聚醚型聚氨酯的氢键、微相分离及性能

用本体一步法合成了5种不同硬段含量(11.0％～46.9％)的二苯甲烷-4,4′-二异氰酸酯/环氧乙烷封端型聚环氧丙烷聚醚/乙二醇的聚醚型聚氨酯,并借助于IR,DSC,DMS和材料试验机等手段对该聚氨酯的氢键、微相分离及力学性能进行了表征。结果表明:随着硬段含量的增加,其>NH与微区中的>C=O的氢键化程度逐渐提高,软段微区中—O—的氢键化程度逐渐降低;微相分离程度逐渐提高;拉伸强度及硬度随之增加,扯断伸长率在硬段含量40％左右出现极大值。     

Structure of resorcinol,phenol, and furan resins by MALDI‐TOF mass spectrometry and 13C NMR

The structure of traditional, linear phenol–resorcinol–formaldehyde (PRF) resins, urea‐branched PRF resins, and phenol–resorcinol–furfural (PRFuran) resins has been investigated in depth by both matrix‐assisted laser desorption/ionization time of flight (MALDI‐TOF) mass spectroscopy and ¹³C NMR. The structure of a variety of oligomers has been obtained, and the structures present in each of the three types of resins related to the very different percentages of resorcinol needed for their equal performance as adhesives. The oligomers type and species distribution appeared very different for each case. PRF resins performance is improved by maximizing either the proportion of resorcinol‐containing oligomers or methylol‐groups containing oligomers, even without any resorcinol, or both. It is equally obtained by the minimization of the relative proportion of the low reactivity Phenol (CH₂ Phenol) species in which resorcinol is not present, this being the most important parameter. This can be obtained by more effective use of the resorcinol by just modifying the resin manufacturing procedure. This parameter instead does not appear to be determinant in PRFuran resins. In these, it is the higher molecular weight of furfural in relation to formaldehyde that engenders for the same manufacturing procedure a correspondingly lower proportion of resorcinol in the resin. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2665–2674, 2004     

聚合转化率对硫调型氯丁胶结构与性能的影响

研究了硫调型氯丁橡胶乳液聚合中转化率对产晶结构与性能的影响.结果表明,随单体转化率的提高,聚合物的凝胶量及其交联密度增大,致使断链速度减慢,所得断链胶的门尼粘度上升,残存凝胶量增加,分子支化程度增大,分子量分布变宽,焦烧时间缩短。而相应硫化胶的拉伸强度、撕裂强度、冲击弹性和硬度等提高,扯断伸长率和永久变形下降。这些变化一般在转化率为80——85％时有明显转折.综合考虑产量与质量,聚合转化率控制在82±2％较为适宜。     

Pore structure of bulk tungsten carbide powder catalysts

Bulk tungsten carbide catalysts are prepared by direct carburization/reduction of tungsten trioxide in methane-hydrogen mixtures. The catalytic properties of such catalysts have been studied by several authors. The porous structure of these catalysts is studied by adsorption of N₂, Kr, CF₄ and neohexane. Adsorption isotherms and hysteresis loops for the catalysts suggest the presence of a microporous structure made of parallel plates distant approximately by 20 Å. These results are compared to those obtained using such catalysts for hydrogen oxidation and where condensation in the porous structure was observed.     

大型常压锥顶贮罐的设计

以工程实例为依据，论述国内以往较少采用的大型梁柱式支承锥顶贮罐的结构，介绍了国内外相关设计标准，给出了贮罐的典型结构－斜椽，横梁和立柱的计算公式，并用Excel电子表格编制了计算书。     

Ruthenium tetroxide catalysed oxidation of Illinois No. 6 coal: The formation of volatile monocarboxylic acids

Ruthenium tetroxide selectively oxidizes activated aromatic compounds under mild conditions and has been used for the catalytic oxidation of several different coals. The quantities of the volatile monocarboxylic acids with 2–6 carbon atoms have been determined by an isotope dilution technique. The amount of ethanoic acid ranges from 1 to 3mol/100C and the quantities of propanoic acid, and butanoic acid exceed 0.1 mol/100C. Methylpropanoic, pentanoic, 2-methylbutanoic, 3-methylbutanoicand hexanoic acid are formed in lesser amounts. The outcome of the experiment depends upon whether or not the coal has been extracted prior to oxidation. The results for Illinois No. 6 coal expressed in moles of ethanoic acid produced/l00C illustrate this feature: raw whole coal, 1.9; coal extracted by the method of Hayatsu and co-workers, 1.0. Dehydrogenation with benzoquinone prior to oxidation increases the yield of ethanoic acid to $\text{sol1.5mol}\text{100C.}$ The amounts of ethanoic acid obtained from the other extracted coals are 1.0 for Texas lignite, 1.2 for Rawhide subbituminous, 3.4 for Pittsburgh No. 8, 3.3 for a higher ranking bituminous coal (PSOC 726) and 0.7 for an anthracite (PSOC872). The results obtained in this study are compared with related information concerning the distribution of alkyl groups within coal by other methods.     

层次约束结构的虚拟装配建模技术

为了解决虚拟环境下装配建模在信息完备性和模型复杂性等方面的问题,提出了一种基于层次约束结构的虚拟装配模型.该模型分为产品层、部件层、零件层、特征层、几何面层和面片层来表达,不同层元素之间存在层次映射关系,同一层元素之间存在约束关系.通过CAD系统和虚拟装配系统之间的数据转换,实现了虚拟装配模型的生成算法,并给出了根据虚拟装配模型生成的虚拟装配场景图的结构.基于层次约束结构的虚拟装配模型具有信息表达完备,信息集成度高,满足实时性要求等优点,同时还能与CAD系统和虚拟装配场景图实现集成.实例验证了虚拟装配建模的有效性.     

基于形状记忆合金的TMD半主动控制

针对建筑结构在随机荷载或风荷载作用下可能发生的频率不确定问题,特别是结构自振频率会随振幅的大小而发生漂移的非线性振动问题,提出性能可靠、构造简单的形状记忆合金SMA-TMD自适应半主动控制系统.从理论上探讨形状记忆合金在变刚度TMD控制装置中的应用,并进行相应的参数设计.同时,在研究随机荷载作用下TMD系统动力特性的基础上,结合短时傅里叶变换(STFT)设计出该系统的自适应半主动控制算法.算例表明,SMA-TMD自适应控制系统能较好地识别结构系统的时频特性,并进行有效的控制,具有性能可靠和自适应能力强等特点.该自适应控制系统较传统的TMD被动控制减震效果更好,鲁棒性更强.     

等效剪切刚度的框架结构损伤识别方法

为研究有别于现有侧重于研究结构具体构件(梁、柱及支撑等)的建筑结构损伤识别方法,提出应直接从整体开展框架结构损伤识别方法.将框架结构转换成"等效剪切型"结构,数值分析表明,结构具体构件出现损伤(即刚度发生退化)时,会引起受影响层的等效剪切刚度发生变化,因此,可以采用层等效剪切刚度变化率与层抗侧刚度作为指标来进行结构损伤定位与损伤程度评定.通过大量的框架结构数值模拟计算,归纳出了一套能将损伤定位到结构层及从整体来评定结构损伤程度的方法.