Characterization of konjac glucomannan–quaternized poly(4‐vinyl‐N‐butyl) pyridine blend films and their preservation effect

Novel polymer blends were prepared from a mixture of 2 wt % konjac glucomannan and 4 wt % quaternized poly(4‐vinyl‐N‐butyl) pyridine (QPVP) in aqueous solution and dried at room temperature for 72 h. Their structure and properties were studied by infrared, wide‐angle X‐ray diffraction, scanning electron microscopy, thermogravimetric analysis, and differential scanning calorimetry. Thermal stability in the dry state was reduced with increasing content of QPVP. Compared with QPVP film, the tensile strength of the films was improved in the dry state. The maximum value of 12.74% tensile break elongation was reached when the content of QPVP was 30%. Structural analysis indicated that clear phase separation was observed when the content of QPVP was only 50%. Results from the filmcoating preservation experiments with lychee showed that this blend film had water‐holding ability. The fruit weight loss rate and rot rate both decreased in various degrees. The potential uses of these novel polymer films could be as preservative films. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1868–1875, 2004     

A study of structural determinants in the interleukin-1 fold

The structures of interleukin-1ß, basic fibroblastgrowth factor and Erythrina trypsin inhibitor have been analysedin order to determine whether the hydrophobic core remains conserved,even when the structures have extremely low sequence similarities.We find that there are significant differences in the way eachprotein achieves a satisfactory arrangement of core residuesand that positions which contribute to the core of one structureare not guaranteed to contribute to the integrity of another.Furthermore, the side-chain packing arrangements of these coreresidues vary significantly between the three structures. Duringthis analysis the side-chain rotamers for three independentlydetermined interleukin-1ß structures were also compared.It was found that although buried residues are generally inagreement the remaining residues frequently occupy differentrotamers in the three structures. This suggests that althoughmeaningful studies are possible for buried side-chains the resultsobtained from equivalent analyses of accessible residues shouldbe treated with caution. These results are discussed with specificreference to the optimization of side-chain packing in proteinsof known structure.     

XRQ-Ⅱ型开车燃烧控制系统的结构及应用

XRQ-Ⅱ型开车燃烧控制系统由泵组、阀组、燃烧器、快速关断阀门及控制柜等组成,燃料经油枪喷嘴雾化喷出在燃烧器中安全稳定地燃烧,控制柜保证供油及点火、火焰检测.在600 kt/a硫磺制酸系统焚硫炉烘炉及催化剂升温中的实际应用表明,XRQ-Ⅱ型开车燃烧控制系统具有便于自控操作、提高焚硫炉烘炉内衬质量、缩短催化剂升温时间等优点.     

A predicted three-dimensional structure of human cytochrome P450: implications for substrate specificity

A three-dimensional structure for human cytochrome P450IA1 waspredicted based on the crystal coordinates of cytochrome P450camfrom Pseudomonas putida. As there was only 15% residue identitybetween the two enzymes, additional information was used toestablish an accurate sequence alignment that is a prerequisitefor model building. Twelve representative eukaryotic sequenceswere aligned and a net prediction of secondary structure wasmatched against the known -helices and ß-sheets ofP450cam. The cam secondary structure provided a fixed main-chainframework onto which loops of appropriate length from the humanP450IA1 structure were added. The model-built structure of thehuman cytochrome conformed to the requirements for the segregationof polar and nonpolar residues between the core and the surface.The first 44 residues of human cytochrome P450 could not bebuilt into the model and sequence analysis suggested that residues1–26 formed a single membrane-spanning segment. Examinationof the sequences of cytochrome P450s from distinct gene familiessuggested specific residues that could account for the differencesin substrate specificity. A major substrate for P450IA1, 3-methyl-cholanthrene,was fitted into the proposed active site and this planar aromaticmolecule could be accommodated into the available cavity. Residuesthat are likely to interact with the haem were identified. Thesequence similarity between 59 eukaryotic enzymes was representedas a dendrogram that in general clustered according to genefamily. Until a crystallographic structure is available, thismodel-building study identifies potential residues in cytochromeP450s important in the function of these enzymes and these residuesare candidates for site-directed mutagenesis.     

