Disclosing the Role of Defect-Engineered Metal–Organic Frameworks in Mixed Matrix Membranes for Efficient CO2 Separation: A Joint Experimental-Computational Exploration

Incorporation of defects in metal–organic frameworks (MOFs) offers new opportunities for manipulating their microporosity and functionalities. The so-called “defect engineering” has great potential to tailor the mass transport properties in MOF/polymer mixed matrix membranes (MMMs) for challenging separation applications, for example, CO₂ capture. This study first investigates the impact of MOF defects on the membrane properties of the resultant MOF/polymer MMMs for CO₂ separation. Highly porous defect-engineered UiO-66 nanoparticles are successfully synthesized and incorporated into a CO₂-philic crosslinked poly(ethylene glycol) diacrylate (PEGDA) matrix. A thorough joint experimental/simulation characterization reveals that defect-engineered UiO-66/PEGDA MMMs exhibit nearly identical filler–matrix interfacial properties regardless of the defect concentrations of their parental UiO-66 filler. In addition, non-equilibrium molecular dynamics simulations in tandem with gas transport studies disclose that the defects in MOFs provide the MMMs with ultrafast transport pathways mainly governed by diffusivity selectivity. Ultimately, MMMs containing the most defective UiO-66 show the most enhanced CO₂/N₂ separation performance—CO₂ permeability = 470 Barrer (four times higher than pure PEGDA) and maintains CO₂/N₂ selectivity = 41—which overcomes the trade-off limitation in pure polymers. The results emphasize that defect engineering in MOFs would mark a new milestone for the future development of optimized MMMs.     

电话机来电显示电路CSC9270DGP的测试软件开发

本文介绍了电话机来电显示电路CSC9270DGP的测试原理和方法,CSC9270DGP是一个完整的双音多频接收电路,具有频带分离滤波器和数字解码功能。重点介绍了该电路在ETS－570大规模测试系统上的测试软件开发。CSC9270DGP是一个数模混和电路,有3／4是模拟部分,本文介绍了如何在数字系统上测试模拟电路的方法。     

一种基于音质评估的语音伪装通信新方法

研究一种语音伪装新方法,将保密语音替换成另外一种语音以便于在公网上安全传输。保密语音经2.4kb/低速率压缩编码后,依据设计的客观音质评估模型,将参数隐蔽地嵌入普通语音;检测时利用逆过程恢复保密语音。实验表明算法的信噪比较传统算法提高约3.5dB,并在受到压缩、滤波等攻击时具有较高的鲁棒性。     

Deep blue/ultraviolet microcavity OLEDs based on solution-processed PVK:CBP blends

There is an increasing need to develop stable, high-intensity, efficient OLEDs in the deep blue and UV. Applications include blue pixels for displays and tunable narrow solid-state UV sources for sensing, diagnostics, and development of a wide band spectrometer-on-a-chip. With the aim of developing such OLEDs we demonstrate an array of deep blue to near UV tunable microcavity (μc) OLEDs (λ ∼373–469 nm) using, in a unique approach, a mixed emitting layer (EML) of poly(N-vinyl carbazole) (PVK) and 4,4′-bis(9-carbazolyl)-biphenyl (CBP), whose ITO-based devices show a broad electroluminescence (EL) in the wavelength range of interest. This 373–469 nm band expands the 493–640 nm range previously attained with μcOLEDs into the desired deep blue-to-near UV range. Moreover, the current work highlights interesting characteristics of the complexity of mixed EML emission in combinatorial 2-d μcOLED arrays of the structure 40 nm Ag/x  nm MoO_x/∼30 nm PVK:CBP (3:1 weight ratio)/y  nm 4,7-diphenyl-1,10-phenanthroline (BPhen)/1 nm LiF/100 nm Al, where x = 5, 10, 15, and 20 nm and y = 10, 15, 20, and 30 nm. In the short wavelength μc devices, only CBP emission was observed, while in the long wavelength μc devices the emission from both PVK and CBP was evident. To understand this behavior simulations based on the scattering matrix method, were performed. The source profile of the EML was extracted from the measured EL of ITO-based devices. The calculated μc spectra indeed indicated that in the thinner, short wavelength devices the emission is primarily from CBP; in the thicker devices both CBP and PVK contribute to the EL. This situation is due to the effect of the optical cavity length on the relative contributions of PVK and CBP EL through a change in the wavelength-dependent emission rate, which was not suggested previously. Structural analysis of the EML and the preceding MoO_x layer complemented the data analysis.     

火炮身管大缠角混合膛线计算机数字控制电解加工技术研究

分析了火炮身管大缠角混合膛线的成型过程,提出圆锥体单边切进楔形工作齿的阴极结构,经试验确定了阴极体锥度、长度与楔形工作齿角度的匹配关系。编制了电解加工专家系统,对阳线进出口和中间段分别采用电压控制和电流控制,实现了在控制阴极进给和旋转的同时在线检测并控制加工参数。生产证明该阴极结构合理,控制系统精确。     

星载AIS混合信号的混叠位置估计

针对AIS混合信号的混合位置估计问题,改进了 传统双窗检测法。混合 信号混合部位和未混合部位在幅度和频率上存在明显差异,通过混合部分与未混 合部分到达窗内的能量比值来估计重叠段与未重叠段的始末位置,对传统估计信 号起始位置的判决函数进行了改进,估计精度更高。仿真表明,相较于传统双窗 检测法,本文能够准确估计出混合信号的重叠始末位置。     

《移动商务》课程信息化教学设计

伴随着教育信息化和混合式教学的浪潮,许多课程都开始了信息化的教学改革。本文以《移动商务》课程为例,从课程定位、课程目标、课程设计、课程实施、课程评价五个方面对该课程的信息化教学予以总结,希望进一步提高《移动商务》课程的教学效果。     

基于MATCOM的MATLAB与VC＋＋之间的混合编程

利用MATCOM与VC进行接口通信的优点,介绍了一种基于MATCOM的MATLAB与VC＋＋之间混合编程的方法、步骤及实例,文中以卡尔曼滤波器为实例来进行详细的说明。此方法以MATCOM为转换工具,将.m文件转化为C＋＋代码,而且还将MATCOM与VC＋＋相结合进行了图形绘制,以及利用VC＋＋中MFC可以生成良好界面的功能,通过对控件编程,利用按钮来显示出图形。这种串口通信的混合编程方法,不仅能充分发挥两种语言各自的优势,并且可以脱离MATLAB来独立运行,此方法既简便、方便又有很强的可操作性。     

基于CORDIC算法的Hough变换及其FPGA实现

为了既能提高Hough变换的计算速度,同时能保持精度以及不大的存储量,讨论了Hough变换和CORDIC算法各自的特点,论证了用CORDIC算法实现Hough变换的可行性。研究了采用流水线构架的CORDIC算法,提出了一种基于CORDIC混合基算法的特殊处理器来计算Hough变换,使迭代次数减少1/4,并可显著改善迭代的速度。这种方法占用资源面积比较小,并且结构规则简单,适合于FPGA设计实现,具有较高应用价值。