Synthesis and characterization of poly(ethylene aspartate)-metal complexes

Poly(ethylene aspartate) [PEA] was synthesized by the melt condensation of D,L-aspartic acid and ethylene glycol. PEA containing pendent amino and carbonyl groups in its repeating chain was used as the polymeric ligand for complexation with transition metal ions, viz. Co(II), Ni(II), Cu(II), Mn(II), Zn(II), Cd(II), Ca(II), Mg(II), Pb(II) and Hg(II). Complexation was found to be most effective in DMSO. The resulting polyester-metal complexes were solid coloured materials which have been characterized by IR spectroscopy, elemental analysis and magnetic susceptibility measurements. The thermal stability of the polyester-metal complexes was investigated by thermogravimetric analysis (TGA). On the basis of the physico-chemical studies, an oxygen and nitrogen coordinated structure for the polyester-metal complexes is proposed.     

Selecting a waste management option using a life-cycle analysis approach

Solid-waste management, and in particular the disposal of used packaging, is currently the subject of much topical debate. This is driven by both consumer and legislative pressures. Consumers see used packaging as a highly visible element of municipal solid waste, complaining of excessive packaging and low levels of recycling. Legislators, perhaps in pandering to the views expressed by consumer bodies, have been active within the CEC and individual Member States by introducing (or proposing) legislation or similar regulatory tools and targets to facilitate a greater diversion of used packaging from disposal by landfill to alternative solid-waste management practices, in particular recycling, which are widely accepted to have a lower impact on the environment. In this paper the relative environmental profiles of pursuing alternative solid-waste management practices to disposal by landfill are explored, focusing not just on solid waste per se but also on associated considerations of energy consumption and emissions, which are invariably overlooked as factors contributing to the environmental impact of solid-waste management practices.     

Prediction of Final Product Properties After Cocurrent Spray Drying

The effect of drying and atomization conditions on the physical properties of powders for agglomerate-like materials and skin-forming material are studied in this article. A neural model is used for powder bulk and tapped density predictions.     

暖通空调工程设计常见问题

通过对施工图审查工作进行总结，指出了暖通空调和防火防排烟设计中存在的问题及防火规范本身的一些不足。     

A limit analysis of nonlinear elastic lateral displacements of thin-walled reinforced and prestressed beams

An incremental iterative process based on direct energy minimization is presented for a limit analysis of nonlinear elastic lateral displacements and twists of reinforced and prestressed beams. Problems encountered with the constitutive relations are discussed and two possible material models are presented.     

巯基棉预浓集—中子活化法测定水泥及其浸出水中的微量汞

在不同酸度下巯基棉可以从溶液中富集和分离Au、As、Ag、Br、Cu、Ca Co、InHg、Ni、Se、Sb、Sn、Pb、W、Fe和In等30多种元素。由于用巯基棉吸附待测元素后不必洗脱,因此大大提高了富集能力,可用于海水、地下水、地表水及工业废水中一些元素的测量。本文用巯基棉富集后进行中子活化分析测定水泥及其浸出水中的汞。     

静态电子轨道衡组成部分解析及其合理选择

阐述静态电子轨道衡诸多优点;工作原理、允许误差及误差分配;轨道衡的结构组成部分、解析各部分的工作特性及技术指标要求;合理选配及推荐实例.