Application of K2CO3 catalysts in the coal gasification process using nuclear heat

Conventional gasification processes use coal not only as feedstock to be gasified but also for supply of energy for reaction heat, steam production, and other purposes. With a nuclear high temperature reactor (HTR) as a source for process heat, it is possible to transform the whole of the coal feed into gas. This concept offers advantages over existing gasification processes: saving of coal, as more gas can be produced from coal; less emission of pollutants, as the HTR is used for the production of steam and electricity instead of a coal-fired boiler; and a lower production cost for the gas. However, the process has the disadvantage that the temperature is limited to the outlet temperature (950 °C max) of the helium cooling gas of the HTR. Therefore the possibility of catalytic steam gasification was examined. Model calculations based on experimental results show that use of 3–4 wt% relative to coal of K²CO³ catalyst increases the throughput of a large scale nuclear gasification plant by ≈65%, while gas production costs decrease by ≈15%. Corrosion by catalysts is not significant at low concentration (< 5 wt%) and low temperature (< 900 °C).     

Transient Hot-Strip Method for Simultaneous Determination of Thermal Conductivity and Thermal Diffusivity of Refractory Materials

The transient hot-strip method has been used for determining thermal conductivity and thermal diffusivity of a refractory brick. The technique is based on recording the transient temperature increase of a 25-μm-thick, 8-mm-wide, and 70-mm-long iron strip clamped between two sample halves and heated with a constant direct current. The method is accurate to within 5% in the thermal conductivity and to within 10% in the thermal diffusivity in the temperature range 20° to 700°C.     

纳米稀土复合固体超强酸催化合成乙酸苄酯

采用共沉淀法制备了纳米稀土复合固体超强酸SO4^2-／ZrO2-2％Nd2O3催化剂，电镜分析表明，催化剂颗粒直径在25nm左右，比表面积测定：71．03m^2／g。酸强度-12．70〈Ho〈-11．99。并对合成乙酸苄酯的最佳反应条件进行了研究。研究表明：当苯甲醇与乙酸的物质的量比为1：2，反应时间为5h，反应温度为120℃，催化剂用量为6％苯甲醇的质量时，酯化率可达92．04％。研究发现，该催化剂可重复使用并可活化再生。     

Air-source heat pump coupled with economized vapor injection scroll compressor and ejector:Design and experimental research

Ejector can utilize high pressure energy from liquid mechanism,it can be used in heat pump system coupled with economized vapor injection(EVI)scroll compressor.When running under low temperature conditions,the performance of the EVI system with ejector can be improved further.In this paper,the design method of the heat pump system with ejector is presented,and the process for designing the heat pump with ejector(EVIe)was summarized.One prototype heat pump was designed under the condition of the evaporation ...     

有限体积法求解立体角离散误差

为解决采用有限体积法求解辐射传输方程时引起离散误差的问题,从有限体积法立体角内热流密度的求解过程出发,运用泰勒级数推导了近似误差的表达式,并分析影响离散误差的各种因素,包括离散射线数,辐射强度分布,假散射及网格比.根据分析结果,采用辐射强度的连续分布模型,模拟了各种因素对误差的影响.结果表明,辐射强度的分布函数对于有限体积法的离散误差有一定程度影响.当增加网格数及减小网格尺寸比时,可以有效地减小离散误差.假散射与离散误差间呈较强的非线性耦合关系.     

盈余质量与公司治理关系的实证研究

对公司治理系统中的主要特征变量与盈余质量关系的统计分析结果表明:独立董事的比例和盈余质量之间存在倒U型曲线关系;董事会会议次数和盈余质量正相关;而董事会规模和盈余质量的关系不显著;债务约束不构成中国上市公司盈余管理的动机;而提高净资产收益率的动机非常明显.政策结论在于:单纯的独立董事制度改革对提高盈余质量的作用有限,公司治理改革必须配合市场改革措施才能更有效地发挥提高盈余质量的作用.     

有侧移半刚性连接组合框架柱的稳定分析

为了研究有侧移半刚性连接组合框架的稳定性能,利用三柱子框架模型,考虑了梁端和柱远端不同约束情况对柱有效长度系数的影响,提出柱有效长度系数的简化方法.通过算例研究了节点的非线性弯矩-转角关系和荷载水平大小对柱有效长度系数的影响,比较了简化方法、Barakat-Chen方法与精确方法的计算结果.研究表明:简化方法比Barakat-Chen方法有更好的精确度,与精确方法计算结果接近.     

大口径光学透镜瞬态温度场模拟

为考察热辐射效应对光学元件稳、瞬态温度场的影响,给出了考虑辐射和导热耦合换热情况下复杂几何结构光学透镜稳、瞬态热特性的适体坐标下离散坐标法.对喷管形和圆柱形介质进行计算并与其他方法比较表明,建立的适体坐标系下辐射与导热耦合换热计算方法精度较好.对两端为球缺中间为圆柱的大口径透镜内的辐射与导热耦合换热过程进行了数值模拟.计算结果表明,为了精确地预测半透明介质如透镜内的温度分布,应该考虑辐射与导热耦合作用,且应当考虑介质的光谱特性.     

城市污水的层流换热特性理论

为有效利用城市污水热能,以污水源热泵系统中的流动工质——城市污水为研究对象,通过理论分析的方法,对其层流状态下的换热特性进行理论推导和实验验证.结果表明:污水作为热泵的冷热源,有良好的换热特性,推导得出的换热准则关联式h=4.53λ/D,为污水源热泵系统设计提供依据,同时为应用污水余热技术提供理论基础.     

Simulation and optimization of SOFC-BCHP system

As the prime motor of dispersed energy system, the high-temperature solid oxide fuel cells (SOFC) are high efficient with large heat recovery. This study presents a simulation of SOFC building-based cooling, heat and power (BCHP) system, which can meet basic requirements in power and heating (cooling) of the designated customers. The peak power load can be met by power grid, while the peak heating (cooling) load requirement can be met by backup equipments. In order to solve the economic dispatch problem of the energy system, a restricted nonlinear optimization model has been developed. The production costs can be minimized via both the equality constraints of customer’s heat and power demands, and other inequality constrains of equipments’ capacities. The sequential quadratic programming method has been used to search the solution. The study indicates that the model can be used to optimize the system’s capacities and run strategy. An office building case has been computed, and it is indicated that the model can be served in design and optimization of SOFC-BCHP system.