles and films. The Batch process leads to somewhat heterogeneous films, but the hard (MMA‐rich) microdomains are made compatible with their soft (EHA‐rich) matrix because of the assumed formation of tapered‐type copolymers. Tack measurements indicate the importance of the particle and film structures. Too much hardness or softness leads to unacceptable lacks of adhesion and cohesion, respectively. Homogeneous structures prove adequate, but their tack properties collapse with rising temperature. Heterogeneous structures, with extensive phase segregation, prove unsatisfactory because they lack adhesion and cohesion. Finally, the association of well‐balanced composition and compatible heterogeneity is the criterion for suitable PSA behavior. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2749–2756, 2003 相似文献
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93.
本详细描述了移动IP的工作过程,并介绍了移动IP的隧道技术和IPSec,最后对移动IP技术中存在几个热点问题进行了讨论。 相似文献
94.
Unconrolled agglomeration of particles and adhesion of the particulate mass to wall surfaces are common severe problems in many drying operations. This paper reviews the mechanisms of interparticle and particle-surface attraction as well as the theory and the existing tests for characterising powders in terms of internal strength, wall friction and adhesion. The usefulness of the information obtained from these tests in dryer design and operation is critically reviewed. The importance of powder stickiness in various types of dryers is discussed and established methods of combating the problem are presented Recommendations an made for further research in the area of powder cohesion and adhesion. 相似文献
95.
A series of short fibre reinforced styrene butadiene rubber (SBR) composites were prepared by incorporating sisal fibres of
different lengths and different concentrations. The vulcanization behaviour and the properties of the vulcanizates were measured
by the relevant ASTM procedures. The processing characteristics such as green strength and mill shrinkage were improved by
the addition of fibres. The properties like tensile strength, tear strength, moduli at 10% and 20% elongations were found
to be maximum for composites containing longitudinally oriented fibres of length 6 mm. Mixes containing 35 phr loading of
fibres and bonding agent showed better mechanical performance than others. The failure behaviour of tensile and tear specimens
have been analysed by scanning electron microscopy techniques.
Paper presented at the poster session of MRSI AGM VI, Kharagpur, 1995 相似文献
96.
用粘土熟料、软质粘土及复合结合剂研制的胶结剂,用于马克法铸钢输铝管系统的胶结,其使用性能和使用寿命达到或超过了进口胶结剂的水平。 相似文献
97.
聚丙烯表面改性及与涂料的粘结 总被引:3,自引:2,他引:1
刘景江 《高分子材料科学与工程》1992,8(5):1-5
讨论了聚丙烯制品喷涂着色的优点及影响聚丙烯制品与涂料之间粘结强度的各种因素。综述和评价了对聚丙烯进行表面改性的必要性及各种表面改性方法。 相似文献
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