氯盐在水泥海排灰结合料中的固化机理

目的 通过内掺氯盐对水泥海排灰结合料微观结构的分析,揭示内掺氯盐的水泥海排灰结合料的固化机理.方法 采用SEM、XRD和理论分析的方法 对水泥海排灰结合料的性能和微观结构进行研究,并且分析含氯盐的水泥海排灰的固化机理.结果 当海排灰中含有氯盐时,水泥海排灰结合料7 d、28 d龄期均能生成一种新的晶体-Friedel盐;海排灰中掺加质量分数为0.5%氯盐的结合料试件经过无侧限强度试验7 d龄期强度较高,28 d龄期强度最高.结论 海排灰中的氯盐可以在水泥海排灰结合料中得到固化,从而提高结合料的强度.     

高硫煤还原磷石膏反应中SO_2浓度影响因素

为了探讨高硫煤还原磷石膏生成SO2的反应机理,通过热重分析等手段,对连续升温条件下不同C/SO3比和不同高硫煤粒径对SO2浓度的影响进行了研究。实验结果表明:用高硫煤还原磷石膏可以大大提高SO2浓度,在700~800℃和1 000~1 100℃时SO2浓度出现了2个峰值,与磷石膏煅烧产生的SO2浓度比较,最大分别提高了25.55%和42%;<800℃时较强的还原气氛有利于SO2的生成,反之;在700~800℃时高硫煤粒径对SO2浓度的影响最显著,SO2浓度最大相差约15%;SO2浓度随着粒径的减小呈先减小后增大的趋势。     

盐渍化软弱土地基处治措施对比分析

为了综合提高西北地区盐渍化软弱土地段公路地基处理的工程质量,以嘉—安一级公路盐渍化软弱土地段的地基处治项目为工程依托,通过MARC有限元数值计算分析、现场实际监测数据结果以及地基处治措施的社会经济效果评价,研究了适用于西北盐渍化软弱土地基处治的合理措施.结果表明,在处理该特殊土地基时,水泥粉喷桩、强夯置换、振动沉管挤密砂石桩都符合规范要求;从处治效果上来看,后两者的效果要优于水泥粉喷桩,振动沉管挤密砂石桩的效果最好;从社会经济效益评价结果来看,强夯置换在处理盐渍化软弱土地基时的费用最低,最省时,经济效果明显.     

水泥工业结构调整的特点及对人才的需求

我国是世界上最大的水泥生产国和消费国.目前水泥工业进入了结构调整阶段.随着我国经济和社会发展水平的提高,人们对资源和环境问题的重视,水泥工业的结构调整出现了新的特点,对人才的需求也出现了新的变化.     

镁渣硅酸盐水泥的性能

用2种不同来源的镁渣作为水泥混合材配制镁渣硅酸盐水泥。研究了其标准稠度用水量、凝结时间、强度等基本性能,考察了镁渣对水泥干燥收缩的影响,并通过XRD、DSC/TG、SEM等微观手段研究了镁渣在水泥中的作用效应。结果表明：镁渣作为水泥的混合材具有一定的减水缓凝效果;镁渣掺量在10%～30%范围内时,水泥样品符合通用硅酸盐水泥42.5R级的标准,掺量为35%～40%符合32.5R型复合硅酸盐水泥的要求;镁渣掺量为30%～40%时对水泥砂浆的干燥收缩有抑制作用;镁渣与水泥熟料水化产物发生反应,使水泥浆体结构更加致密。     

我国基坑工程发展现状综述

分析了国内外基坑工程的发展和研究现状;详细介绍了我国基坑工程的主要支护类型,包括水泥土墙、土钉墙、锚杆、排桩与地下连续墙等;最后分析了我国基坑工程存在的主要问题,并展望了今后的发展趋势。     

快硬硫铝酸盐水泥浆体-矾土集料界面的微结构

用XRD层析技术、SEM/EDAX和DTA等手段测定了矾土集料-硬化硫铝酸盐水泥浆体界面区的组成、微结构及形貌,同时用XRD线宽法测定了界面区中AFt晶体尺寸及其分布。研究发现,在矾土界面区中,AFt主要以胶体形态富集,C(?)H_2以晶体形态富集,界面区的厚度为70μm左右。为此,提出了矾土集料界面区微结构的形成机理。     

Compressive strength and hydration of wastepaper sludge ash-ground granulated blastfurnace slag blended pastes

Compressive strength and hydration characteristics of wastepaper sludge ash-ground granulated blastfurnace slag (WSA-GGBS) blended pastes were investigated at a water to binder (w/b) ratio of 0.5. The strength results are compared to those of normal Portland cement (PC) paste and relative strengths are reported. Early relative strengths (1 day) of WSA-GGBS pastes were very low but a marked gain in relative strength occurred between 1 and 7 days and this increased further after 28 and 90 days. For the 50% WSA-50% GGBS blended paste, the strength achieved at 90 days was nearly 50% of that of the PC control paste. Transmission electron microscopy (TEM), X-ray diffraction (XRD) and thermogravimetric (TG) analysis were carried out to identify the mineral components in the WSA and the hydration products of WSA and WSA-GGBS pastes. The principal crystalline components in the WSA are gehlenite, calcium oxide, bredigite and α′-C₂S (stabilised with Al and Mg) together with small amounts of anorthite and calcium carbonate and traces of calcium hydroxide and quartz. The α′-C₂S and bredigite, which phase separate from liquid phase that forms a glass on cooling, are difficult to distinguish by XRD. The hydration products identified in WSA paste are CH, C₄AH₁₃, C₃A.0.5CC?.0.5CH.H_11.5 and C-S-H gel plus possible evidence of small amounts of C₂ASH₈ and C₃A.3CS?.H₃₂. Based upon the findings, a hydration mechanism is presented, and a model is proposed to explain the observed strength development.     

Effect of silica fume and fly ash on heat of hydration of Portland cement

Results of calorimeter tests on Portland cement-silica fume-fly ash mixtures are presented. Data indicate that silica fume accelerates cement hydration at high water/cementitious ratios and retards hydration at low water/cementitious ratios. On the other hand, fly ash retards cement hydration more significantly at high water/cementitious ratios. When silica fume and fly ash are added together with cement, the reactivity of the silica fume is hampered and the hydration of the cementitious system is significantly retarded.     

水泥工业DCS控制系统的抗干扰措施

介绍水泥工业DCS控制系统干扰的来源,并提出抗干扰措施.