电子陶瓷和器件的低温共烧技术

较系统地介绍了电子器件用低温共烧陶瓷(low temperature cofired ceramics,LTCCs)材料,探讨了其工艺中的若干问题。电子器件用低温共烧陶瓷材料包括:玻璃/陶瓷复合材料、结晶化玻璃、晶化玻璃/陶瓷复合材料以及液相烧结陶瓷,其中典型的和最为常用的LTCCs为玻璃/陶瓷(特别是氧化铝)复合材料。正在研究的一些陶瓷介质材料中,Bi基介质材料引起了人们的关注。玻璃/陶瓷复合材料的制备工艺中,应当着重关注和加深了解玻璃的流动性和结晶性、玻璃的起泡、玻璃和陶瓷颗粒间的反应、共烧材料的匹配等问题,从优选材料配方和优化工艺着手,从而获得优质可靠的材质和器件。     

CGA560增强助磨剂在水泥粉磨中的应用研究

研究了CGA560增强助磨剂在水泥粉磨中对台时产量和水泥质量的影响。试验结果表明:在磨机状况不改变的条件下,CGA560增强助磨剂的加入可提高磨机产量10%-30%;同时可有效减少过粉磨现象,优化水泥颗粒级配,提高了水泥粉磨细度及比表面积;因而使水泥强度等性能得到了明显改善和提高。     

胶层厚度对拉伸试样应力分布影响的数值分析

运用弹塑性有限元法研究了胶层厚度对承受拉伸载荷的对接接头胶层内应力分布的影响．三维有限元法数值分析的结果表明，随胶层厚度减小，胶层中正应力SZ与剪应力SYZ的分布趋于均匀；而对正应力SY而言，胶层厚度为0．15mm时，其边缘峰值应力最低。     

Effects of apitong (Dipterocarpus spp.) extractives on bond strength development and curing rate of adhesives

Emulsion polymer isocyanate ( ), polyvinyl acetate ( ) and resorcinol-formaldehyde ( ) adhesives were used to produce single lap shear specimens using resinous and non-resinous apitong (Dipterocarpus spp.) timbers. Tests showed that joints made with highly resinous apitong were about 40% weaker than similar joints made with non-resinous apitong. The resinous apitong was treated with different solvents to yield five different extractives which were characterized by infra-red analysis. Apitong extractives were then added to and adhesives and joints made with buna (Fagus crenata), a timber known to be low in extractives and easy to bond. Joints prepared using extractive-containing adhesives were generally weaker than those made with the unmodified adhesives. RF adhesives containing extractives cured more slowly than unmodified . It is thought that the acidic nature of the extractives changes the pH of the system sufficiently to affect the curing mechanism     

纳米稀土复合固体超强酸催化合成乙酸苄酯

采用共沉淀法制备了纳米稀土复合固体超强酸SO4^2-／ZrO2-2％Nd2O3催化剂，电镜分析表明，催化剂颗粒直径在25nm左右，比表面积测定：71．03m^2／g。酸强度-12．70〈Ho〈-11．99。并对合成乙酸苄酯的最佳反应条件进行了研究。研究表明：当苯甲醇与乙酸的物质的量比为1：2，反应时间为5h，反应温度为120℃，催化剂用量为6％苯甲醇的质量时，酯化率可达92．04％。研究发现，该催化剂可重复使用并可活化再生。     

Rheology of cementitious paste with silica fume or limestone

The rheological behaviour of cementitious pastes where cement has increasingly been replaced by densified silica fume (SF), untreated SF or limestone has been studied. The effect of SF on the flow resistance, taken as the area under the flow curve, was found to depend on the dispersing ability of the plasticizer as illustrated by pastes with naphtalene sulphonate-formaldehyde condensate (SNF) and polyether grafted polyacrylate (PA).The gel strengths increased with increasing SF replacement of cement independently of plasticizer type. The cementitious gel strength was, however, depending on the type of SF since pastes with densified SF developed lower gel strengths than pastes with untreated SF. This phenomenon was attributed to agglomerates in the densified SF which remained unbroken by the mixing and measurement sequence.Both flow resistance and gel strength decreased with increasing limestone replacement. Thus, silica fume may have an advantage over limestone filler as stabilizing agent for self-compacting concrete preventing segregation upon standing and reduced form pressure due to a more rapid gel formation.     

有侧移半刚性连接组合框架柱的稳定分析

为了研究有侧移半刚性连接组合框架的稳定性能,利用三柱子框架模型,考虑了梁端和柱远端不同约束情况对柱有效长度系数的影响,提出柱有效长度系数的简化方法.通过算例研究了节点的非线性弯矩-转角关系和荷载水平大小对柱有效长度系数的影响,比较了简化方法、Barakat-Chen方法与精确方法的计算结果.研究表明:简化方法比Barakat-Chen方法有更好的精确度,与精确方法计算结果接近.     

树脂增强选择性激光烧结多孔金属件的研究

针对选择性激光烧结(SLS)间接方法成型的金属零件形坯,经脱脂和高温烧结后形成的零件存在大量孔隙和空洞,其致密度和强度都较低,不能满足实际应用要求的问题,采用改性耐高温环氧树脂浸渗零件烧结坯的方法,使多孔金属件致密化,并粘结内部金属网架,提高零件的机械性能.对浸渗烧结坯的拉伸强度的测试和扫描电镜(SEM)以及热失重(TGA)的分析结果表明,浸渗树脂后的烧结坯拉伸强度提高了约4倍;改性环氧树脂和金属网架粘结在一起,形成一个密实的网络结构,致密度大幅提高;零件可在200℃的温度下使用.该方法可以制造注塑模具和功能零件.     

Zonal disintegration phenomenon in enclosing rock mass surrounding deep tunnels -- Elasto-plastic analysis of stress field of enclosing rock mass

The zonal disintegration phenomenon (ZDP) is a typical phenomenon in deep block rock masses. In order to investigate the mechanism of ZDP, an improved non-linear Hock-Brown strength criterion and a bi-linear constitutive model of rock mass were used to analyze the elasto-plastic stress field of the enclosing rock mass around a deep round tunnel. The radius of the plastic region and stress of the enclosing rock mass were obtained by introducing dimensionless parameters of radial distance. The results show that tunneling in deep rock mass causes a maximum stress zone to appear in the vicinity of the boundary of the elastic and the plas-tic zone in the surrounding rock mass. Under the compression of a large tangential force and a small radial force, the rock mass in the maximum stress zone was in an approximate uniaxial loading state, which could lead to a split failure in the rock mass.     

大体积混凝土温升与强度增长的试验研究

针对大体积混凝土结构构件实体强度与普通标准养护试块强度发展规律间的差别等问题,通过研究实际工程尺寸试件温度场的分布和实验室混凝土变温养护试验,以不同养护制度下的试块强度得出了大体积混凝土结构实体强度的发展规律,为工程施工提供了依据,成功地解决了工期与质量的矛盾,取得了较好的技术经济效果.