纳米管合成研究进展

当今纳米科学技术飞速发展，其中纳米管已构成了纳米材料的一个非常重要的类别。本文介绍近几年来由化学键结合的纳米管以及由分子间力形成的一些纳米或具有中观尺度的管状结构材料的合成研究进展。     

水滴形歧管的结构分析

本文就衣架式模头水滴形歧管的结构设计，根据聚合物加工的流变理论，结合生产实际对水滴形截面的歧管流道分配系统进行分析，使得所设计的挤塑模在尽可能高的流速下，生产出符合尺寸及形状公差的均质片材。     

Structural characterization of 1,2-polybutadiene by 13C-n.m.r. spectroscopy: 2. Sequence distribution of 1,2-unit in hydrogenated polybutadienes

The configurational sequences of 1,2-unit in a series of hydrogenated syndiotactic 1,2-polybutadienes were determined in relation to the sequence distribution of 1,2- and 1,4-units on the basis of the ¹³C-n.m.r. signal assignment of the methyl carbons. The observed triad distributions of 1,2- and 1,4-units and configurational distributions of the 1,2-unit are in good agreement with the calculated distributions from transition probabilities. The number average sequence lengths of the 1,2-unit and the 1,2-unit in the racemic addition are 5.7 to 8.0 and 4.1 to 5.4, respectively. From the extrapolation of the plot of the number average sequence length against the crystallinity of the starting 1,2-polybutadienes, the minimum sequence length for crystallization is estimated to be 3.7 for the 1,2-unit in the racemic addition.     

Research on Variable Structure and Adaptive Control for Strap-on Rocket

固体捆绑运载火箭变结构自适应控制

陈曦,刘玉玺,汪轶俊

（上海宇航系统工程研究所）

创新点说明：

对于新型固体捆绑火箭而言,由于箭体安装固体助推器,存在推力偏差较大、推力同步性较大的问题,导致火箭的结构干扰增大。安装尾翼外干扰增大,如经过大风区时,风干扰对箭体产生较大的影响。同时考虑建立动力学模型的过程中存在的参数不确定性、参数摄动、三通道间耦合的问题,传统的控制方法难以满足新型固体捆绑火箭的要求,因此本文率先将基于模型参考的变结构自适应控制方法应用于固体捆绑运载火箭上。

研究目的：

本文针对固体捆绑运载火箭控制系统的特点,应用变结构自适应控制理论,设计适用于固体捆绑运载火箭的控制系统,保障固体捆绑运载火箭的正常飞行。

研究方法：

（1）建立固体捆绑运载火箭动力学模型,考虑模型中参数不确定性、未建模动态及通道间耦合;

（2）分析固体捆绑运载火箭存在的干扰,例如：四个固体助推带来的推力偏差、推力不同步性、推力线偏斜,质心横移、芯级、发动机及尾翼安装误差、芯级发动机液体燃料晃动、箭体弹性振动等各类结构误差及风干扰等外干扰;

（3）针对固体捆绑运载火箭设计变结构自适应控制律的设计并证明其稳定性;

（4）Simulink仿真分析验证。

结果：

本文使用变结构自适应控制理论设计的控制系统可全局渐进稳定,三通道姿态角跟踪误差较小,姿态角收敛速度较快,系统性能良好,可有效处理各类结构干扰、外干扰、气动参数不确定性及未建模动态等问题,该控制系统的动态特性及控制品质良好,具有工程应用的前景。

结论：

本文将基于模型参考的变结构自适应控制方法应用于新型固体捆绑运载火箭的控制系统的设计中。给出了仅有俯仰方向有大姿态变动的条件下的火箭动力学偏量模型,并在此基础上设计变结构自适应控制律,同时证明了该控制系统的稳定性。本文通过理论及仿真分析,证明了变结构自适应控制理论在新型固体捆绑运载火箭上的应用可行性,具有一定的工程应用前景。

关键词：运载火箭;模型参考;变结构控制;自适应控制

     

一种双U形缺陷地结构低通滤波器的设计

基于双U形缺陷地结构设计了一种低通滤波器。首先利用三维电磁场仿真软件分析了双U形DGS结构的S参数频响特性,然后利用该DGS结构加工制作了DGS结构低通滤波器,实验室测得该滤波器3 dB截止频率为3．26 GHz,通带范围内波纹最大是0．4 dB。插入损耗大于20 dB的阻带宽度为5．2 GHz。     

基于模型缩聚的θ指标损伤识别方法

为实现大型三维空间结构的损伤检测,提出了一种基于模型缩聚技术的检测方法。该方法利用有限数量的加速度传感器,得到大型三维桁架结构的自振频率和模态振型,以完成损伤的识别。数值仿真结果表明：该方法在损伤的定位识别和定量识别上能达到预期的适用性和可靠性。