Photodegradation mechanism and stabilization of polyphenylene oxide and rigid‐rod polymers

Poly(2,4‐dimethyl‐1,4‐phenylene oxide) (PPO), poly(benzo[1,2‐d:5,4‐d′]bisoxazole‐2,6‐diyl‐1,4‐phenylene) (PBO) and poly(benzo[1,2‐d:4,5‐d′]bisthiazole‐2,6‐diyl‐1,4‐phenylene) (PBZT), which are polymers with extended conjugated structures, undergo a self‐sensitized photo‐induced electron‐transfer reaction. A second component is not required. This article presents many similar observations on these polymers when they are exposed to light and evidence to support the proposed photo‐induced electron‐transfer mechanism. Methods to stabilize these polymers against photo‐oxidation are also described. Workers investigating other conjugated polymeric systems may find the experimental methods, observations and polymer stabilization approaches discussed in this review useful. Copyright © 2005 Society of Chemical Industry     

非金属夹杂物对硬线盘条拉拔性能的影响及其工艺控制

分析了非金属夹杂物对硬线盘条拉拔性能的影响及其来源 ,通过考察分析冶炼、浇注生产工艺针对非金属夹杂物含量的影响 ,提出了避免或减少非金属夹杂物含量的工艺控制方法。     

连续式棒线材轧机孔型系统的选择

论述了连续式棒线材轧机孔型系统的种类和特点，介绍了粗轧机组和中轧机组孔型系统的选择原则和方法。     

基于SolidWorks的螺杆压缩机机体三维建模设计

应用SolidWorks软件,建立了螺杆压缩机机体三维实体模型.对螺杆压缩机机体的内、外螺旋面的建模进行了分析和研究,提出了建立分段螺旋面模型的基本思路和方法.     

A Study of Surface Deformation during Wire‐Rod Rolling of High Speed Steels using Experimental and Computational Techniques

The evolution of surface defects during shape rolling of high‐speed steel billets is studied using longitudinal surface defects prepared by machining and welding. The reduction of the defects during rolling in a production mill is compared to the total area reduction of the billets. Samples are collected after pass 4, 6, 8, 14, 19 and the final pass, 28, representing the finished 5.5mm wire. By inspecting the cross sections, the rotation of the billets from pass to pass is evaluated. Results from FE simulations on solid billets are compared to the experimental results. Generally, simulations predict less reduction than observed experimentally. In most cases cracks reduce most effectively followed by carbon steel welds and stainless steel welds.     

卷取机前侧导板的设计结构分析

卷取机前侧导板的作用是把带钢对准轧制中心线送入夹送辊,并在进入夹送辊时导板夹持带钢以减少钢卷的塔形。     

内摩擦副式抽油杆扶正器的研制与应用

常规抽油杆扶正器随着抽油杆运动,造成扶正器与油管内壁摩擦,磨损速度快,搅拌井筒内原油加剧原油乳化,在高造斜、大斜度稠油井其问题更加突出.文章研究了内摩擦副式抽油杆扶正器,其特点是摩擦副摩擦阻力小、扶正套相对油管内壁运动少、磨损慢.在胜利桩139陆上丛式井组应用16口井,检泵周期可延长200 d.     

抽油杆尼龙扶正器的研制与应用

分析了油管和抽油杆产生偏磨的原因，指出防止油管和抽油杆偏磨的有效措施是采用抽油杆扶正器。针对现有扶正器存在的问题，研制了具有扶正和刮蜡功能的新型抽油杆尼龙扶正器。新型扶正器分活动式和热固式两种。前者是由形状相同、内壁带凸校的两部分扣在一起，靠锁齿锁紧固定在抽油杆杆体上，而后者是将扶正器注塑在抽油杆杯体上。介绍了两种新型扶正器的规格和主要技术指标。热固式尼龙扶正器的现场使用情况表明，抽油杆断脱率大大降低，油管断裂、穿孔事故减少，检泵周期延长。     

管杆漏磁探伤现场应用中的问题及对策

阐述了漏磁探伤漏磁场沿管、杆径向的分布特征 ,分析了影响探伤装置漏磁检测准确性的 4个因素 ,验证了信号提离距离的变化对传感器和探伤装置灵敏度的影响。针对在用的大多数浮动式传感器固定机构存在的两个严重缺点 ,提出采用自定位传感器固定机构 ,可消除机械装置对传感器灵敏度的影响。提出了一套标定和校验检测装置的方法 ,以保证探伤仪器的检测灵敏度始终恒定 ,提高检测结果的准确性和可靠性。