不同活化剂对石油焦基活性炭孔结构的影响

以石油焦为原料 ,Na OH,KOH和 Na2 CO3 为活化剂制备活性炭 ,采用氮气吸附考察了不同活化剂对活性炭的比表面积、中孔和微孔孔径分布、孔容积及平均孔径等孔结构的影响 .结果表明 :KOH活化制备的活性炭包含 1 nm的微孔和 4nm的中孔 ,总孔容 0 .648cm3 /g,比表面积大 ;Na OH制备的活性炭以 1 nm的微孔为主 ,占总孔容 ( 0 .1 65 cm3 /g)的 98% ,平均孔径 1 .83nm;Na2 CO3 制备的活性炭以 4nm的中孔为主 ,占总孔容 ( 0 .1 43cm3 /g)的 68.5 % ,平均孔径 3.42 nm,比表面积小 .3种样品的孔径都呈现出多峰分布特征 .KOH和 Na2 CO3 活化制备的活性炭的 N2 吸附脱附曲线属于 型 ,Na OH活化制备的活性炭吸附脱附曲线属于 型 .     

Surface Areas of Nitrated Hydrotalcites

Hydrotalcites in the nitrate form were prepared using microwave irradiation in the hydrotreatment step. The surface area (BET) of nitrated hydrotalcites was evaluated. Solids were characterized by atomic absorption, X-ray diffraction and BET analysis. Thermal pretreatment temperature determined the surface area of the hydrotalcites.     

Carbon Aerogels as Electrode Material in Supercapacitors

Due to their large specific surface area and their high electrical conductivity carbon aerogels are promising materials for electrodes in electrochemical double-layer capacitors (supercapacitor). The carbon aerogels were made via pyrolysis of resorcinol formaldehyde aerogels. The latter were prepared by supercritical and subcritical drying as well. The important findings of our investigation were, that the highest capacities of 46 F/cm³ were measured for samples with a density of about 800 kg/m³ pyrolyzed at 800°C. Also it was shown that RF-gels with molar resorcinol/catalyst ratios 1000 or higher can be dried subcritically without cracking or significant shrinkage. Carbon aerogels derived from these RF-aerogels have a small mesopore surface area, however an especially large micropore area. They provide electrical capacities which are most suitable for their use in supercapacitors.     

PVA基活性碳纤维的研制

探索了由民用大丝束聚乙烯醇纤维(PVAF)试制活性碳纤维(ACF)的可能性,以开辟新的原料路线,降低产品成本。PVAF首先用脱水剂处理,脱水剂浓度为10%(质量),然后在200—300℃进行热处理,处理后的纤维再经预氧化和碳化活化转化为ACF,ACF的收率为37.7%,比表面积为1050m~2/g。此外,还探索了用O_3处理PVAF。用差热、热失重和红外等手段对产物进行了表征,推论了相应的反应机理。结果表明:经适当处理的PVAF可制得具有较好吸附性能的ACF。     

论局域网的安全防范

网络技术、通信技术和计算机技术的突飞猛进使得很多的企业单位、机关部门和学校搭建了属于自己的局域网.信息安全问题是局域网实际应用过程中最受关注的问题.本文阐述了局域网安全的内涵和意义,分析了目前局域网安全防范中存在的问题,并根据笔者的实际经验给出了有效增强局域网安全防范的相关建议.     

Analysis of junction temperatures in high-power GaN-based LEDs

We presented the analysis of the incomplete conduction in bonding medium in high power GaN-based light-emitting diode (LED) packages. A numerical study was carried out with parametric model to understand the junction temperature variation due to bonding medium defects. Transient thermal measurement was performed to evaluate LED’s junction temperature. Thermal resistance from chip to lead frame was 20 K/W in our sample LED. It was suggested that only 60% of the surface area of the bonding medium was involved...     

信息化系统在滦河下游灌区管理中的应用

针对滦下灌区设备老化、管理落后的问题,按照经济实用、运行稳定、技术先进、随时升级的原则,对滦下灌区管理处进行了灌区信息化建设.灌区信息化系统主要包括自动化采集、自动化控制、智能化调度3大功能,初步实现了自动采集数据、遥控启闭闸门、远程屏幕监控、智能磁卡收费等功能.该灌区管理系统自应用以来成效明显,可为我国其他灌区自动化改造借鉴.     

Zipf定律在划定经济区域内的实证研究——以长江三角洲经济区为例

国外关于Zipf定律的实证研究的区域空间多采用国家层次,而国内关于Zipf定律的实证研究则涉及国家、跨省的经济区及行政省的不同层次,于是这就有可能存在经济区域空间划定是否合理的问题。现以长江三角洲地区为例,通过修正的引力模型计算城市之间的经济联系强度及潜能,以此进行长江三角洲经济区域的空间划定,并在划定的经济区域内进行Zipf定律的实证研究,以验证经济区域空间划定是否合理。研究结果显示了经济区域空间划定的合理性。     

双足机器人行走稳定性研究

双足机器人行走的稳定性是双足行走最为重要的衡量指标之一.针对传统的基于零力矩点（ZMP）步态稳定性判据方法,分析了ZMP、COP的相互关系,表明在双足机器人与水平地面无粘性力和无吸附力作用下,其ZMP即为压力中心点COP.基于具有足趾关节的双足机器人足底支撑面多种变化,提出对多点接触时支撑多边形区域描述.结合ZMP/COP、COG的在支撑面内相对位置,提出了基于ZMP/COP、COG的综合稳定性判据.经仿真分析,与传统单一的ZMP稳定性判据相比,该综合稳定性判据能够更为准确地反映步态的稳定性.     

Renewal strategies for old industrial areas in the post-industrial age—Take “Zurich-West” in Switzerland as an example

This paper introduces and analyses the renewal planning of “Zurich-West”, an old industrial area. It points out that systematic and comprehensive target orientation, extensive collaboration in argumentation and decision-making, and the design ideas of coexistence and integration are the key to its success. Considering the status quo of China’s old industrial district remodeling, the paper offers some suggestions. Supported by the National Natural Science Foundation of China (Grant No. 50878045)