熔融石英陶瓷的性能及其应用

介绍了石英陶瓷的性能特点、制备过程及应用领域     

Assessing the predictive capability of two‐phase models for the mechanical behavior of alumina/epoxy nanocomposites

A review of analytical modeling of particulate reinforcement is made as a prelude to the problem of microstructural inhomogeneity in nanocomposite materials. Noting the inevitability of dispersion nonuniformity, and variations in agglomerate morphology and filler‐matrix interaction, the need to question the application of such models to novel materials arises. Employing the mechanical properties of alumina/epoxy nanocomposites, with known dispersion characteristics, an evaluation of the predictive capability of various models for Young's modulus, strength, and failure strain is made. Comparison between models is accompanied by a discussion of the parameters used in the fitting of macroscopic behavior to microstructural features. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 869–879, 2005     

大冶硫酸四系列干吸塔结构特点

以干燥塔为例，介绍大冶公司硫酸四系列干吸塔的结构特点。除捕沫层简体及出气管为316L不锈钢外，其余塔体均为碳钢内衬瓷砖结构。塔底为球形底，中心排酸。采用槽管式分酸器，分酸点密度为43个/m^2，设可调闸板以保证各槽酸量均匀；闸板外设置带孔板的分布板，以消除进口酸的冲击，保证槽内酸液面平稳。比较了该塔与常规塔的不同之处，强调了设备节点的优化设计。     

Composites based on eucalyptus tar pitch/castor oil polyurethane and short sisal fibers

Polymeric materials are being developed with renewable resources to promote industrial progress with environmentally friendly technologies. For this reason, polyurethane samples were prepared with 4,4′‐diphenylmethane diisocyanate (NCO/OH = 1), eucalyptus tar pitch (biopitch), castor oil as a polyol, and dibutyltin dilaurate as a catalyst. These materials were reinforced with different contents of short sisal fibers (0, 2.5, 5.0, 7.5, and 10.0%) and were prepared by resin‐transfer molding. The composites were characterized by IR absorption spectroscopy, thermal analysis (thermogravimetry and differential scanning calorimetry), impact resistance, scanning electron microscopy, and water absorption resistance. These materials showed hydrophobic characteristics, despite the addition of sisal fibers. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3797–3802, 2003     

复合泡沫塑料的性能改进研究

为改善复合泡沫塑料的介电性能,采用金属氧化物粒子填充改性双马来酰亚胺空芯玻璃微球复合泡沫塑料得到了高介电常数、低介质损耗因数、低密度、力学性能良好的电介质材料。     

聚醚型聚氨酯的氢键、微相分离及性能

用本体一步法合成了5种不同硬段含量(11.0％～46.9％)的二苯甲烷-4,4′-二异氰酸酯/环氧乙烷封端型聚环氧丙烷聚醚/乙二醇的聚醚型聚氨酯,并借助于IR,DSC,DMS和材料试验机等手段对该聚氨酯的氢键、微相分离及力学性能进行了表征。结果表明:随着硬段含量的增加,其>NH与微区中的>C=O的氢键化程度逐渐提高,软段微区中—O—的氢键化程度逐渐降低;微相分离程度逐渐提高;拉伸强度及硬度随之增加,扯断伸长率在硬段含量40％左右出现极大值。     

粉尘含碳球团还原方式及气氛对其还原挥发性能的影响

在1150℃和1250℃、0．1L／min和10L／min的气量下，对通人含不同CO2量的氮气影响粉尘含碳球团还原速度的实验研究表明：以滚动方式所造球团中，氧化物的还原完全以间接还原的方式进行，气氛中非还原气体流速（或流量）的增加对粉尘含碳球团氧化铁还原速度有显著的降低作用，但还原温度提高则对气量增加造成的氧化铁还原速度降低有显著的抵消作用．气氛对球团中锌的挥发速度影响很小，对铅的挥发速度几乎不产生影响．     

长链脂肪族氧化胺对合成纤维的抗静电作用

研究了题示表面活性剂对涤纶和丙纶的抗静电性能,探讨了不同结构的脂肪族氧化胺的抗静电效果和环境湿度、上油量对其抗静电性的影响。认为:氧化胺在低湿(30%RH)条件下也能保持良好的抗静电作用;二甲基十二烷基氧化胺在同类物中的抗静电性最佳(比电阻为0.95×10~8Ω);氧化胺作丙纶油剂的抗静电组分,可提高丙纶的加工性能和成品质量;氧化胺在纤维上的上油量(0.06%)相当低时也显示了较好的抗静电作用。     

聚合转化率对硫调型氯丁胶结构与性能的影响

研究了硫调型氯丁橡胶乳液聚合中转化率对产晶结构与性能的影响.结果表明,随单体转化率的提高,聚合物的凝胶量及其交联密度增大,致使断链速度减慢,所得断链胶的门尼粘度上升,残存凝胶量增加,分子支化程度增大,分子量分布变宽,焦烧时间缩短。而相应硫化胶的拉伸强度、撕裂强度、冲击弹性和硬度等提高,扯断伸长率和永久变形下降。这些变化一般在转化率为80——85％时有明显转折.综合考虑产量与质量,聚合转化率控制在82±2％较为适宜。