高流态大掺量粉煤灰混凝土的研制及应用

通过混凝土配合比的正交试验及有关因素影响效果的分析,确定了高流态大掺量粉煤灰混凝土配合比的最优方案,进而成功用于最深的混凝土防渗墙工程中,为高流态大掺量粉煤灰混凝土的广泛应用提供了参考。     

Effect of Vortex Restructuring on Heat Transfer in an “Inverted” Flame

The papers deals with formation of vortex structures during combustion of a fuel gas–air mixture injected vertically down through a hole in a flat plate. It has been established that the shape, position, and number of vortex cells are determined by the flow rate and composition of the fuel mixture. It is shown that as the flow rate increases from the minimum critical value for which a vortex structure arises, the number of vortex cells decreases from five or six to one. A further increase in the gas flow rate leads to transition to turbulence of the combustion product flow. The presence of a vortex structure increases the critical Reynolds number at which the flow becomes turbulent. Reverse transition to the structure with an increased number of vortex cells occurs with a delay in the gas flow rate (gas discharge hysteresis). Variation in flow rate is accompanied by bifurcation of the number of vortex cells.     

BaFe12O19/聚氨酯磁性复合微球的制备和表征

通过BaFe12O19硅烷偶联剂改性,聚乙二醇1000、甲苯二异氰酸酯在二甲苯溶液中预聚合,预聚物溶液在分散剂聚乙烯吡咯烷酮K30的水溶液中悬浮聚合,三步合成了BaFe12O19/聚氨酯复合微球.用扫描电镜、红外光谱仪、热重-差示扫描同步热分析仪和振动样品磁强计对微球的形貌、结构、玻璃化温度(Tg)和磁性能进行了表征.结果表明:合成的微球以BaFe12O19颗粒为核聚氨酯为壳.表面分布有微孔,微球粒径在400μm左右,粒径大小可通过控制反应条件调节.微球中磁性物质BaFe12O19的含量为11.11%(质量分数),Tg在290 ℃左右,耐热性能好,微球的饱和磁化强度为3.36×103 A/m,矫顽力为3.06×104 A/m.该复合微球是一种有潜在应用价值的新型血管内栓塞材料.     

木塑复合材料制品一步法挤出成型技术的研究

介绍了木塑复合材料制品一步法挤出成型中常见的5种挤出设备,提出了选择这些设备时需要考虑的一些因素,分析了木塑复合制品挤出成型技术中温度、压力、喂料和排气等问题产生的原因。并结合实验和理论,从螺杆、机筒、机头设计和加料器选择等方面提出了解决这些问题的措施。     

化学镀法制备SiC/Cu金属陶瓷复合粉体工艺的研究

为改善SiC与其他金属的结合性能，采用化学镀法在SiC粉体上镀Cu，制备包覆型陶瓷颗粒。通过精选、粗化、敏化、活化表面镀前处理，用硫酸铜镀液成功地得到在SiC上均匀镀Cu的包覆粉体，利用Olympus显微镜观察到包覆程度可达95％，通过详细讨论镀液的配方、pH值、镀液与SiC粉体的配比与对包覆效果的影响，最终得到硫酸铜用量控制在10—15g／l能得到我们所控制的沉积反应速度；包覆反应过程中pH值控制在11—13之间较为合适。     

12 MW热电联产装置运行总结

总结了12MW热电联产装置的特点及运行情况。实际运行情况证明,建设热电联产装置是以煤为原料的中、小氮肥企业彻底解决造气炉渣及细灰综合利用,使其变废为宝的一条重要途径,也是氮肥企业降低生产成本、增加效益、提高企业市场竞争力的必然选择。     

Thermooxidative degradation of natural rubber/clay composite

The clay is treated with a reducing agent and an acid so as to obtain a clay containing various metal components with a variable‐valence state. Then, the clay is coprecipitated with natural rubber (NR) latex to prepare a vulcanized NR/clay composite. The degradation process of the NR/clay composite under hot air condition was studied dynamically by using a Fourier transform infrared spectrometer attaching an in situ sample cell and was also investigated using the TGA method. The test result obtained from the infrared spectrometry indicated that under low decomposition temperature, the decomposition products of the test samples mainly are ethylene, low molecular olefinic hydrocarbon, and carbonyl compounds. As the decomposition temperature rises, the low molecular olefinic hydrocarbon content decreases, the olefine with longer chain is formed, and a lot of alkane decomposition products are formed at the same time. When the content of the metal components with a variable‐valence state in clay such as Cu, Mn, Co, and Fe increases, the oxidation products containing the carbonyl group, the olefinic hydrocarbon, and CO₂ in the decomposition product of the test sample also increase. The TGA result clearly shows a shoulder peak that appears by the side of the main peak on the DTG curve of NR/clay composite. With the increase in the content of metal components with variable‐valence state in clay, the initial degradation temperature of the test sample (T₀), the degradation peak temperature (T_p1), and the final degradation temperature (T_f1) in first‐stage reaction, as well as the degradation peak temperature (T_p2) and the last final degradation temperature (T_f) in second‐stage reaction of all the test samples more or less shift to the direction of low temperature; besides, the activation energy (E) of the reaction of the test samples more or less decreases. This means that the metal components with variable‐valence state promote the oxidative degradation of the clay–rubber masterbatch. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3809–3815, 2006     

论大钢模体系在剪力墙结构施工中的应用

简要叙述了大钢模施工的应用前景,着重分析了大钢模施工的优、缺点,大力推广大钢模施工技术的应用。     

硼酸镁晶须的合成研究

报道了硼酸镁晶须的合成研究结果。硼酸镁晶须是一种性能价格比高的晶须产品，利用熔盐法合成出长10—50μm、直径0．5—2μm的硼酸镁晶须。还就硼酸镁晶须增强复合材料的研究和硼酸镁晶须工业化的前景作了展望。     

腈纶高缩毛条生产工艺探讨

分析了腈纶高缩纤维的特点，通过与常规纤维制条工艺比较，对高缩毛条生产工艺进行了探讨。实验结果表明：多区拉断机工艺条件是保证成品毛条缩率的重要因素，拉断机车速和热板间隙对成品毛条缩率有重要影响。